公开(公告)号：US5196487A

公开(公告)日：1993-03-23

申请号：US712279

申请日：1991-06-10

申请人： Hideo Kogure ,  Heihachi Murase ,  Naozumi Iwasawa

发明人： Hideo Kogure ,  Heihachi Murase ,  Naozumi Iwasawa

IPC分类号： C07F7/18 ,  C08F2/46 ,  C08F299/00 ,  C09D5/08 ,  C09D183/07 ,  C09D183/08

CPC分类号： C07F7/1836 ,  C08F299/00 ,  C09D183/08 ,  C09D5/08

摘要： A corrosion preventive resin having in the molecule at least one chelate forming group selected from among groups represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are each a hydrogen atom or alkyl having 1 to 8 carbon atoms, and groups represented by teh general formula ##STR2## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and are each a hydrogen atom, alkyl having 1 to 8 carbon atoms or a group forming a bivalent o-phenylene group along with two carbon atoms attached thereto. A photopolymerizable composition which includes (a) a resin having in the molecule at least one mole of polymerizable double bond per 1000 g of the resin and having per molecule at least one chelate forming group selected from among the groups represented by formula (II) and formula (III), and (b) a photopolymerization initiator is also disclosed.

摘要翻译： 一种防腐树脂，其在分子中具有至少一种螯合形成基团，其选自由式（I）表示的基团，其中R 1和R 2相同或不同，各自为氢原子或具有1至8个碳原子的烷基 原子和由通式（II）表示的基团，其中R 3，R 4，R 5和R 6相同或不同，各自为氢原子，具有1至8个碳原子的烷基或形成二价o- 亚苯基以及与其连接的两个碳原子。 一种可光聚合组合物，其包含（a）分子中每1000克所述树脂具有至少1摩尔可聚合双键并且每分子具有选自式（II）表示的基团中的至少一种螯合形成基团和 式（III）和（b）光聚合引发剂也被公开。

公开(公告)号：US4636324A

公开(公告)日：1987-01-13

申请号：US712724

申请日：1985-03-18

申请人： Heihachi Murase ,  Kiyoshi Nanishi

发明人： Heihachi Murase ,  Kiyoshi Nanishi

IPC分类号： C09D183/04 ,  C09K3/18 ,  C09D5/20

CPC分类号： C09D183/04 ,  C08K3/0075 ,  C08K5/01 ,  C08K5/09

摘要： The present invention provides: a composition for use in preventing the formation of ice comprising (A) organopolysiloxane, (B) alkali metal compound and (C) liquid or solid paraffin; a method for preventing the formation of ice by applying the composition to the surface of an object; and another method for preventing the formation of ice by applying a primer containing a silane coupling agent to the surface of an object and applying the composition to the primer coat formed.

摘要翻译： 本发明提供：用于防止形成冰的组合物，其包含（A）有机聚硅氧烷，（B）碱金属化合物和（C）液体或固体石蜡; 一种通过将组合物施用到物体的表面来防止形成冰的方法; 以及另一种通过将含有硅烷偶联剂的底漆施用到物体表面并将组合物施加到所形成的底漆涂层来防止形成冰的方法。

公开(公告)号：US4305994A

公开(公告)日：1981-12-15

申请号：US177509

申请日：1980-08-12

申请人： Heihachi Murase

发明人： Heihachi Murase

IPC分类号： B05D3/10 ,  C09D5/46 ,  B05D1/36

CPC分类号： B05D3/102 ,  B05D3/10 ,  B05D7/54 ,  B05D2202/00 ,  B05D2451/00 ,  Y10T428/31529 ,  Y10T428/31678 ,  Y10T428/31681

摘要： In a process for forming a multilayer coated film which comprises coating a multilayer coat-forming paint on the surface of a substrate to form a multilayer coated film thereon, the improvement wherein prior to the coating, the surface of the substrate is treated with a solution containing at least one onium compound selected from compounds of formulae (I) and (II) below ##STR1## wherein Y represents a nitrogen, phosphorus or arsenic atom, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are identical or different and each represents a hydrogen atom or an organic group having not more than 8 carbon atoms, and X.sub..crclbar. represents an anion.

