公开(公告)号：US5756846A

公开(公告)日：1998-05-26

申请号：US740742

申请日：1996-11-04

申请人： Birgit Driessen-Holscher ,  Wilhelm Keim ,  Thomas Prinz ,  Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch

发明人： Birgit Driessen-Holscher ,  Wilhelm Keim ,  Thomas Prinz ,  Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch

IPC分类号： C07C209/60 ,  C07C211/21 ,  C07C209/04

CPC分类号： C07C209/60

摘要： Octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine, from which octyl-1-amine can be prepared, are prepared selectively by telomerizing butadiene and ammonia in a two-phase system, the catalyst being used in an aqueous phase and an organic medium which is immiscible or only slightly miscible with water being employed as the second phase.

摘要翻译： 通过在二相体系中调节丁二烯和氨来选择性地制备可以制备辛基-1-胺的八氢-2,7-二烯基-1-胺和辛-1,7-二烯基-3-胺， 催化剂用于水相和与水混溶或仅与水混合的有机介质用作第二相。

公开(公告)号：US6147238A

公开(公告)日：2000-11-14

申请号：US512532

申请日：2000-02-24

申请人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

发明人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C209/54 ,  C07C209/60 ,  C07C211/21 ,  C07F5/02 ,  C07F9/50 ,  C07F15/00 ,  C07F9/02 ,  C07C209/04

CPC分类号： C07F15/006 ,  C07C209/60 ,  C07F15/0066 ,  C07F9/5022

摘要： Process for the preparation of octa-2,7-dienyl-1-amine by telomerization of butadiene with ammonia in a two-phase system in the presence of hydrophilic palladium complexes, characterized in that octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine are isolated separately from one another from the reaction mixture present after telomerization, and the octa-1,7-dienyl-3-amine isolated in this way is subjected to an isomerization reaction to form octa-2,7-dienyl-1-amine, and also novel triphenylphosphine mono- and dimethoxytri(sodium sulphonates) and the use of triphenylphosphine trimethoxytri(sodium sulphonates), triphenylphosphine trimethyltri(sodium sulphonates) and triphenylphosphine trifluorodi- and tri(sodium sulphonates) as ligands for the preparation of palladium complexes.

公开(公告)号：US6051738A

公开(公告)日：2000-04-18

申请号：US257801

申请日：1999-02-25

申请人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

发明人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C209/54 ,  C07C209/60 ,  C07C211/21 ,  C07F5/02 ,  C07F9/50 ,  C07F15/00 ,  C07C209/04

CPC分类号： C07F15/006 ,  C07C209/60 ,  C07F15/0066 ,  C07F9/5022

摘要： Process for the preparation of octa-2,7-dienyl-1-amine by telomerization of butadiene with ammonia in a two-phase system in the presence of hydrophilic palladium complexes, characterized in that octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine are isolated separately from one another from the reaction mixture present after telomerization, and the octa-1,7-dienyl-3-amine isolated in this way is subjected to an isomerization reaction to form octa-2,7-dienyl-1-amine, and also novel triphenylphosphine mono- and dimethoxytri(sodium sulphonates) and the use of triphenylphosphine trimethoxytri(sodium sulphonates), triphenylphosphine trimethyltri(sodium sulphonates) and triphenylphosphine trifluorodi- and tri(sodium sulphonates) as ligands for the preparation of palladium complexes.

摘要翻译： 通过在亲水性钯络合物的存在下，在二相体系中用氨将丁二烯与氨进行调聚来制备八-2,7-二烯基-1-胺的方法，其特征在于将八氢-2,7-二烯基-1-胺 和辛-1,7-二烯基-3-胺从调聚后存在的反应混合物彼此分开分离，并以这种方式分离的八a-17,7-二烯基-3-胺进行异构化反应 形成八-2,7-二烯基-1-胺，以及新型三苯基膦单 - 和二甲氧基三（磺酸钠），并使用三苯基膦三甲氧基三（磺酸钠），三苯基膦三甲基三（磺酸钠））和三苯基膦三氟化三 磺酸盐）作为制备钯络合物的配体。

公开(公告)号：US6160168A

公开(公告)日：2000-12-12

申请号：US511825

申请日：2000-02-24

申请人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

发明人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

IPC分类号： C07F15/00 ,  C07F9/28

CPC分类号： C07F15/0066 ,  C07F15/006

摘要： Process for the preparation of octa-2,7-dienyl-1-amine by telomerization of butadiene with ammonia in a two-phase system in the presence of hydrophilic palladium complexes, characterized in that octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine are isolated separately from one another from the reaction mixture present after telomerization, and the octa-1,7-dienyl-3-amine isolated in this way is subjected to an isomerization reaction to form octa-2,7-dienyl-1-amine, and also novel triphenylphosphine mono- and dimethoxytri(sodium sulphonates) and the use of triphenylphosphine trimethoxytri(sodium sulphonates), triphenylphosphine trimethyltri(sodium sulphonates) and triphenylphosphine trifluorodi- and tri(sodium sulphonates) as ligands for the preparation of palladium complexes.

