公开(公告)号：US5200511A

公开(公告)日：1993-04-06

申请号：US860139

申请日：1992-03-30

申请人： Hermann Loeffler ,  Manfred Patsch

发明人： Hermann Loeffler ,  Manfred Patsch

IPC分类号： C09B62/09 ,  C09B62/04 ,  C09B62/44 ,  C09B62/513

CPC分类号： C09B62/043 ,  C09B62/4415

摘要： Reactive dyes of the formula ##STR1## where m is 0 or 1,A.sup.1 and A.sup.2 are different and each is a fiber-reactive radical or else, in the case of A.sup.2, hydrogen,D.sup.1 and D.sup.2 are substituted or unsubstituted phenylene, substituted or unsubstituted phenylenemethyl, substituted or unsubstituted naphthylene or substituted or unsubstituted naphthylenemethyl,K.sup.1 and K.sup.2 are each the radical of a coupling component of the aminonaphthalenesulfonic acid series andL is a bridge member,are useful for dyeing and printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 其中m为0或1的反应性染料，A1和A2不同，并且各自为纤维反应性基团，或者在A2的情况下，氢，D1和D2被取代或 未取代的亚苯基，取代或未取代的亚苯基甲基，取代或未取代的亚萘基或取代或未取代的萘基甲基，K1和K2各自为氨基萘磺酸系的偶联组分的基团，L为桥连构件，可用于染色和印刷羟基或 含氮底物。

公开(公告)号：US5223607A

公开(公告)日：1993-06-29

申请号：US717048

申请日：1991-06-18

申请人： Hermann Loeffler ,  Manfred Patsch ,  Reinhold Krallmann

发明人： Hermann Loeffler ,  Manfred Patsch ,  Reinhold Krallmann

IPC分类号： C09B62/09 ,  D06P1/382 ,  D06P3/10 ,  D06P3/66

CPC分类号： C09B62/09

摘要： Reactive azo dyes useful for dyeing and printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1##wherem is 0, 1 or 2,n is 1 or 2,R.sup.1 and R.sup.2 are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,T is carboxyl or hydroxysulfonyl,Hal is fluorine or chlorine,Y is fluorine, chlorine or the radical NR.sup.1 R.sup.2, OR.sup.1 or SR.sup.1, where R.sup.1 and R.sup.2 are each as defined above, andthe ring A may be benzofused and/or substituted, with the proviso thata) the sum total of acidic groups is at least 8 and thatb) when the structural element of the formula ##STR2## is present and Y is fluorine or chlorine and T is hydroxysulfonyl, the sum total of hydroxysulfonyl radicals is at least 10.

摘要翻译： 可用于染色和印刷含羟基或含氮底物的活性偶氮染料具有式（1）其中m为0,1或2，n为1或2，R 1和R 2为氢或取代或未取代的式 C 1 -C 4 - 烷基，T是羧基或羟基磺酰基，Hal是氟或氯，Y是氟，氯或NR 1 R 2，OR 1或SR 1，其中R 1和R 2各自如上所定义，并且环A可以是苯并稠合的， /或取代，条件是a）酸性基团的总和至少为8，b）当存在式“IMAGE”的结构元素且Y为氟或氯且T为羟基磺酰基时，总和 的羟基磺酰基至少为10。

