Process for the preparation of 2-oxoiminophenylacetonitrile
    2.
    发明授权
    Process for the preparation of 2-oxoiminophenylacetonitrile 失效
    2-氧代亚氨基苯基乙腈的制备方法

    公开(公告)号:US4233233A

    公开(公告)日:1980-11-11

    申请号:US35755

    申请日:1979-05-03

    CPC分类号: C07C253/30

    摘要: In the preparation of 2-oximinophenylacetonitrile by reacting benzyl cyanide with an alkyl nitrite in the presence of a base, the improvement which comprises employing an inorganic base as the base and effecting the reaction in an aqueous solution of an alcohol. Advantageously the reaction mixture, consisting of an alcohol, an aqueous solution of an inorganic base and benzyl cyanide, is circulated by means of a pump and thereby operates an injector which sucks in the alkyl nitrite. Desirably the alkyl nitrite is a C.sub.1 -C.sub.5 alkyl nitrate having the same alkyl radical as the alcohol, about 1.05 to 1.15 moles of alkyl nitrite are employed per mole of benzyl cyanide, the inorganic alkali is an aqueous solution of potassium hydroxide or sodium hydroxide, the molar ratio of benzyl cyanide to potassium or sodium hydroxide is about 1:1.1-1.3, the reaction is effected at about 20.degree. to 40.degree. C., and after the reaction has ended the alkaline reaction mixture is acidified with hydrochloric acid or sulphuric acid at a temperature above about 40.degree. C. and the 2-oximinophenylacetonitrile formed is separated off.

    摘要翻译: 在碱存在下,使苄基氰与亚硝酸烷基酯反应制备2-肟基苯基乙腈,其改进在于使用无机碱作为碱,并在醇的水溶液中进行反应。 有利的是,由醇组成的反应混合物,无机碱和苄基氰的水溶液通过泵循环,从而操作吸入亚硝酸烷基酯的注射器。 理想地,亚硝酸烷基酯是具有与醇相同的烷基的C1-C5烷基硝酸盐,每摩尔苄基氰使用约1.05-1.15摩尔亚硝酸烷基酯,无机碱是氢氧化钾或氢氧化钠的水溶液, 苄基氰与氢氧化钾或氢氧化钠的摩尔比为约1:1.1-1.3,反应在约20℃至40℃进行,反应结束后,碱性反应混合物用盐酸或硫酸 在高于约40℃的温度下分离出酸和形成的2-肟基苯基乙腈。

    Method and apparatus for radial expansion of rings
    4.
    发明授权
    Method and apparatus for radial expansion of rings 失效
    环的径向膨胀的方法和装置

    公开(公告)号:US4688407A

    公开(公告)日:1987-08-25

    申请号:US779820

    申请日:1985-09-25

    申请人: Horst Schroder

    发明人: Horst Schroder

    IPC分类号: B21H1/06 B21J13/08 B21D3/14

    CPC分类号: B21H1/06

    摘要: In a method for the radial expansion of rings, in particular by means of rolling tools, it is provided in accordance with the invention that the radial surfaces and the end faces of the ring that is to be machined are machined in alternation using the same pair of tools. The apparatus for performing the method includes a ring rolling machine in which the ring that is to be formed rests on a support that is pivotable by 90.degree. to alternatively bring the radial surfaces and the end faces of the ring into engagement with the tools.

    摘要翻译: 在环的径向膨胀的方法中,特别是通过滚动工具,根据本发明,提供了要被加工的环的径向表面和端面使用相同的对进行交替加工 的工具。 用于执行该方法的装置包括一个环形滚轧机,其中待形成的环座位于可枢转90°的支撑件上,以便使该环的径向表面和端面与工具接合。