摘要翻译： 通过在亲水性钯络合物的存在下，在二相体系中用氨将丁二烯与氨进行调聚来制备八-2,7-二烯基-1-胺的方法，其特征在于将八氢-2,7-二烯基-1-胺 和辛-1,7-二烯基-3-胺从调聚后存在的反应混合物彼此分开分离，并以这种方式分离的八a-17,7-二烯基-3-胺进行异构化反应 形成八-2,7-二烯基-1-胺，以及新型三苯基膦单 - 和二甲氧基三（磺酸钠），并使用三苯基膦三甲氧基三（磺酸钠），三苯基膦三甲基三（磺酸钠））和三苯基膦三氟化三 磺酸盐）作为制备钯络合物的配体。

公开(公告)号：US6153780A

公开(公告)日：2000-11-28

申请号：US512535

申请日：2000-02-24

申请人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

发明人： Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch ,  Thomas Prinz ,  Birgit Driessen-Holscher ,  Wilhelm Keim

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C209/54 ,  C07C209/60 ,  C07C211/21 ,  C07F5/02 ,  C07F9/50 ,  C07F15/00 ,  C07C209/04

CPC分类号： C07F15/006 ,  C07C209/60 ,  C07F15/0066 ,  C07F9/5022

摘要： Process for the preparation of octa-2,7-dienyl-1-amine by telomerization of butadiene with ammonia in a two-phase system in the presence of hydrophilic palladium complexes, characterized in that octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine are isolated separately from one another from the reaction mixture present after telomerization, and the octa-1,7-dienyl-3-amine isolated in this way is subjected to an isomerization reaction to form octa-2,7-dienyl-1-amine, and also novel triphenylphosphine mono- and dimethoxytri(sodium sulphonates) and the use of triphenylphosphine trimethoxytri(sodium sulphonates), triphenylphosphine trimethyltri(sodium sulphonates) and triphenylphosphine trifluorodi- and tri(sodium sulphonates) as ligands for the preparation of palladium complexes.

公开(公告)号：US6084113A

公开(公告)日：2000-07-04

申请号：US120938

申请日：1998-07-22

申请人： Birgit Driessen-Holscher ,  Wilhelm Keim ,  Thomas Prinz ,  Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch

发明人： Birgit Driessen-Holscher ,  Wilhelm Keim ,  Thomas Prinz ,  Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C209/60 ,  C07C211/21 ,  C07F15/00 ,  C07F9/02 ,  C07F1/00 ,  C07F13/00

CPC分类号： B01J31/1875 ,  B01J31/24 ,  C07B61/00 ,  C07C209/60 ,  C07F15/0066 ,  B01J2231/20 ,  B01J2231/32 ,  B01J2531/10 ,  B01J2531/70 ,  B01J2531/80 ,  B01J2531/824 ,  B01J2531/96

摘要： In a process for the telomerization of dienes with nucleophiles in a liquid two-phase system, use is made as catalysts of complexes comprising a transition metal as central atom and at least one tris-(hydroxyalkyl)-phosphine or -phosphine oxide as ligand. The use as catalysts of compounds comprising a transition metal as central atom and at least one tris-(hydroxy-C.sub.2 -C.sub.5 -alkyl)-phosphine or -phosphine oxide as ligand, new compounds of this type and aqueous solutions of such compounds are likewise described.

摘要翻译： 在液相双相体系中用亲核试剂调节二烯的方法中，可以使用包含过渡金属作为中心原子和至少一种三 - （羟基烷基） - 膦或 - 氧化膦作为配体的络合物的催化剂。 作为包含过渡金属作为中心原子和至少一种三 - （羟基-C 2 -C 5 - 烷基） - 膦或 - 膦氧化物作为配体的化合物的催化剂的使用，同样地，这类化合物的新化合物和这些化合物的水溶液同样地 描述。

公开(公告)号：US5834611A

公开(公告)日：1998-11-10

申请号：US878589

申请日：1997-06-19

申请人： Birgit Driessen-Holscher ,  Wilhelm Keim ,  Thomas Prinz ,  Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch

发明人： Birgit Driessen-Holscher ,  Wilhelm Keim ,  Thomas Prinz ,  Hans-Joachim Traenckner ,  Jorg-Dietrich Jentsch

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C209/60 ,  C07C211/21 ,  C07F15/00 ,  B01J31/00 ,  C07C209/00 ,  C07F9/02

CPC分类号： B01J31/1875 ,  B01J31/24 ,  C07B61/00 ,  C07C209/60 ,  C07F15/0066 ,  B01J2231/20 ,  B01J2231/32 ,  B01J2531/10 ,  B01J2531/70 ,  B01J2531/80 ,  B01J2531/824 ,  B01J2531/96

摘要： In a process for the telomerization of dienes with nucleophiles in a liquid two-phase system, use is made as catalysts of complexes comprising a transition metal as central atom and at least one tris-(hydroxyalkyl)-phosphine or -phosphine oxide as ligand. The use as catalysts of compounds comprising a transition metal as central atom and at least one tris-(hydroxy-C.sub.2 -C.sub.5 -alkyl)-phosphine or -phosphine oxide as ligand, new compounds of this type and aqueous solutions of such compounds are likewise described.