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公开(公告)号:US11258100B2
公开(公告)日:2022-02-22
申请号:US16654920
申请日:2019-10-16
Applicant: Industrial Technology Research Institute
Inventor: Hsiao-Wen Huang , Chun-Tsung Hsu , Che-Wei Chang , Ping-I Pan , Chien-Chih Chiang , Chang-Chung Yang
IPC: H01M10/0568 , H01M10/0567 , H01M10/054 , C07F5/02 , C07D233/58
Abstract: An electrolyte composition and a metal-ion battery employing the same are provided. The electrolyte composition includes a metal chloride, an imidazolium salt of Formula (I), an alkali halide, and an oxalate-containing borate wherein R1, R2, and R3 are independently C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C1-8 alkoxy, C2-8 alkoxyalkyl, or C1-8 fluoroalkyl; and X− is F−, Cl−, Br−, or I−. The metal chloride is aluminum chloride, iron chloride, zinc chloride, copper chloride, manganese chloride, chromium chloride, or a combination thereof.
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公开(公告)号:US11283110B2
公开(公告)日:2022-03-22
申请号:US16706961
申请日:2019-12-09
Applicant: Industrial Technology Research Institute
Inventor: Che-Wei Chang , Chun-Tsung Hsu , Hsiao-Wen Huang , Ping-I Pan , Chien-Chih Chiang , Chang-Chung Yang
IPC: H01M6/04 , H01M10/0568 , H01M10/0567 , H01M4/583 , H01M4/48 , H01M4/38 , H01M4/36 , H01M4/02
Abstract: An electrolyte composition and a metal-ion battery employing the same are provided. The electrolyte composition includes a metal salt of Formula (I), an ionic liquid, and an additive MiXj Formula (I), wherein M can be lithium ion, sodium ion, potassium ion, beryllium ion, magnesium ion, calcium ion, scandium ion, yttrium ion, titanium ion, zirconium ion, hafnium ion, vanadium ion, niobium ion, tantalum ion, chromium ion, molybdenum ion, tungsten ion, manganese ion, technetium ion, rhenium ion, iron ion, ruthenium, osmium ion, cobalt ion, rhodium ion, iridium ion, nickel ion, palladium ion, platinum ion, copper ion, silver ion, gold ion, zinc ion, cadmium ion, mercuric ion, indium ion, thallium ion, tin ion, lead ions, arsenic ions, antimony ions, bismuth ion, gallium ion, or aluminum ion; X− can be F−, Cl−, Br−, I−, BF4, PF6−, [(CF3SO2)2N]−, CF3SO3−, NO3−, CH3CO2−, SO42−, C2O42−, or [B(C2O4)2]−; and i is 1, 2, 3, 4, 5, or 6; and j is 1, 2, 3, 4, 5, or 6. The additive includes a substituted or unsubstituted C5-C30 nitrogen-containing heterocyclic compound.
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