公开(公告)号：US07083732B1

公开(公告)日：2006-08-01

申请号：US10069565

申请日：2000-08-25

申请人： Hervé Chollet ,  Jean-Louis Babou ,  Frédéric Barbette ,  Roger Guilard

发明人： Hervé Chollet ,  Jean-Louis Babou ,  Frédéric Barbette ,  Roger Guilard

IPC分类号： C02F1/28 ,  C02F1/42

CPC分类号： B01J45/00 ,  G21F9/12 ,  Y10S210/911 ,  Y10S210/912 ,  Y10S210/913 ,  Y10S210/914

摘要： The invention is related to a method and an installation for removal of metal cations contained in a liquid, in which said liquid is brought into contact at a temperature greater than or equal to 60° C. with a chelating ion exchange resin formed from a polyazacycloalkane grafted on a solid support, said resin having been conditioned, previously to said contacting, at a pH of 4 to 6.

摘要翻译： 本发明涉及一种用于除去液体中所含的金属阳离子的方法和装置，其中所述液体以大于或等于60℃的温度与由多氮杂环烷烃形成的螯合离子交换树脂接触 接枝在固体载体上，所述树脂预先在4至6的pH下进行所述接触。

公开(公告)号：US06372903B1

公开(公告)日：2002-04-16

申请号：US09600996

申请日：2000-07-26

申请人： Ahmad Mehdi ,  Franck Denat ,  Frédéric Barbette ,  Roger Guilard ,  Gilles Lagrange

发明人： Ahmad Mehdi ,  Franck Denat ,  Frédéric Barbette ,  Roger Guilard ,  Gilles Lagrange

IPC分类号： C07D25502

CPC分类号： B01J20/3263 ,  B01J20/3204 ,  B01J20/3219 ,  B01J20/3259 ,  B01J45/00 ,  C07F7/1804

摘要： The invention concerns a method for preparing polyazacycloalkanes immobilised on a silica gel from a polyazacycloalkane of formula (A) in which: R1 and R2 represent a hydrogen atom, an alkyl radical, or a [hetero(aryl)]alkyl radical; W1, W2 and W3 represent a radical of formula (B): —[(CT1T2)n—[N(R3)]p—(CT3T4)m]l— such as defined in the description; R3 represents a hydrogen atom, an alkyl radical or a [hetero(aryl)]alkyl radical, provided that the polyazacycloalkane ring of the compound of formula (A) comprises not more than 30 cyclic carbon atoms, and not more than 6 cyclic nitrogen atoms. The invention is characterised in that: (a) the compound of formula (A) is reacted with a compound of formula (C): Z—R4—Si(X1)(X2)(X3), such as defined in the description to form a compound of formula (D); (b) said compound of formula (D) is condensed on the silanol sites of a silica gel to form the immobilised polyazacycloalkane of formula (E); and (c) some ethanol sites having not reacted are, if required, protected by Z′, a group protecting the hydroxyl function. The invention is useful for separating oxygen from air.

摘要翻译： 本发明涉及一种由式（A）的多氮杂环烷固定在硅胶上的多氮杂环烷烃的方法，其中：R1和R2表示氢原子，烷基或[杂（芳基）]烷基; W1，W2和W3表示式（B）的基团： - [（CT1T2）n- [N（R3）] p-（CT3T4）m] -1-如描述中所定义; R 3表示氢原子，烷基或[杂（芳基）]烷基，条件是式（A）化合物的多氮杂环烷烃环包含不多于30个环状碳原子，并且不超过6个环状氮原子 。 本发明的特征在于：（a）式（A）化合物与式（C）化合物：Z-R 4 -Si（X 1）（X 2）（X 3） 形成式（D）的化合物; （b）所述式（D）化合物在硅胶的硅烷醇位上缩合形成式（E）的固定化的多氮杂环烷烃; 和（c）如果需要，一些没有反应的乙醇部位被保护羟基官能团的Z'保护。 本发明可用于从空气中分离氧气。