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    Polymerizable composition and process for producing optical resin comprising the same
    1.
    发明授权
    Polymerizable composition and process for producing optical resin comprising the same 有权
    聚合性组合物及其制造方法

    公开(公告)号：US06365707B1

    公开(公告)日：2002-04-02

    申请号：US09584105

    申请日：2000-05-31

    申请人： Akinori Ryu ,  Seiichi Kobayashi ,  Hiroyuki Morijiri ,  Chitoshi Shimakawa ,  Koju Okazaki ,  Yoshinobu Kanemura ,  Nobuo Kawato

    发明人： Akinori Ryu ,  Seiichi Kobayashi ,  Hiroyuki Morijiri ,  Chitoshi Shimakawa ,  Koju Okazaki ,  Yoshinobu Kanemura ,  Nobuo Kawato

    IPC分类号： C08G7500

    CPC分类号： C08G75/08 ,  C08G59/302 ,  C08G65/22 ,  G02B1/04 ,  C08L81/00

    摘要： A polymerizable composition according to the present invention is characterized by that it comprises a compound (a) having at least one structure represented by the following formula (1): wherein R1 is a divalent hydrocarbon group having 1 to 10 carbon atoms, R2, R3 and R4 each independently represents a hydrocarbon group having 1 to 10 carbon atoms or a hydrogen atom; X stands for an S or O atom and the average number of S atom is at least 50% based on the total number of S and O atoms which consist of the three membered ring; and X′ is —S— or —O—, at least two compounds (b) having a tertiary amino group substituted with aliphatic and/or aromatic group(s), which are each different in catalytic activity as a polymerization catalyst, with the proviso that the ratio of the total of the tertiary amino groups in the at least two compounds (b) to the episulfide groups in compound (a) is in the range of 0.0001 to 0.02 in terms of a molar ratio of amino/episulfide functional group.

    摘要翻译： 根据本发明的可聚合组合物的特征在于其包含具有至少一个由下式（1）表示的结构的化合物（a）：其中R1是具有1-10个碳原子的二价烃基，R2，R3 R 4各自独立地表示碳原子数1〜10的烃基或氢原子。 基于由三元环组成的S和O原子的总数，X表示S或O原子，S原子的平均数至少为50％ X'为-S-或-O-，至少两个具有被脂肪族和/或芳香族基团取代的叔氨基的化合物（b），它们各自作为聚合催化剂的催化活性各不相同，与 条件是化合物（a）中至少两种化合物（b）中的叔胺基团与环硫化物基团的总量的比例以氨基/环硫化物官能团的摩尔比计在0.0001至0.02的范围内 。

    Polymerizable composition
    3.
    发明授权
    Polymerizable composition 有权
    可聚合组合物

    公开(公告)号：US06458917B2

    公开(公告)日：2002-10-01

    申请号：US09918549

    申请日：2001-08-01

    申请人： Hiroyuki Morijiri ,  Seiichi Kobayashi ,  Koju Okazaki ,  Chitoshi Shimakawa ,  Akinori Ryu ,  Yoshinobu Kanemura

    发明人： Hiroyuki Morijiri ,  Seiichi Kobayashi ,  Koju Okazaki ,  Chitoshi Shimakawa ,  Akinori Ryu ,  Yoshinobu Kanemura

    IPC分类号： C08G7508

    CPC分类号： C08G75/08 ,  C07D303/34 ,  C07D331/02 ,  C08G59/302 ,  C08G65/22 ,  G02B1/04 ,  C08L81/00

    摘要： An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.

    摘要翻译： 通过固化包含具有至少一个分子内二硫键的（硫代）环氧化合物的可聚合组合物制备的光学树脂显示相当高的折射率，同时保持良好的光学性能和高的阿贝数。 此外，上述可聚合组合物中加入伯胺和/或仲胺作为泛黄抑制剂，其比例为胺的总NH 2和NH基总数的0.001至0.5，硫代环氧和环氧基的总摩尔数 具有至少一个分子内二硫键的（硫代）环氧化合物中的基团可以提供透明树脂，其中在保持高折射率的同时充分防止与其相关的黄变和降低的耐热性。

    Polymerizable composition
    4.
    发明授权
    Polymerizable composition 有权
    可聚合组合物

    公开(公告)号：US06300464B2

    公开(公告)日：2001-10-09

    申请号：US09745448

    申请日：2000-12-26

    申请人： Hiroyuki Morijiri ,  Seiichi Kobayashi ,  Koju Okazaki ,  Chitoshi Shimakawa ,  Akinori Ryu ,  Yoshinobu Kanemura

    发明人： Hiroyuki Morijiri ,  Seiichi Kobayashi ,  Koju Okazaki ,  Chitoshi Shimakawa ,  Akinori Ryu ,  Yoshinobu Kanemura

    IPC分类号： C08G7508

    CPC分类号： C08G75/08 ,  C07D303/34 ,  C07D331/02 ,  C08G59/302 ,  C08G65/22 ,  G02B1/04 ,  C08L81/00

    摘要： An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.

    摘要翻译： 通过固化包含具有至少一个分子内二硫键的（硫代）环氧化合物的可聚合组合物制备的光学树脂显示相当高的折射率，同时保持良好的光学性能和高的阿贝数。 此外，上述可聚合组合物中加入伯胺和/或仲胺作为泛黄抑制剂，其比例为胺的总NH 2和NH基总数的0.001至0.5，硫代环氧和环氧基的总摩尔数 具有至少一个分子内二硫键的（硫代）环氧化合物中的基团可以提供透明树脂，其中在保持高折射率的同时充分防止与其相关的黄变和降低的耐热性。