公开(公告)号：US5149789A

公开(公告)日：1992-09-22

申请号：US490710

申请日：1990-03-08

申请人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

发明人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

IPC分类号： C09B50/00 ,  C09B62/04 ,  C09B62/08 ,  D06P3/10 ,  D06P3/66

CPC分类号： C09B62/043

摘要： Reactive dyes of the formula ##STR1## where 1 is 0 or 1,n is 0 or 1,E is nitrogen or C--Cl,A is the radical of an azo dye attached to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group,B--if E is nitrogen--is the radical of an azo dye or of a formazan dye which in either case is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group or else--if n is 0--is fluorine, chlorine or unsubstituted or substituted amino, or --if E is C--C1--is fluorine, chlorine or methyl,X.sup.1 and X.sup.2 are independently of the other fluorine or chlorine,X.sup.3 is fluorine or chlorine or else--if E is C--Cl--methylsulfonyl andZ.sup.1 and Z.sup.2 are independently of the other a radical of the formula ##STR2## where L.sup.3 and L.sup.4 are independently of the other hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,with the proviso that l and n are not simultaneously 0 and that, if E is C--Cl or if n is 0 and Z.sup.1 is the radical of the formula ##STR3## where L.sup.3 and L.sup.4 are each as defined above, A may also be the radical of a formazan dye which is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 式1的反应性染料，其中1为0或1，n为0或1，E为氮或C-Cl，A为通过亚氨基或C 1 -C 4烷基连接到三嗪环上的偶氮染料的基团， 烷基亚氨基，B-如果E是氮 - 是偶氮染料或甲an染料的基团，其在任一情况下通过亚氨基或C 1 -C 4 - 烷基亚氨基键合到三嗪环，否则 - 如果n是0- 是氟，氯或未取代或取代的氨基，或 - 如果E是C-C1 - 是氟，氯或甲基，则X1和X2独立于其他氟或氯，X3是氟或氯，或者 - 如果E是C -Cl-甲基磺酰基，Z 1和Z 2独立地为下式的基团：其中L 3和L 4独立于另一个氢或未取代或取代的C 1 -C 4 - 烷基，其中 条件是l和n不同时为0，并且如果E是C-Cl或如果n是0，并且Z1是式“IMAGE”的基团，其中L3和L4各自如上所定义，A也可以是t 通过亚氨基或C 1 -C 4烷基亚胺基与三嗪环结合的甲an染料的基团可用于染色或印刷含羟基或含氮基底。

公开(公告)号：US4988802A

公开(公告)日：1991-01-29

申请号：US483647

申请日：1990-02-23

申请人： Hermann Loeffler ,  Manfred Patsch

发明人： Hermann Loeffler ,  Manfred Patsch

IPC分类号： C09B62/085 ,  C09B62/03 ,  C09B62/09

CPC分类号： C09B62/03 ,  C09B62/09

摘要： Reactive dyes which possess three reactive groups and conform to the formula ##STR1## where R.sup.1 is hydrogen, methyl or ethyl,X is hydrogen or hydroxysulfonyl,Hal is fluorine or chlorine,D is phenylene, carboxyl- hydroxysulfonyl-monosubstituted or -disubstituted phenylene or hydroxysulfonylmonosubstituted or -disubstituted naphthylene, andA is a reactive group which reacts only substitutively with the hydroxyl groups of the cellulose, or A--D together are a benzo-fused reactive group which reacts only substitutively with the hydroxyl groups of the cellulose, are used for dyeing or printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 具有三个反应性基团并符合式（IMAGE）的反应性染料，其中R1是氢，甲基或乙基，X是氢或羟基磺酰基，Hal是氟或氯，D是亚苯基，羧基 - 羟基磺酰基 - 单取代或二取代的亚苯基或羧基 - 羟基磺酰基单取代或二取代的亚萘基，A是仅与纤维素的羟基取代反应的反应性基团，或AD一起是仅与纤维素的羟基取代的苯并稠合反应性基团，用于染色 或印刷含羟基或含氮底物。

