Blends of grafted acrylate polymers and mass-made ABS-type resins
    1.
    发明授权
    Blends of grafted acrylate polymers and mass-made ABS-type resins 失效
    接枝丙烯酸酯聚合物和大量制备ABS型树脂的共混物

    公开(公告)号:US4460744A

    公开(公告)日:1984-07-17

    申请号:US255956

    申请日:1981-04-20

    IPC分类号: C08L55/02 C08L51/00

    CPC分类号: C08L55/02

    摘要: Excellently-propertied, physical and intimately-admixed blends of polymers (i.e., "polyblends") comprise in intimate admixtures (A) large particle size, mass-made acrylonitrile/butadiene/styrene (i.e., "ABS")-type resins; and (B) certain grafted and/or interpolymerized rubber concentrates (i.e., "MMA") or MMA copolymers with certain other acrylic and/or vinyl monomers onto predominantly polybutadiene (i.e., "PBD") elastomeric substrate(s).

    摘要翻译: 聚合物(即“聚合物共混物”)的主要特性,物理和密实混合的共混物包括紧密混合物(A)大颗粒尺寸,大量制备的丙烯腈/丁二烯/苯乙烯(即“ABS”)型树脂; 和(B)某些接枝和/或共聚的橡胶浓缩物(即“MMA”)或与某些其它丙烯酸和/或乙烯基单体的MMA共聚物在主要是聚丁二烯(即“PBD”)弹性体基材上。

    Acrylate-grafted elastomers as polymer modifiers
    2.
    发明授权
    Acrylate-grafted elastomers as polymer modifiers 失效
    丙烯酸酯接枝弹性体作为聚合物改性剂

    公开(公告)号:US4366289A

    公开(公告)日:1982-12-28

    申请号:US255603

    申请日:1981-04-20

    CPC分类号: C08L51/04 C08L53/00

    摘要: Nicely compatibilized polymer blends (i.e., "polyblends") exhibiting attendant physical properties which are generally improved over those intrinsically coincident with the individual polymeric ingredients therein are comprised, as fundamental Components therefor, of:(A) a substantial and effectively compatibilizing quantity of a graft or block inter- or copolymer of methyl methacrylate (i.e., "MMA") and/or equivalent acrylate monomer(s) on or with a synthetic or natural rubber elastomer (i.e., "EL") substrate as a basic component of the polyblend which is referred to hereinafter as an MMA-grafted rubber concentrate or, by way of simplified acronymical definition of same, a "GRC(MMA)" which is constitutionally substantially if not entirely free of any non-interpolymerized polymethylmethacrylate (i.e., "PMMA") or equivalent homopolymeric or copolymeric inclusions; plus(B) a significant quantity of a hydrocarbonaceous and/or halo-hydrocarbonaceous polymer, copolymer and/or interpolymer (including graft and block copolymer forms having elastomeric constituents) of styrene (i.e., "ST") and/or another alkenyl aromatic monomer; and, as an additionally optional ingredient,(C) another polymeric ingredient (such as, but without limitation, ABS or an ABS-type resin) that in physically blended admixture with a Component (B) polymeric ingredient results in a composite exhibiting attendant physical properties that are generally inferior in comparison to those intrinsically coincident with the individual polymeric ingredients therein.

    摘要翻译: 作为其主要组成部分,包含显着伴随的物理性能的非常相容的聚合物共混物(即“聚合物共混物”),其通常相对于与本发明的各种聚合物成分本质上一致的物理性质而言是改进的:(A)实质上和有效相容量的 在合成或天然橡胶弹性体(即“EL”)基材上或与合成或天然橡胶弹性体(即“EL”)基质作为聚合物共混物的基本组分的甲基丙烯酸甲酯(即“MMA”)和/或等同的丙烯酸酯单体的接枝或嵌段共聚物 在下文中将其称为MMA接枝橡胶浓缩物,或者通过简化的缩略语定义,“GRC(MMA)”在组成上基本上如果不完全不含任何非共聚聚甲基丙烯酸甲酯(即“PMMA” )或等效的均聚或共聚物夹杂物; 加上(B)苯乙烯(即“ST”)和/或另一种链烯基芳族单体的显着量的含烃和/或卤代烃聚合物,共聚物和/或互聚物(包括具有弹性体组分的接枝和嵌段共聚物形式) ; 并且作为另外的任选成分,(C)与组分(B)聚合成分物理混合混合的另一种聚合物成分(例如但不限于ABS或ABS型树脂)导致复合材料显示伴随物理 与其中各种聚合物成分本质上一致的性质通常较差的性质。

    Transparent blends of polymethylmethacrylate and certain styrene
copolymers
    3.
    发明授权
    Transparent blends of polymethylmethacrylate and certain styrene copolymers 失效
    聚甲基丙烯酸甲酯和某些苯乙烯共聚物的透明共混物

    公开(公告)号:US4508871A

    公开(公告)日:1985-04-02

    申请号:US470419

    申请日:1983-02-28

    CPC分类号: C08L25/08 C08L33/12 C08L55/02

    摘要: Innately-transparent, polymethylmethacrylate polyblends, and transparent shaped articles therefrom fabricated, are comprised with components therein of:(a) polymethylmethacrylate; and(b) at least one copolymer of styrene (and/or equivalent vinyl aromatic monomers) with one or more of certain vinyl acids; plus and optionally or as an alternative;(c) at least one mass-made acrylonitrile-butadiene-styrene or acrylonitrile-butadiene-styrene-type resin in addition to or in replacement of and substitution for said component (b).

    摘要翻译: 透明的聚甲基丙烯酸甲酯聚合物共混物和由其制成的透明成型制品包括其中的成分:(a)聚甲基丙烯酸甲酯; 和(b)苯乙烯(和/或等同的乙烯基芳族单体)与一种或多种某些乙烯基酸的至少一种共聚物; 加上和可选地或作为替代; (c)除了或代替所述组分(b)之外,还含有至少一种大量制备的丙烯腈 - 丁二烯 - 苯乙烯或丙烯腈 - 丁二烯 - 苯乙烯类树脂。