摘要翻译： 在形成多层涂膜的方法中，其包括在基材表面上涂覆多层涂层涂料以在其上形成多层涂膜，其改进在于，在涂布之前，用溶液处理基材表面 含有至少一种选自下述式（I）和（II）的化合物的鎓化合物，其中Y表示氮，磷或砷原子，R 1，R 2，R 3和R 4相同或不同，各自表示氢原子 或不大于8个碳原子的有机基团，X（ - ）表示阴离子。

公开(公告)号：US5445871A

公开(公告)日：1995-08-29

申请号：US279066

申请日：1994-07-22

申请人： Heihachi Murase ,  Tsutomu Norimatsu ,  Masao Ogawa ,  Naoya Haruta

发明人： Heihachi Murase ,  Tsutomu Norimatsu ,  Masao Ogawa ,  Naoya Haruta

IPC分类号： C08J7/04 ,  B32B7/02

CPC分类号： C08J7/045 ,  C08J7/047 ,  C08J2483/00 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/265 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31667

摘要： A surface-modified plastic plate for use in optical disc bases, windows of aircrafts, automobiles or of architectural structures, solar cell receptors, liquid crystal display panels and protective sheet of computer touch panels, which comprises a laminate consisting of a plastic substrate; a cured film of an actinic ray-curable primer composition, said cured film formed onto a surface of the plastic substrate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.1 .mu.m or more but less than 1.0 .mu.m; and a surface-modified plastic plate for use in windows, preferably windows of aircrafts, automobiles and architectural structures, which comprises a laminate consisting of a plastic plate, preferably comprising a plastic selected from polymethyl methacrylate polymer and polycarbonate in the case of the window of the aircraft; a cured film of a heat-curable primer composition, said cured film being formed on a surface of the plastic plate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.25 .mu.m or more but less than 1.0 .mu.m.

摘要翻译： 用于光盘基座，飞机窗口，汽车或建筑结构的表面改性塑料板，太阳能电池接收器，液晶显示面板和计算机触摸面板的保护片，其包括由塑料基板组成的层压板; 光固化性底漆组合物的固化膜，所述固化膜形成在塑料基板的表面上，膜厚为0.1〜10μm; 以及通过物理沉积工艺形成在固化膜上并具有0.1μm以上且小于1.0μm的厚度的无机材料层; 以及用于窗户，优选飞机，汽车和建筑结构的窗户的表面改性塑料板，其包括由塑料板组成的层压板，该塑料板优选地包括选自聚甲基丙烯酸甲酯聚合物和聚碳酸酯的塑料，在窗口 飞机; 热固性底漆组合物的固化膜，所述固化膜形成在所述塑料板的表面上，膜厚度为0.1-10μm; 以及通过物理沉积工艺在固化膜上形成的厚度为0.25μm以上且小于1.0μm的无机材料层。

公开(公告)号：US4246368A

公开(公告)日：1981-01-20

申请号：US903260

申请日：1978-05-05

申请人： Heihachi Murase

发明人： Heihachi Murase

IPC分类号： C09D5/46 ,  C09D157/00 ,  C08L63/00 ,  C08L33/06 ,  C08L33/14 ,  C08L67/00

CPC分类号： C09D157/00 ,  Y10S524/904 ,  Y10S525/934

摘要： A powder coating composition for forming multi layer coatings comprising:(1) at least one of finely divided thermosetting addition copolymers having a glass transition temperature of 35.degree. to 75.degree. C. and comprising as comonomers a wt. % of a hardness imparting monomer and b wt. % of a softness imparting monomer based on the copolymer wherein a+b.ltoreq.60, b.ltoreq.a and b.ltoreq.20, and(2) at least one of finely divided thermosetting resinous materials having incompatibility or low compatibility with the copolymer and a substantially greater surface tension than the copolymer when melted at the same temperature and substantially differing from the copolymer in composite parameter.

