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1.发明授权Flexible method for the joint production of (i) formic acid, (ii) a carboxylic acid comprising at least two carbon atoms and/or the derivatives thereof, and (iii) a carboxylic acid anhydride 有权用于联合生产（i）甲酸，（ii）含有至少两个碳原子的羧酸和/或其衍生物的柔性方法，和（iii）羧酸酐公开(公告)号：US07253316B2
公开(公告)日：2007-08-07
申请号：US10532561
申请日：2003-10-21
CPC分类号： C07C51/54 , C07C51/09 , C07C51/56 , Y02P20/582 , C07C53/02 , C07C57/04 , C07C53/124 , C07C53/122 , C07C63/313 , C07C53/12
摘要： Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).
摘要翻译： 公开了一种联合生产（i）甲酸（III）的方法; （ii）包含至少两个碳原子（II）和/或其衍生物的羧酸; 和（iii）羧酸酐（VII）。 根据所述方法，通过含有至少两个碳原子（II）的羧酸，（a）甲酸酯（I）与甲酸（III）和相应的羧酸酯（IV）进行酯交换; （b）步骤（a）中形成的羧酸酯（IV）的至少一部分被羰基化以获得羧酸酐（V）; 和（c）步骤（b）中形成的羧酸酐（V）的至少一部分通过羧酸（VI）进一步脱水以形成羧酸酐（VII）和羧酸（ II）。
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2.发明申请Postcrosslining of Water Absorbing Polymers With Cyclic Carbamates and/or Cyclic Ureas 有权具有循环氨基甲酸酯和/或环状尿素的吸水性聚合物的交联公开(公告)号：US20080171837A1
公开(公告)日：2008-07-17
申请号：US11630949
申请日：2005-07-28
申请人： Kai Michael Exner , Thomas Daniel , Mark Elliott , Ulrich Riegel
发明人： Kai Michael Exner , Thomas Daniel , Mark Elliott , Ulrich Riegel
IPC分类号： C08G69/48
CPC分类号： A61L15/60
摘要： Disclosed is a process for postcrosslinking a water absorbing polymer by the polymer being treated with at least one postcrosslinker and postcrosslinked and dried during or after the treatment by raising the temperature, the at least one postcrosslinker being a cyclic carbamate or a cyclic urea, wherein the cyclic carbamate or the cyclic urea was obtained by reacting respectively an aminoalcohol or a diamine with a cyclic carbonate.
摘要翻译： 公开了一种通过用至少一种后交联剂处理的聚合物后交联吸水聚合物的方法，并且在处理期间或之后通过升高温度进行后交联和干燥，所述至少一种后交联剂是环状氨基甲酸酯或环脲，其中 通过使氨基醇或二胺与环状碳酸酯反应，得到环状氨基甲酸酯或环状脲。
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3.发明授权公开(公告)号：US07754822B2
公开(公告)日：2010-07-13
申请号：US10565050
申请日：2004-07-07
申请人： Thomas Daniel , Ulrich Riegel , Mark Elliott , Ubbo von Oehsen , Kai Michael Exner , Klemens Massonne
发明人： Thomas Daniel , Ulrich Riegel , Mark Elliott , Ubbo von Oehsen , Kai Michael Exner , Klemens Massonne
IPC分类号： C08F8/32
CPC分类号： C08J3/245 , C08F8/30 , C08J2300/14 , Y10S493/96 , C08F20/00
摘要： A process for postcrosslinking a water-absorbing polymer comprises said polymer being treated with a postcrosslinker and, during or after said treating, being postcrosslinked and dried by temperature elevation, said postcrosslinker being a compound of the formula I where R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently hydrogen, C1-C12-alkyl, C2-C12-alkenyl or C6-C12-aryl, wherein C1-C12-alkyl, C2-C12-alkenyl or C6-C12-aryl may be halogen substituted. The liquid-absorbing polymers are useful in hygiene articles and packaging materials.
