Abstract:
A ceramic hard layer is formed on the surface of a formed article by subjecting the formed article of a substantially amorphous alloy to a heat treatment in an atmosphere containing a reactive gas under the conditions of temperature and time falling within the amorphous region in the isothermal transformation curve (TTT curve) of the alloy. The heat treatment is carried out, for instance, in an atmosphere containing oxygen and/or nitrogen at a concentration of not less than 1 ppm or in the air at a temperature of not less than the lowest temperature required for the oxidation or nitriding reaction of at least one component element of the matrix material. By this heat treatment, it is possible to produce a ceramic hard layer on the surface of the article in such a manner that the content of oxide and/or nitride gradually decreases in the depth direction.