摘要翻译： 一种用于形成多层涂层的粉末涂料组合物，包括：（1）至少一种细分热固性加成共聚物，其玻璃化转变温度为35-75℃，并且包含共聚单体wt％ ％的硬度赋予单体和bwt。 ％的基于共聚物的柔软性赋予单体，其中a +b≤60，b≤a和b≤20，和（2）至少一种细分散的热固性树脂材料，其具有不相容性或与 该共聚物和当在相同温度下熔融并且与复合参数中的共聚物基本不同时，共聚物具有显着更大的表面张力。

公开(公告)号：US5188750A

公开(公告)日：1993-02-23

申请号：US790088

申请日：1991-11-13

申请人： Hideo Kogure ,  Heihachi Murase ,  Koichi Tamura

发明人： Hideo Kogure ,  Heihachi Murase ,  Koichi Tamura

IPC分类号： C09D143/04 ,  C09D183/04 ,  C09D183/14 ,  C09K3/18

CPC分类号： C09K3/185 ,  C09D143/04 ,  C09D183/04 ,  C09D183/14

摘要： This invention provides:(A) an anti-icing composition comprising a silicone resin which is at least one condensate selected from the group consisting of:(i) a condensate of an alkoxydimethylsiloxane compound represented by the formula ##STR1## wherein R.sub.1 l is a methyl group or an ethyl group, A is an oxygen atom, an ethylene group or a 1,3-propylene group, a is an integer of 5 to 150, b and e are different or the same and each represent an integer of 1 to 3, c is an integer of 3-b and d is an integer of 3-e,(ii) a condensate of the compound of the formula (I) and an alkoxysilane compound represented by the formula(R.sub.3)h--Si--(OR.sub.2)j (II) wherein R.sub.2 is a methyl group or an ethyl group, R.sub.3 is an alkyl group having 1 to 8 carbon atoms, h is an integer of 0 to 3 and j is an integer of 4-h,(iii) a condensate of the compound of the formula (I) and a dihydroxydimethylsiloxane compound represented by the formula ##STR2## wherein k is an integer of 10 to 200, and (iv) a condensate of the compound of the formula (I), the alkoxysilane compound of the formula (II) and the dihydroxydimethylsiloxane compound of the formula (III); and(B) a method of preventing icing which comprises applying to an article an aerosol comprising the foregoing anti-icing composition and a propellant.

摘要翻译： 本发明提供：（A）防结冰组合物，其包含硅氧烷树脂，其为至少一种选自下列的缩合物：（i）由式（I）表示的烷氧基二甲基硅氧烷化合物的缩合物，其中R1 l是甲基或乙基，A是氧原子，亚乙基或1,3-亚丙基，a是5〜150的整数，b和e不同或相同，各自表示整数 1〜3的整数，c为3-b的整数，d为3-e的整数，（ii）式（I）的化合物与式（R3）表示的烷氧基硅烷化合物的缩合物，h- Si（OR 2）j（II）其中R 2为甲基或乙基，R 3为碳原子数1〜8的烷基，h为0〜3的整数，j为4〜 （iii）式（I）化合物和由式（III）表示的二羟基二甲基硅氧烷化合物的缩合物，其中k为10至200的整数，和（iv）t的缩合物 式（I）的化合物，式（II）的烷氧基​​硅烷化合物和式（III）的二羟基二甲基硅氧烷化合物; 和（B）防结冰的方法，其包括向制品施加包含前述防冰组合物和推进剂的气溶胶。

