公开(公告)号：US06403225B1

公开(公告)日：2002-06-11

申请号：US09438146

申请日：1999-11-10

申请人： Ikuo Narisawa ,  Makoto Takeishi ,  Heihachi Murase ,  Toshihiro Takekawa ,  Yasuaki Kai ,  Tetsuro Tayu

发明人： Ikuo Narisawa ,  Makoto Takeishi ,  Heihachi Murase ,  Toshihiro Takekawa ,  Yasuaki Kai ,  Tetsuro Tayu

IPC分类号： B32B1706

CPC分类号： C03C17/009 ,  B32B17/10018 ,  B32B17/10165 ,  B32B17/10688 ,  Y10T428/31612 ,  Y10T428/31663

摘要： The invention relates to an article superior in slipping a waterdrop down a surface of the article. The article has a substrate; and a functional layer formed on a surface of the substrate. The functional layer is chemically bonded to the surface of the substrate through siloxane-bonding. The article is prepared by a method including: (a) dissolving in a solvent (1) a silicone that is one of a first silicone having at an end a hydrolyzable functional group and a second silicone having at an end a hydrolyzable functional group and at the other end a fluoroalkyl group, (2) an acid, and (3) water, thereby to prepare a mixed liquid; (b) applying the mixed liquid to the surface of the substrate, thereby to form thereon a precursory layer; and (c) drying the precursory layer into the functional layer. In the preparation of the article, a silica precursor sol is optionally added to the mixed liquid. Alternatively, a combination of a silica precursor sol and a fluoroalkylsilane having at its end a hydrolyzable functional group is optionally added to the mixed liquid. Furthermore, an underlayer made from a hydrolyzable silicon compound may be provided between the substrate and the functional layer.

摘要翻译： 本发明涉及一种将水滴从制品的表面滑下来的优点。 该物品具有底物; 以及形成在所述基板的表面上的功能层。 功能层通过硅氧烷键化学键合到基板的表面。 该制品通过以下方法制备：（a）将溶剂（1）溶解在作为末端具有可水解官能团的第一硅酮中的硅酮和末端具有可水解官能团的第二硅酮， 另一端为氟烷基，（2）酸和（3）水，由此制备混合液; （b）将混合液体施加到基板的表面，由此在其上形成前兆层; 和（c）将前体层干燥成功能层。 在制品中，任选地将二氧化硅前体溶胶加入到混合液中。 或者，任选地将二氧化硅前体溶胶和其末端具有可水解官能团的氟代烷基硅烷的组合加入到混合液中。 此外，可以在基板和功能层之间设置由可水解硅化合物制成的底层。