摘要翻译： 用于后吸附聚合物的方法包括用后交联剂处理的所述聚合物，并且在所述处理期间或之后，通过温度升高进行后交联和干燥，所述后交联剂是式I的化合物，其中R 1，R 2，R 3，R 4 ，R 5，R 6，R 7，R 8和R 9各自独立地为氢，C 1 -C 12 - 烷基，C 2 -C 12 - 烯基或C 6 -C 12 - 芳基，其中C 1 -C 12 - 烷基，C 2 -C 12 - 烯基或C 6 -C 12 - 芳基可以是卤素取代的。 液体吸收聚合物可用于卫生制品和包装材料。
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4.发明申请公开(公告)号：US20090318715A1
公开(公告)日：2009-12-24
申请号：US12438192
申请日：2007-08-15
申请人： Patrick Deck , Kai Michael Exner , Boris Buschhaus
发明人： Patrick Deck , Kai Michael Exner , Boris Buschhaus
IPC分类号： C07C319/02 , C07D307/33
CPC分类号： C07C319/14 , C07D307/33 , C07C323/52
摘要： The present invention relates to a process for preparing compounds of the formula (I) by reacting compounds of the formula (II) with thiolates (RS)nM.The present invention further relates to a process for preparing compounds of the formula (II) from γ-butyrolactone.
摘要翻译： 本发明涉及通过使式（II）化合物与硫醇盐（RS）nM反应来制备式（I）化合物的方法。 本发明还涉及从γ-丁内酯制备式（II）化合物的方法。
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5.发明授权Postcrosslinking of water absorbing polymers with cyclic carbamates and/or cyclic ureas 有权吸水聚合物与环状氨基甲酸酯和/或环脲的后交联公开(公告)号：US07655733B2
公开(公告)日：2010-02-02
申请号：US11630949
申请日：2005-07-28
申请人： Kai Michael Exner , Thomas Daniel , Mark Elliott , Ulrich Riegel
发明人： Kai Michael Exner , Thomas Daniel , Mark Elliott , Ulrich Riegel
CPC分类号： A61L15/60
摘要： Disclosed is a process for postcrosslinking a water absorbing polymer by the polymer being treated with at least one postcrosslinker and postcrosslinked and dried during or after the treatment by raising the temperature, the at least one postcrosslinker being a cyclic carbamate or a cyclic urea, wherein the cyclic carbamate or the cyclic urea was obtained by reacting respectively an aminoalcohol or a diamine with a cyclic carbonate.
摘要翻译： 公开了一种通过用至少一种后交联剂处理的聚合物后交联吸水聚合物的方法，并且在处理期间或之后通过升高温度进行后交联和干燥，所述至少一种后交联剂是环状氨基甲酸酯或环脲，其中 通过使氨基醇或二胺与环状碳酸酯反应，得到环状氨基甲酸酯或环状脲。
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公开(公告)号：US07626058B2
公开(公告)日：2009-12-01
申请号：US12089775
申请日：2006-10-06
申请人： Gunther van Cauwenberge , Johann-Peter Melder , Kirsten Dahmen , Klemens Massonne , Steffen Oehlenschlaeger , Kai Michael Exner
发明人： Gunther van Cauwenberge , Johann-Peter Melder , Kirsten Dahmen , Klemens Massonne , Steffen Oehlenschlaeger , Kai Michael Exner
IPC分类号： C07C209/08
CPC分类号： C07C209/08 , C07C211/10 , C07C211/14
摘要： Processes are described comprising: (i) providing a reactant comprising 1,2-dichloroethane; and (ii) reacting the reactant with ammonia to form a reaction product comprising one or more ethylene amines and hydrogen chloride, wherein the reaction is carried out in the presence of an organic, nitrogen- or phosphorus-containing compound which reacts with the hydrogen chloride to form an ionic liquid.