公开(公告)号：US5035934A

公开(公告)日：1991-07-30

申请号：US436997

申请日：1989-11-15

申请人： Takeshi Tomiyama ,  Sadaaki Hashimoto ,  Heihachi Murase

发明人： Takeshi Tomiyama ,  Sadaaki Hashimoto ,  Heihachi Murase

IPC分类号： B32B27/08 ,  C07C265/00 ,  C08G18/28 ,  C08G18/61 ,  C08G18/62 ,  C08G18/71 ,  C08G18/77 ,  C08L27/12 ,  C08L87/00 ,  C09J7/02 ,  C09K3/18

CPC分类号： C08G18/289 ,  C08G18/6279 ,  C08G18/718 ,  C08G18/778 ,  C09J7/025 ,  C09J2205/114 ,  C09J2427/006 ,  C09J2451/006 ,  C09J2475/006 ,  C09J2483/006 ,  Y10T428/1429 ,  Y10T428/3154 ,  Y10T428/31544

摘要： Disclosed is an adhesive sheet for preventing icing, the sheet being characterized in that the sheet comprises a release sheet (1), a pressure-sensitive adhesive layer (2) formed on the sheet (1), a base sheet (3) adhered to the layer (2) and an anti-icing layer (4) formed on the base sheet (3) and that the anti-icing layer (4) is formed from a composition (A) or a composition (B), the composition (A) consisting essentially of:(a) a copolymer having hydroxyl, or hydroxyl and other reactive group and comprising an essential monomer components a fluoroolefin and a vinyl monomer having hydroxyl and copolymerizable with the fluoroolefin,(b) a silicone compound represented by the formula ##STR1## wherein n is an integer of 6 to 300, k is an integer of 0 to 6, h is 0 or 1, m is an integer of 0 to 6, j is 1 or 2, and Y is hydroxyl, carboxyl, epoxy, or a monovalent or bivalent groups containing one or two free isocyanate groups, and(c) a polyisocyanate compound, and the composition (B) consisting essentially of:(d) a graft copolymer prepared by reacting the component (a) and the component (b), and(c) the polyisocyanate compound.

摘要翻译： 公开了一种用于防止结冰的粘合片，其特征在于，片材包括剥离片（1），形成在片材（1）上的压敏粘合剂层（2），粘合到片材 所述层（2）和形成在所述基片（3）上的防冰层（4）和所述防结冰层（4）由组合物（A）或组合物（B）形成，所述组合物（ A）基本上由以下组成：（a）具有羟基或羟基和其它反应性基团并且包含必需单体组分的共聚物，其中氟烯烃和具有羟基的乙烯基单体和可与氟烯烃共聚的乙烯基单体，（b）由式 （I）其中n为6〜300的整数，k为0〜6的整数，h为0或1，m为0〜6的整数，j为1或2，Y为羟基 ，羧基，环氧基或含有一个或两个游离异氰酸酯基团的一价或二价基团，和（c）多异氰酸酯化合物，组合物（B）c 主要包括：（d）通过使组分（a）和组分（b）反应制备的接枝共聚物，和（c）多异氰酸酯化合物。

公开(公告)号：US5032641A

公开(公告)日：1991-07-16

申请号：US380595

申请日：1989-06-26

申请人： Kiyoshi Nanishi ,  Hideo Kogure ,  Heihachi Murase

发明人： Kiyoshi Nanishi ,  Hideo Kogure ,  Heihachi Murase

IPC分类号： C08L33/16 ,  C08L43/04 ,  C09D133/16 ,  C09D143/04

CPC分类号： C09D133/16 ,  C09D143/04 ,  C08L33/16 ,  C08L43/04

摘要： A water-repellant film-forming composition comprisinga mixture of(a) a (co)polymer of 5 to 100% by weight of a specific fluoroalkyl group-containing (meth)acrylic monomer and 0 to 95% by weight of an unsaturated monomer co-polymerizable with the fluoroalkyl group-containing (meth)acrylic monomer, and(b) a copolymer of 0.1 to 75% by weight of a specific silicon-containing polymerizable unsaturated monomer and 25 to 99.9% by weight of an unsaturated monomer copolymerizalbe with the silicon-containing polymerizable unsaturated monomer, andfine silica particles having an average particle diameter of not more than 5 micrometers, in specified amounts.