公开(公告)号：US5245020A

公开(公告)日：1993-09-14

申请号：US853518

申请日：1992-03-18

申请人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

发明人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

IPC分类号： C09B62/04

CPC分类号： C09B62/043

摘要： Reactive dyes of the formula ##STR1## where l is 0 or 1,n is 0 or 1,E is nitrogen or C--ClA is the radical of an azo dye attached to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimido group,B--if E is nitrogen--is the radical of an azo dye or of a formazan dye which in either case is bonded to the triazine ring via an imino of C.sub.1 -C.sub.4 -alkylimino group or else--if n is 0--is fluorine, chlorine or unsubstituted or substituted amino, or--if E is C--Cl--is fluorine, chlorine or methyl,X.sup.1 and X.sup.2 are independently of the other fluorine or chlorine,X.sup.3 is fluorine or chlorine or else--if E is C--Cl--methylsulfonyl andZ.sup.1 and Z.sup.2 are independently of the the other a radical of the formula ##STR2## where L.sup.3 and L.sup.4 are independently of the other hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,with the proviso that l and n are not simultaneously 0 and that, if E is C--Cl or if n is 0 and Z.sup.1 is the radical of the formula ##STR3## where L.sup.3 and L.sup.4 are each as defined above, A may also be the radical of a formazan dye which is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 其中l为0或1的反应性染料，其中l为0或1，n为0或1，E为氮或C-Cl为经由亚氨基或C 1 -C 4烷基亚氨基连接到三嗪环上的偶氮染料的基团 基团，B-如果E是氮，则是偶氮染料或甲an染料的基团，在任一情况下，通过C 1 -C 4 - 烷基亚氨基的亚氨基键合到三嗪环，或者 - 如果n是0- 氟，氯或未取代或取代的氨基，或 - 如果E是C-Cl-是氟，氯或甲基，则X1和X2独立于其它氟或氯，X3是氟或氯，或者 - 如果E是C- Cl-甲基磺酰基，Z 1和Z 2独立地为下式的基团：其中L 3和L 4独立于另一个氢或未取代或取代的C 1 -C 4 - 烷基，条件是 l和n不同时为0，并且如果E是C-Cl，或者如果n是0，并且Z1是式“IMAGE”的基团，其中L3和L4各自如上定义，则A也可以是 通过亚氨基或C 1 -C 4烷基亚胺基与三嗪环结合的甲an染料的基团可用于染色或印刷含羟基或含氮基底。

公开(公告)号：US5216137A

公开(公告)日：1993-06-01

申请号：US726242

申请日：1991-07-05

申请人： Hermann Loeffler ,  Manfred Patsch ,  Reinhold Krallmann

发明人： Hermann Loeffler ,  Manfred Patsch ,  Reinhold Krallmann

IPC分类号： C09B62/04

CPC分类号： C09B62/043

摘要： Azo reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where m is 0, 1 or 2,n is 0 or 1,p is 0 or 1,R.sup.1 and R.sup.2 are each independently of the other hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.3 is hydrogen, methyl or ethyl,T is carboxyl or hydroxysulfonyl,Hal is fluorine or chlorine, andthe ring A may be benzofused or substituted.

摘要翻译： 可用于染色或印刷含羟基或含氮底物的偶氮活性染料具有式（1）其中m为0,1或2，n为0或1，p为0或1， R 1和R 2各自独立地为另一个氢或取代或未取代的C 1 -C 4 - 烷基，R 3是氢，甲基或乙基，T是羧基或羟基磺酰基，Hal是氟或氯，并且环A可以是苯并稠合或取代的。

公开(公告)号：US5175262A

公开(公告)日：1992-12-29

申请号：US781643

申请日：1991-10-25

申请人： Hermann Loeffler ,  Klaus Pandl ,  Manfred Patsch ,  Siegel Bernd

发明人： Hermann Loeffler ,  Klaus Pandl ,  Manfred Patsch ,  Siegel Bernd

IPC分类号： C09B62/04 ,  C09B62/44

CPC分类号： C09B62/4415 ,  C09B62/043

摘要： Reactive dyes of the formula ##STR1## where R.sup.1 is hydrogen, methyl or ethyl,X is hydrogen or hydroxysulfonyl,Hal is fluorine or chlorine,D is phenylene, carboxyl- or hydroxysulfonyl-monosubstituted or -disubstituted phenylene or hydroxysulfonyl-monosubstituted or -disubstituted naphthylene,A is a fiber-reactive radical, or A--D combined is a benzo-fused fiber-reactive radical, andZ is a bridge member, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 其中R 1是氢，甲基或乙基，X是氢或羟基磺酰基，Hal是氟或氯，D是亚苯基，羧基或羟基磺酰基单取代或二取代亚苯基或羟基磺酰基单取代或二取代的反应性染料 亚萘基，A是纤维反应性基团，或AD组合是苯并稠合纤维反应性基团，Z是桥接部件，可用于染色或印刷含羟基或含氮基材。

公开(公告)号：US4952681A

公开(公告)日：1990-08-28

申请号：US205359

申请日：1988-07-27

申请人： Guenter Hansen ,  Ernst Schefczik ,  Karl-Heinz Etzbach ,  Helmut Reichelt ,  Hermann Loeffler

发明人： Guenter Hansen ,  Ernst Schefczik ,  Karl-Heinz Etzbach ,  Helmut Reichelt ,  Hermann Loeffler

IPC分类号： C09B29/00 ,  C09B62/35 ,  C09B29/033 ,  C09B29/33 ,  C09B29/36

CPC分类号： C09B29/0059

摘要： Compounds of the formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are disclosed. They are useful for dyeing synthetic fibers or plastics.