摘要翻译： 描述了方法，其包括：（i）提供包含1,2-二氯乙烷的反应物; 和（ii）使反应物与氨反应以形成包含一种或多种亚乙基胺和氯化氢的反应产物，其中该反应在与氯化氢反应的有机，含氮或磷的化合物存在下进行 以形成离子液体。
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7.发明申请公开(公告)号：US20090215925A1
公开(公告)日：2009-08-27
申请号：US10585877
申请日：2005-01-18
IPC分类号： C09J167/06 , C08L33/10 , C07D303/34
CPC分类号： C07C233/20 , C07C69/54 , C07C69/732
摘要： The invention relates to a dispersion or solution of a polymer in water, organic solvents or mixtures thereof. The invention is characterised in that the polymer contains at least 0.001 mols of 3,4 dihydroxyphenyl groups (calculated at 109 g/mol) for 100 g polymer.
摘要翻译： 本发明涉及聚合物在水，有机溶剂或其混合物中的分散体或溶液。 本发明的特征在于聚合物含有至少0.001摩尔的3,4-二羟基苯基（以109克/摩尔计算）为100g聚合物。
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公开(公告)号：US07547807B2
公开(公告)日：2009-06-16
申请号：US10582912
申请日：2004-12-14
IPC分类号： C07C315/00
CPC分类号： C07F9/5428 , C07F9/5442
摘要： The present invention relates to a process for preparing quaternary phosphonium salts by reacting a ternary phosphine with an optionally substituted, saturated or monounsaturated or polyunsaturated electrophile having from 3 to 25 carbon atoms in ternary solvent mixtures.
摘要翻译： 本发明涉及通过使三元膦与在三元溶剂混合物中具有3至25个碳原子的任选取代的饱和或不饱和或多不饱和亲电体反应来制备季鏻盐的方法。
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公开(公告)号：US20090043121A1
公开(公告)日：2009-02-12
申请号：US12255460
申请日：2008-10-21
IPC分类号： C07C69/612
CPC分类号： C07C403/12 , C07C2601/16
摘要： The present invention relates to a process for preparing vitamin A acetate by reacting β-vinylionol with triphenylphosphine in the presence of sulfuric acid in a solvent mixture consisting of 60 to 80% by weight methanol, 10 to 20% by weight water and 10 to 20% by weight aliphatic, cyclic or aromatic hydrocarbons having 5 to 8 carbon atoms to give β-ionylideneethyltriphenylphosphonium salts and subsequent Wittig reaction with 4-acetoxy-2-methylbut-2-enal.
摘要翻译： 本发明涉及一种制备维生素A乙酸酯的方法，该方法是在硫酸存在下，使β-乙烯醇与三苯膦反应，在60至80％（重量）甲醇，10至20％（重量）水和10至20份 重量％的具有5至8个碳原子的脂族，环状或芳族烃，得到β-离子亚乙基三苯基鏻盐，随后与4-乙酰氧基-2-甲基丁-2-烯的维t希反应。
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公开(公告)号：US06989454B2
公开(公告)日：2006-01-24
申请号：US10485200
申请日：2002-07-17
申请人： Hartmut Hibst , Ralf Noe , Kai Michael Exner , Mark Duda
发明人： Hartmut Hibst , Ralf Noe , Kai Michael Exner , Mark Duda
IPC分类号： C07D307/36
CPC分类号： C07D307/60
摘要： A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube reactor having two successive reaction zones, where the first, feed-side reaction zone contains at least one catalyst which is suitable for the oxydehydrogenation of n-butenes to 1,3-butadiene and the second, product-side reaction zone contains at least one catalyst which is suitable for the oxidation of 1,3-butadiene to maleic anhydride, is carried out using a shell-and-tube reactor which has at least one heat transfer medium circuit in the region of the first, feed-side reaction zone and at least one further heat transfer medium circuit in the region of the second, product-side reaction zone.
摘要翻译： 在具有两个连续反应区域的管壳式反应器中，通过含氧气体异构催化气相氧化含正丁烯的烃物流来制备马来酸酐的方法，其中第一个进料侧 反应区含有至少一种适用于正丁烯氧化脱氢至1,3-丁二烯的催化剂，第二产物侧反应区含有至少一种适用于1,3-丁二烯氧化的催化剂 马来酸酐使用壳管式反应器进行，该管式反应器在第一进料侧反应区域中具有至少一个传热介质回路，并且在第二进料侧反应区域中至少一个另外的传热介质回路 ，产品侧反应区。
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