Method and Composition For Sorbing Toxic Substances
    3.
    发明申请
    Method and Composition For Sorbing Toxic Substances 审中-公开
    吸附有毒物质的方法和组成

    公开(公告)号:US20100218676A1

    公开(公告)日:2010-09-02

    申请号:US12781955

    申请日:2010-05-18

    申请人: Joseph Iannicelli

    发明人: Joseph Iannicelli

    摘要: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

    摘要翻译: 使用吸附剂组合物从介质中提取有毒物质如重金属。 吸附剂组合物是通过红泥硫化产生的,该泥浆含有源于铝土矿的拜耳处理的水合氧化铁。 示例性硫化化合物是H 2 S,Na 2 S,K 2 S,(NH 4)2 S和CaS x。 硫含量通常比红泥中的残留硫高约0.2至约10%。 与大部分测试重金属(Hg,Cr,Pb,Cu,Zn,Cd,Se,Th和U)的红泥相比,硫化红泥是一种改进的吸附剂。 与红泥不同,硫化红泥不会浸出天然含有的金属。 硫化红泥还可防止与红泥混合时金属浸出。 硫化红泥和红泥的混合物比单独硫化红泥更有效地吸附其他离子,如As,Co,Mn和Sr。

    Method and composition for sorbing toxic substances
    4.
    发明授权
    Method and composition for sorbing toxic substances 失效
    吸附有毒物质的方法和组成

    公开(公告)号:US07763566B2

    公开(公告)日:2010-07-27

    申请号:US11277282

    申请日:2006-03-23

    申请人: Joseph Iannicelli

    发明人: Joseph Iannicelli

    IPC分类号: B01J20/02

    摘要: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

    摘要翻译: 使用吸附剂组合物从介质中提取有毒物质如重金属。 该组合物是通过红泥硫化产生的,其中含有源自铝土矿矿石的拜耳处理的水合氧化铁。 示例性硫化化合物是H 2 S,Na 2 S,K 2 S,(NH 4)2 S和CaS x。 硫含量通常比红泥中的残留硫高约0.2至约10%。 与大部分测试重金属(Hg,Cr,Pb,Cu,Zn,Cd,Se,Th和U)的红泥相比,硫化红泥是一种改进的吸附剂。 与红泥不同,硫化红泥不会浸出天然含有的金属。 硫化红泥还可防止与红泥混合时金属浸出。 硫化红泥和红泥的混合物比单独硫化红泥更有效地吸附其他离子,如As,Co,Mn和Sr。

    REDUCING WATER PURIFICATION MATERIAL, METHOD FOR PRODUCING REDUCING WATER PURIFICATION MATERIAL, METHOD FOR TREATING WASTEWATER, AND WASTEWATER TREATMENT APPARATUS
    7.
    发明申请
    REDUCING WATER PURIFICATION MATERIAL, METHOD FOR PRODUCING REDUCING WATER PURIFICATION MATERIAL, METHOD FOR TREATING WASTEWATER, AND WASTEWATER TREATMENT APPARATUS 有权
    减少水净化材料,减少水净化材料的生产方法,废水处理方法和废水处理装置

    公开(公告)号:US20070209989A1

    公开(公告)日:2007-09-13

    申请号:US10598494

    申请日:2005-04-25

    IPC分类号: C02F1/48

    摘要: A reducing water purification material having a reducing iron-based precipitate selected from green rust, iron ferrite, reducing iron hydroxide, and a mixture thereof. A wastewater treatment process having steps of adding a reducing iron compound to wastewater, leading the wastewater to which the reducing iron compound is added to a reaction tank and forming a precipitate, separating the formed precipitate by a solid-liquid separation to obtain a sludge, and alkalinizing all or a portion of the separated sludge to form an alkaline sludge followed by returning to the reaction tank, wherein in the precipitation step, the wastewater to which the reducing iron compound is added and the alkaline sludge are mixed and are allowed to react in a non-oxidizing atmosphere under alkaline condition to form a reducing iron compound precipitate as the precipitate, thereby incorporating contaminants in the precipitate to remove the contaminants from the wastewater.

