公开(公告)号：US20130248765A1

公开(公告)日：2013-09-26

申请号：US13990192

申请日：2011-11-28

申请人： Hiroshi Niino ,  Yutaka Aoki

发明人： Hiroshi Niino ,  Yutaka Aoki

IPC分类号： C09K11/06

CPC分类号： C09K11/06 ,  C08J3/20 ,  C08K5/00 ,  C08K5/56 ,  C08L33/12 ,  C08L101/00 ,  C09K2211/1088 ,  C09K2211/186 ,  H01L51/0081

摘要： Disclosed is a production method of a thermoplastic resin composition comprising: blending a thermoplastic resin (A) and a metal complex (B) and a ligand (C2), wherein the metal complex (B) has a ligand (C1) coordinated therein, and wherein the ligand (C2) has a higher boiling point than the ligand (C1) under atmospheric pressure, and then heating and mixing the resulting blend at a temperature of not less than a boiling point of the ligand (C1) and not more than a boiling point of the ligand (C2), to produce a thermoplastic resin composition that can provide a light-emitting body at low cost in which a light-emitting material is dispersed in the resin in a good dispersion state, excellent in transparency and excellent in light-emitting properties of visible light; a molding material obtained by molding the thermoplastic resin composition; and a light-emitting body obtained by molding the thermoplastic resin composition.

公开(公告)号：US09822235B2

公开(公告)日：2017-11-21

申请号：US13976549

申请日：2012-01-06

申请人： Yutaka Aoki ,  Hiroshi Niino

发明人： Yutaka Aoki ,  Hiroshi Niino

IPC分类号： C08K3/40 ,  H01L31/04 ,  C08L33/12 ,  H01L31/048

CPC分类号： C08K3/40 ,  C08K2201/016 ,  C08L33/12 ,  H01L31/0481 ,  Y02E10/50

摘要： A thermoplastic acrylic resin composition is provided in which translucency properties are suitable for use as a top-sheet member of a photovoltaic cell, warping caused by temperature change is suppressed, and its weathering resistance is excellent; 0.1 to 50 parts by mass of a glass is contained in 100 parts by mass of the thermoplastic acrylic resin; an absolute value of a difference in refractive indices of the thermoplastic acrylic resin and the glass is 0.08 or lower; an average particle size of the glass is 100 to 2,000 μm; a softening temperature of the thermoplastic resin is 80° C. or higher; and the aspect ratio of the glass is 15 or greater. Also, a molded article which is obtained by molding the thermoplastic acrylic resin composition and has a YI value of 20 or lower after weathering-resistance testing. Further, a top-sheet member of a photovoltaic cell is made of the molded article.

公开(公告)号：US09090820B2

公开(公告)日：2015-07-28

申请号：US13990192

申请日：2011-11-28

申请人： Hiroshi Niino ,  Yutaka Aoki

发明人： Hiroshi Niino ,  Yutaka Aoki

IPC分类号： C09K11/06 ,  C08J3/20 ,  C08K5/00 ,  C08K5/56 ,  C08L101/00

CPC分类号： C09K11/06 ,  C08J3/20 ,  C08K5/00 ,  C08K5/56 ,  C08L33/12 ,  C08L101/00 ,  C09K2211/1088 ,  C09K2211/186 ,  H01L51/0081

摘要： Disclosed is a production method of a thermoplastic resin composition comprising: blending a thermoplastic resin (A) and a metal complex (B) and a ligand (C2), wherein the metal complex (B) has a ligand (C1) coordinated therein, and wherein the ligand (C2) has a higher boiling point than the ligand (C1) under atmospheric pressure, and then heating and mixing the resulting blend at a temperature of not less than a boiling point of the ligand (C1) and not more than a boiling point of the ligand (C2), to produce a thermoplastic resin composition that can provide a light-emitting body at low cost in which a light-emitting material is dispersed in the resin in a good dispersion state, excellent in transparency and excellent in light-emitting properties of visible light; a molding material obtained by molding the thermoplastic resin composition; and a light-emitting body obtained by molding the thermoplastic resin composition.