公开(公告)号：US4448919A

公开(公告)日：1984-05-15

申请号：US430018

申请日：1982-09-30

申请人： Heihachi Murase

发明人： Heihachi Murase

IPC分类号： C09D183/04 ,  C08L83/04

CPC分类号： C09K3/185 ,  C09D183/04 ,  C09K3/18

摘要： A composition for use in preventing the formation of ice comprising:(A) organopolysiloxane resin represented by the structural unit ##STR1## wherein R represents hydrogen atom or monovalent organic group attached to the silicon atom by a carbon-to-silicon bond, R' represents hydrogen atom, C.sub.1 to C.sub.20 alkyl group, aryl group, oxime residue, n and m are each 0 or an integer of up to 4, and n plus m is 0 or an integer of less than 4, and(B) alkali metal compound represented by the formulaMa.sym.X.crclbar. wherein M represents alkali metal selected from Li, Na and K, X represents inorganic or organic acid group or hydroxyl group and a is an integer of 1 to 4.

摘要翻译： 用于防止冰层形成的组合物，其包含：（A）由结构单元“IMAGE”表示的有机聚硅氧烷树脂，其中R表示氢原子或通过碳 - 硅键与硅原子连接的一价有机基团，R' 表示氢原子，C1〜C20烷基，芳基，肟基，n和m分别为0或4以下的整数，n加上m为0或小于4的整数，（B）碱金属 式中M（+）X（ - ）表示的化合物，其中M表示选自Li，Na和K的碱金属，X表示无机或有机酸基或羟基，a表示1〜4的整数。

公开(公告)号：US4345004A

公开(公告)日：1982-08-17

申请号：US255663

申请日：1981-04-20

申请人： Nobuyoshi Miyata ,  Heihachi Murase

发明人： Nobuyoshi Miyata ,  Heihachi Murase

IPC分类号： C09D163/02 ,  B05D7/14 ,  B05D7/24 ,  B32B15/085 ,  C08J5/12 ,  C09D5/08 ,  C09D123/02 ,  B32B15/08 ,  B32B27/38

CPC分类号： C08J5/124 ,  B05D7/148 ,  C08J2323/00 ,  Y10T428/31522 ,  Y10T428/31529 ,  Y10T428/31913

摘要： A process for forming an olefinic resin film on a metal substrate, which comprises[A] forming a multilayer coated film consisting of an olefinic resin film as a surface layer portion and a cured epoxy resin film as an under layer portion on a metallic substrate by a single coating operation using a multilayer film-forming coating composition comprising as main resinous components(a) a solid powder containing an olefinic resin having a melt index of 0.3 to 80 g/10 minutes,(b) a solid powder containing a polar group-containing modified olefinic resin having a melt index of 0.3 to 80 g/10 minutes, and(c) a film-forming resinous material comprising an epoxy resin having a number average molecular weight of about 350 to about 4,000 and an epoxy equivalent of 150 to 3,800 and a curing agent therefor, and[B] then heat-bonding an olefinic resin lining material to the olefinic resin surface layer of the multilayer coated film.

摘要翻译： 一种在金属基材上形成烯烃树脂膜的方法，其包括：[A]在金属基材上形成由作为表层部分的烯烃树脂膜和固化的环氧树脂膜作为下层部分的多层涂膜，由 使用多层成膜涂料组合物的单次涂布操作，其包含主要树脂组分（a）含有熔体指数为0.3至80g / 10分钟的烯烃树脂的固体粉末，（b）含极性基团的固体粉末 的熔融指数为0.3〜80g / 10分钟的改性烯烃树脂，（c）含有数均分子量为约350〜约4000，环氧当量为150的环氧树脂的成膜树脂材料 至3800，其固化剂，[B]然后将烯烃树脂衬里材料热粘合到多层涂膜的烯烃树脂表面层。