    摘要翻译: 一种还原性水净化材料,其具有选自绿锈,铁铁素体,还原铁氢氧化物的还原性铁基沉淀物及其混合物。 一种废水处理方法,其具有将还原铁化合物添加到废水中的步骤,将还原铁化合物加入到反应罐中并形成沉淀物的废水,通过固液分离分离形成的沉淀物以获得污泥, 使全部或一部分分离的污泥碱化,形成碱性污泥,然后返回反应槽,其中在沉淀步骤中,加入还原铁化合物的废水和碱性污泥混合并使其反应 在非氧化性气氛中在碱性条件下形成还原铁化合物作为沉淀物沉淀物,从而在沉淀物中掺入污染物以从废水中除去污染物。

    Process for detoxification of CCA-treated wood
    9.
    发明授权
    Process for detoxification of CCA-treated wood 失效
    CCA处理木材的解毒过程

    公开(公告)号:US07160526B2

    公开(公告)日:2007-01-09

    申请号:US10434529

    申请日:2003-05-09

    IPC分类号: C01G3/00 C01G37/00 C01G28/00

    摘要: A chemical process for detoxifying spent CCA (copper, chrome, arsenic)—treated wood, from which CCA and detoxified wood are recovered for recycling comprising the steps of (a) treating CCA-treated wood in the presence of a liquefying reagent such as an organic solvent at 100–250° C. with or without ferrous ions to form liquefied CCA-treated wood (b) adding water or an aqueous solution of an organic solvent to the liquefied CCA-treated wood with stirring to obtain an aqueous solution of liquefied CCA-treated wood (c) adding complexing or precipitating agents, such as phosphoric acid or calcium hydroxide to the aqueous solution of step (b) thereby precipitating insoluble heavy metal complexes or precipitates and forming a solution of detoxified CCA-treated wood (d) separating said heavy metal complexes or precipitates from the solution of detoxified liquefied CCA-treated wood and (e) isolating chromated copper arsenate from said heavy metal complex or precipitate.Further, the solvent may be removed from the solution of detoxified CCA-treated wood of step (d) to obtain concentrated liquefied detoxified CCA-treated wood. This concentrated material may be used as a phenolic or polyurethane intermediate.Additionally, by adding a concentrated inorganic acid, such as sulfuric acid, nitric acid or phosphoric acid, to the complex or precipitated solids of step (d), chromated copper arsenate can be recovered for use in manufacturing additional CCA-treated wood.

    摘要翻译: 回收用于回收CCA和解毒木材的废CCA(铜,铬,砷)处理木材的化学过程,包括以下步骤:(a)在液化试剂存在下处理CCA处理的木材,例如 有机溶剂在100-250℃下有或没有亚铁离子形成液化的CCA处理的木材(b)在搅拌下向液化的CCA处理的木材中加入水或有机溶剂的水溶液,得到液化的水溶液 CCA处理的木材(c)向步骤(b)的水溶液中加入络合或沉淀剂如磷酸或氢氧化钙,从而沉淀不溶重金属络合物或沉淀物并形成解毒的CCA处理的木材溶液(d) 从解毒的液化CCA处理的木材的溶液中分离所述重金属络合物或沉淀物,和(e)从所述重金属络合物或沉淀物中分离铬酸铜铜酸盐。 此外,溶剂可以从步骤(d)的解毒的CCA处理的木材的溶液中除去,得到浓缩的液化解毒的CCA处理的木材。 该浓缩物可用作酚醛或聚氨酯中间体。 此外,通过向浓缩步骤(d)的复合物或沉淀固体中加入浓硫酸,硝酸或磷酸等无机酸,可以回收铬酸铜铜,以制备额外的经CCA处理的木材。

    Method for removing fluorine from a fluorine-containing wastewater
    10.
    发明申请
    Method for removing fluorine from a fluorine-containing wastewater 失效
    从含氟废水中除去氟的方法

    公开(公告)号:US20060266711A1

    公开(公告)日:2006-11-30

    申请号:US11142874

    申请日:2005-05-31

    申请人: Ming-Hui Liao

    发明人: Ming-Hui Liao

    IPC分类号: C02F1/52

    摘要: A method for removing fluorine from wastewater includes the steps of: adding a fluorine-reactive agent, that comprises a water-soluble sodium compound and a water-soluble aluminum compound, into the wastewater so as to form sodium ions and aluminum ions in the wastewater and so as to precipitate sodium aluminum fluoride by reaction of the sodium ions and the aluminum ions with fluorine ions in the wastewater; and removing the precipitate of sodium aluminum fluoride from the wastewater.

    摘要翻译: 从废水中除去氟的方法包括以下步骤:向废水中加入包含水溶性钠化合物和水溶性铝化合物的氟反应剂,以在废水中形成钠离子和铝离子 并通过废水中的钠离子和铝离子与氟离子的反应来沉淀氟化铝钠; 并从废水中除去氟化铝钠的沉淀物。