公开(公告)号：US07294250B2

公开(公告)日：2007-11-13

申请号：US10862365

申请日：2004-06-08

申请人： Hideki Abe ,  Hideaki Kitazawa ,  Kenji Yoshii ,  Junichiro Mizuki

发明人： Hideki Abe ,  Hideaki Kitazawa ,  Kenji Yoshii ,  Junichiro Mizuki

IPC分类号： H01L39/24

CPC分类号： C25D3/66 ,  H01L39/2487

摘要： A very small amount of copper chloride or zinc oxide is added to a mixture of magnesium chloride, potassium chloride, sodium chloride and magnesium borate, a mixed salt is melted under heat, electrodes are inserted into a molten salt and a metallic material employed as a cathode is electroplated with a magnesium diboride (MgB2) film.

摘要翻译： 将少量的氯化铜或氧化锌加入到氯化镁，氯化钾，氯化钠和硼酸镁的混合物中，将混合盐在加热下熔融，将电极插入熔融盐中，将金属材料用作 阴极用二硼化镁（MgB 2 N 2）膜电镀。

公开(公告)号：US07060174B2

公开(公告)日：2006-06-13

申请号：US10364422

申请日：2003-02-12

申请人： Kenji Yoshii ,  Junichiro Mizuki ,  Hideki Abe ,  Hideaki Kitazawa ,  Akiyuki Matsushita

发明人： Kenji Yoshii ,  Junichiro Mizuki ,  Hideki Abe ,  Hideaki Kitazawa ,  Akiyuki Matsushita

IPC分类号： B41M5/20 ,  C04B39/24 ,  H01L39/00

CPC分类号： H01L39/2487 ,  C25B1/00

摘要： A method for electrochemical synthesis of a superconducting boron compound MgB2 which comprises the steps of preparing a powder mixture of magnesium chloride, sodium chloride, potassium chloride and magnesium borate, drying the mixture by electrical heating at a temperature of 400° C. or below under an inert gas atmosphere, and further heating the mixture electrically at a temperature of 400° C. or above so that it is melted and undergoes chemical reaction.

摘要翻译： 一种用于电化学合成超导硼化合物MgB 2 N的方法，其包括以下步骤：制备氯化镁，氯化钠，氯化钾和硼酸镁的粉末混合物，在温度下电加热干燥混合物 在惰性气体气氛下为400℃以下，在400℃以上的温度下进一步加热该混合物，使其熔融并进行化学反应。

公开(公告)号：US20050034992A1

公开(公告)日：2005-02-17

申请号：US10862365

申请日：2004-06-08

申请人： Hideki Abe ,  Hideaki Kitazawa ,  Kenji Yoshii ,  Junichiro Mizuki

发明人： Hideki Abe ,  Hideaki Kitazawa ,  Kenji Yoshii ,  Junichiro Mizuki

IPC分类号： C01G1/00 ,  C01B35/04 ,  C25D3/66 ,  C25D9/10 ,  H01L39/12 ,  H01M4/02

CPC分类号： C25D3/66 ,  H01L39/2487

摘要： A very small amount of copper chloride or zinc oxide is added to a mixture of magnesium chloride, potassium chloride, sodium chloride and magnesium borate, a mixed salt is melted under heat, electrodes are inserted into a molten salt and a metallic material employed as a cathode is electroplated with a magnesium diboride (MgB2) film.

摘要翻译： 将少量的氯化铜或氧化锌加入到氯化镁，氯化钾，氯化钠和硼酸镁的混合物中，将混合盐在加热下熔融，将电极插入熔融盐中，将金属材料用作 阴极用二硼化镁（MgB 2）膜电镀。

公开(公告)号：US5294600A

公开(公告)日：1994-03-15

申请号：US907627

申请日：1992-07-02

申请人： Katsumi Tanigaki ,  Thomas Ebbesen ,  Sadanori Kuroshima ,  Junichiro Mizuki

发明人： Katsumi Tanigaki ,  Thomas Ebbesen ,  Sadanori Kuroshima ,  Junichiro Mizuki

IPC分类号： H01L39/12 ,  C01B31/00

CPC分类号： B82Y30/00 ,  H01L39/123 ,  Y10S423/39 ,  Y10S505/775 ,  Y10S505/80 ,  Y10S977/735

摘要： A superconducting material higher in superconducting transition temperature and superconducting volume ratio than any conventional one is provided, which comprises a fullerene doped with rubidium and cesium. This fullerene system superconducting material makes it possible to improve both the superconducting transition temperature and superconducting volume ratio by having rubidium and cesium doped thereinto compared with any conventional fullerene systems. If the chemical composition of this super conducting material is expressed as Rb.sub.x Cs.sub.y C.sub.n, x and y are arbitrary if an equation x+y=3 is satisfied, preferable to be x=2 and y=1, further preferable to be x=1 and y=s. The superconducting transition temperature Tc and superconducting volume ratio when x=1 and y=2 or x=2 and y=1 are superior to those when x=3 and y=0 or x=0 and y=3, respectively.

摘要翻译： 提供超导材料的超导转变温度和超导体积比高于任何常规材料的超导材料，其包含掺杂有铷和铯的富勒烯。 与任何常规的富勒烯系统相比，该富勒系统超导材料通过使铷和铯掺杂而能够提高超导转变温度和超导体积比。 如果该超导材料的化学成分表示为Rb x C y C n，则x和y如果满足x + y = 3等式，则x和y是任意的，优选为x = 2且y = 1，进一步优选为x = 1，y = s。 当x = 1和y = 2或x = 2和y = 1时的超导转变温度Tc和超导体积比分别优于当x = 3和y = 0或x = 0和y = 3时的超导转变温度Tc和超导体积比。