摘要翻译： 本发明公开了一种热塑性树脂组合物的制造方法，其特征在于，包括：配合热塑性树脂（A）和金属络合物（B）和配位体（C2），其中所述金属络合物（B）与配位体（C1）配位， 其中配体（C2）在大气压下具有比配体（C1）高的沸点，然后在不低于配体（C1）的沸点的温度下加热并混合所得共混物，并且不大于 配合物（C2）的沸点，制造能够以低成本提供发光体以良好的分散状态分散在树脂中的发光体的热塑性树脂组合物，透明性优异， 可见光的发光特性; 通过模塑该热塑性树脂组合物获得的模塑材料; 以及通过模塑该热塑性树脂组合物而获得的发光体。

公开(公告)号：US20130281601A1

公开(公告)日：2013-10-24

申请号：US13976549

申请日：2012-01-06

申请人： Yutaka Aoki ,  Hiroshi Niino

发明人： Yutaka Aoki ,  Hiroshi Niino

IPC分类号： C08K3/40

CPC分类号： C08K3/40 ,  C08K2201/016 ,  C08L33/12 ,  H01L31/0481 ,  Y02E10/50

摘要： A thermoplastic acrylic resin composition is provided in which translucency properties are suitable for use as a top-sheet member of a photovoltaic cell, warping caused by temperature change is suppressed, and its weathering resistance is excellent; 0.1 to 50 parts by mass of a glass is contained in 100 parts by mass of the thermoplastic acrylic resin; an absolute value of a difference in refractive indices of the thermoplastic acrylic resin and the glass is 0.08 or lower; an average particle size of the glass is 100 to 2,000 μm; a softening temperature of the thermoplastic resin is 80° C. or higher; and the aspect ratio of the glass is 15 or greater. Also, a molded article which is obtained by molding the thermoplastic acrylic resin composition and has a YI value of 20 or lower after weathering-resistance testing. Further, a top-sheet member of a photovoltaic cell is made of the molded article.

摘要翻译： 提供了一种热塑性丙烯酸树脂组合物，其中半透明性能适用于光伏电池的顶片部件，由温度变化引起的翘曲被抑制，耐候性优异; 在100质量份热塑性丙烯酸树脂中含有0.1〜50质量份的玻璃; 热塑性丙烯酸树脂和玻璃的折射率差的绝对值为0.08以下; 玻璃的平均粒径为100〜2000μm; 热塑性树脂的软化温度为80℃以上; 玻璃的纵横比为15以上。 另外，通过将耐热性试验后的热塑性丙烯酸树脂组合物成型得到YI值为20以下的成型品。 此外，光伏电池的顶片部件由模制品制成。

公开(公告)号：US08889785B2

公开(公告)日：2014-11-18

申请号：US13391467

申请日：2010-08-19

申请人： Hiroshi Niino ,  Mitsufumi Nodono

发明人： Hiroshi Niino ,  Mitsufumi Nodono

IPC分类号： C08K5/06 ,  C08L33/08 ,  C08L33/10 ,  C08L33/12 ,  C08K3/10 ,  C08K3/16 ,  C08J3/20 ,  C09K11/02 ,  C08L71/02

CPC分类号： C08J3/203 ,  C08L71/02 ,  C09K11/02 ,  C09K2211/14

摘要： Disclosed is a production method of a thermoplastic resin composition which has a good light emission property of visible light by ultraviolet irradiation, the production method comprising: compounding 0.001 to 50 parts by mass of at least one of metal compound (B) selected from a metal complex (B1) and a metal halide (B2), and 0.001 to 30 parts by mass of a polyalkylene glycol compound (C), with respect to 100 parts by mass of a thermoplastic resin (A); and heating it at a temperature of 100 to 320° C.