摘要翻译： 1.式I的化合物参见图示：EP0201896，P71，F3，其中X是氟，氯，溴，SO2E，OH，OCH3，OC2H5，OC3H7，OC4H9，OCH2 C6H5，OC6H11，OC6H5 ，OC 6 H 4 CH 3，OC 6 H 4 Cl，SH，SCH 3，SC 2 H 5，SC 3 H 7，SC 4 H 9，SCH 2 C 6 H 5，SC 2 H 4 OH，SCH 2 COOCH 3，SCH 2 COOC 2 H 5，SC 6 H 11，SC 6 H 5或SC 6 H 4 CH 2，E是烷基 ，链烯基，环烷基，芳烷基，芳基，氯，OH，CH3O，C2H5O，C3H7O，C4H9O，C6H5 -CH2O，C6H5 -CH2 -CH2O，C6H5O，CIC6H4O， CH 3 C 4 H 4 O，NH 2，NHCH 3，N（CH 3）2，NHC 2 H 5，N（C 2 H 5）2，NCH 4 H 9，N（C 4 H 9）2，NHC 6 H 5，NHC 6 H 4 -CH 3，NHC 6 H 4 Cl或NCH 3 C 6 H 5 ，Y是氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C 1 -C 4烷基，NO，NO 2，SO 3 H，CHO，CN， ，C 2 H 5 CO，C 6 H 5 CO，CH 3 SO 2，C 2 H 5 SO 2，C 6 H 5 SO 2或式-CH = B的基团，其中B是亚甲基活性化合物或胺的基团，K是 激进或 耦合部件。

公开(公告)号：US4668774A

公开(公告)日：1987-05-26

申请号：US726372

申请日：1985-04-23

申请人： Hermann Loeffler ,  Rainer Dyllick-Brenzinger

发明人： Hermann Loeffler ,  Rainer Dyllick-Brenzinger

IPC分类号： C09B69/04 ,  C09B44/02 ,  C09B44/04 ,  C09B44/06 ,  C09B44/08 ,  D06P1/02 ,  D06P1/44 ,  D06P1/46

CPC分类号： C09B69/04 ,  Y10S534/02

摘要： Novel dye salts of anionic dyes of the general formula I ##STR1## where F is a radical of an anionic dye, n is 1, 2, 3 or 4, and B.sup.1 and B.sup.2 independently of one another are each unsubstituted or substituted branched alkyl or alkyl-substituted cycloalkyl having a total of 10 to 36 carbon atoms, are very useful for dyeing solvents, printing inks or polymeric film-forming materials.

摘要翻译： 通式I的阴离子染料的新型染料盐其中F是阴离子染料的基团，n是1,2,3或4，并且彼此独立的B 1和B 2各自是未取代的或取代的支链烷基 或具有总共10至36个碳原子的烷基取代的环烷基对染色溶剂，印刷油墨或聚合物成膜材料非常有用。

公开(公告)号：US5352774A

公开(公告)日：1994-10-04

申请号：US125666

申请日：1993-09-23

申请人： Guenter Hansen ,  Ernst Schefczik ,  Karl-Heinz Etzbach ,  Helmut Reichelt ,  Hermann Loeffler

发明人： Guenter Hansen ,  Ernst Schefczik ,  Karl-Heinz Etzbach ,  Helmut Reichelt ,  Hermann Loeffler

IPC分类号： C09B29/00 ,  C09B29/033 ,  C09B29/40 ,  D06P1/18

CPC分类号： C09B29/0059

摘要： The compounds of the general formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are very useful for dyeing synthetic fibers or plastics.

摘要翻译： 其中X是氟，氯，溴，SO2E或未取代或取代的羟基或巯基的通式I的化合物，E是烷基，烯基，环烷基，芳烷基，芳基，氯或未取代或取代的羟基或氨基，Y 氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C1-C4-烷基，可以通过亲电取代引入的基团或式 -CH = B，其中B是亚甲基活性化合物或胺的基团，K是偶合组分的基团，对于合成纤维或塑料的染色非常有用。