摘要翻译： 公开了通过紫外线照射具有良好的可见光发光性的热塑性树脂组合物的制造方法，其制造方法包括：将0.001〜50质量份的金属化合物（B）中的至少一种选自金属 复合物（B1）和金属卤化物（B2），相对于100质量份的热塑性树脂（A）为0.001〜30质量份的聚亚烷基二醇化合物（C）。 并在100〜320℃的温度下加热。

公开(公告)号：US09200123B2

公开(公告)日：2015-12-01

申请号：US13504492

申请日：2010-10-26

申请人： Hiroshi Niino

发明人： Hiroshi Niino

IPC分类号： C08K5/07 ,  C08J3/20 ,  C08K5/00 ,  C09K11/06

CPC分类号： C09K11/06 ,  C08J3/201 ,  C08J3/203 ,  C08K5/0091 ,  C08K5/07 ,  C09K2211/186 ,  C08L33/12

摘要： Disclosed is a production method of a thermoplastic resin composition comprising: compounding 0.001 to 50 parts by mass of a metal complex (B) with respect to 100 parts by mass of a thermoplastic resin (A), and kneading it under a condition of a kneading temperature of 225 to 300° C. and of a kneading time of 0.5 to 20 minutes, wherein a metal of the metal complex (B) is a metal except for zinc; a molded body obtained by molding the thermoplastic resin composition which is obtained by the production method; and a light emission body using the molded body.

摘要翻译： 本发明公开了一种热塑性树脂组合物的制造方法，其特征在于，相对于100质量份热塑性树脂（A），配合0.001〜50质量份的金属络合物（B），在捏合条件下进行混炼 温度为225〜300℃，捏合时间为0.5〜20分钟，金属络合物（B）的金属除锌以外的金属; 通过将通过该制造方法获得的热塑性树脂组合物成型而得到的成型体; 以及使用该成形体的发光体。

公开(公告)号：US20120214922A1

公开(公告)日：2012-08-23

申请号：US13391467

申请日：2010-08-19

申请人： Hiroshi Niino ,  Mitsufumi Nodono

发明人： Hiroshi Niino ,  Mitsufumi Nodono

IPC分类号： C08K5/06

CPC分类号： C08J3/203 ,  C08L71/02 ,  C09K11/02 ,  C09K2211/14

摘要： Disclosed is a production method of a thermoplastic resin composition which has a good light emission property of visible light by ultraviolet irradiation, the production method comprising: compounding 0.001 to 50 parts by mass of at least one of metal compound (B) selected from a metal complex (B1) and a metal halide (B2), and 0.001 to 30 parts by mass of a polyalkylene glycol compound (C), with respect to 100 parts by mass of a thermoplastic resin (A); and heating it at a temperature of 100 to 320° C.

摘要翻译： 公开了通过紫外线照射具有良好的可见光发光性的热塑性树脂组合物的制造方法，其制造方法包括：将0.001〜50质量份的金属化合物（B）中的至少一种选自金属 复合物（B1）和金属卤化物（B2），相对于100质量份的热塑性树脂（A）为0.001〜30质量份的聚亚烷基二醇化合物（C）。 并在100〜320℃的温度下加热。

公开(公告)号：US20120214921A1

公开(公告)日：2012-08-23

申请号：US13504492

申请日：2010-10-26

申请人： Hiroshi Niino

发明人： Hiroshi Niino

IPC分类号： C08K5/07

CPC分类号： C09K11/06 ,  C08J3/201 ,  C08J3/203 ,  C08K5/0091 ,  C08K5/07 ,  C09K2211/186 ,  C08L33/12

摘要： Disclosed is a production method of a thermoplastic resin composition comprising: compounding 0.001 to 50 parts by mass of a metal complex (B) with respect to 100 parts by mass of a thermoplastic resin (A), and kneading it under a condition of a kneading temperature of 225 to 300° C. and of a kneading time of 0.5 to 20 minutes, wherein a metal of the metal complex (B) is a metal except for zinc; a molded body obtained by molding the thermoplastic resin composition which is obtained by the production method; and a light emission body using the molded body.

摘要翻译： 本发明公开了一种热塑性树脂组合物的制造方法，其特征在于，相对于100质量份热塑性树脂（A），配合0.001〜50质量份的金属络合物（B），在捏合条件下进行混炼 温度为225〜300℃，捏合时间为0.5〜20分钟，金属络合物（B）的金属除锌以外的金属; 通过将通过该制造方法获得的热塑性树脂组合物成型而得到的成型体; 以及使用该成形体的发光体。