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1.发明申请公开(公告)号：US20130217900A1
公开(公告)日：2013-08-22
申请号：US13882580
申请日：2011-11-01
IPC分类号： C07C31/135 , C07F9/50 , C07C43/21 , C07D309/12 , C07F7/08
CPC分类号： C07C31/135 , C07B2200/07 , C07C29/149 , C07C29/64 , C07C43/21 , C07C67/08 , C07C67/14 , C07C2601/10 , C07D309/10 , C07D309/12 , C07D309/30 , C07F7/081 , C07F9/5027 , Y02P20/55 , C07C31/44 , C07C69/78 , C07C69/63
摘要： A compound of formula (I), wherein R1 is hydrogen or a hydroxyl protecting group; and R2 and R3 are same or different and are independently selected from halogen or —O—SO2—X; wherein X is —C1-C4 alkyl; C1-C4 alkyl substituted with one or more halogen; or substituted or unsubstituted phenyl wherein said phenyl substituent is selected from halogen, nitro and C1-C4 alkyl; provided that when R3 is bromine, X is not p-toluoyl; and a process for the preparation thereof.
摘要翻译： 式（I）的化合物，其中R 1是氢或羟基保护基; R2和R3相同或不同，独立地选自卤素或-O-SO2-X; 其中X是-C 1 -C 4烷基; 被一个或多个卤素取代的C 1 -C 4烷基; 或取代或未取代的苯基，其中所述苯基取代基选自卤素，硝基和C 1 -C 4烷基; 条件是当R 3为溴时，X不为对甲苯酰基; 及其制备方法。
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2.发明授权公开(公告)号：US08993788B2
公开(公告)日：2015-03-31
申请号：US13882580
申请日：2011-11-01
IPC分类号： C07C31/135 , C07F9/50 , C07C43/21 , C07D309/12 , C07F7/08 , C07C29/149 , C07C29/64 , C07C67/08 , C07C67/14 , C07D309/10 , C07D309/30
CPC分类号： C07C31/135 , C07B2200/07 , C07C29/149 , C07C29/64 , C07C43/21 , C07C67/08 , C07C67/14 , C07C2601/10 , C07D309/10 , C07D309/12 , C07D309/30 , C07F7/081 , C07F9/5027 , Y02P20/55 , C07C31/44 , C07C69/78 , C07C69/63
摘要： A compound of formula (I), wherein R1 is hydrogen or a hydroxyl protecting group; and R2 and R3 are same or different and are independently selected from halogen or —O—SO2—X; wherein X is —C1-C4 alkyl; C1-C4 alkyl substituted with one or more halogen; or substituted or unsubstituted phenyl wherein said phenyl substituent is selected from halogen, nitro and C1-C4 alkyl; provided that when R3 is bromine, X is not p-toluoyl; and a process for the preparation thereof.
摘要翻译： 式（I）的化合物，其中R 1是氢或羟基保护基; R2和R3相同或不同，独立地选自卤素或-O-SO2-X; 其中X是-C 1 -C 4烷基; 被一个或多个卤素取代的C 1 -C 4烷基; 或取代或未取代的苯基，其中所述苯基取代基选自卤素，硝基和C 1 -C 4烷基; 条件是当R 3为溴时，X不为对甲苯酰基; 及其制备方法。
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公开(公告)号：US08461386B2
公开(公告)日：2013-06-11
申请号：US12935166
申请日：2009-04-16
IPC分类号： C07C209/70 , C07C233/18
CPC分类号： C07C233/18 , C07B2200/07 , C07C213/02 , C07C217/08
摘要： The present invention relates to a process for the asymmetric hydrogenation of imines with hydrogen under elevated pressure in the presence of a catalyst system. In particular the present invention relates to the use of the said catalytic system for the enantioselective hydrogenation of prochiral ketimines to asymmetric amines leading to the formation of herbicides.
摘要翻译： 本发明涉及在催化剂体系的存在下，在升高的压力下用氢气对不饱和氢化亚胺的方法。 特别地，本发明涉及所述催化体系用于将前手性酮亚胺对映异构氢化成不对称胺，导致形成除草剂的用途。
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公开(公告)号：US20110054217A1
公开(公告)日：2011-03-03
申请号：US12935166
申请日：2009-04-16
IPC分类号： C07C217/08 , C07C233/18
CPC分类号： C07C233/18 , C07B2200/07 , C07C213/02 , C07C217/08
摘要： The present invention relates to a process for the asymmetric hydrogenation of imines with hydrogen under elevated pressure in the presence of a catalyst system. In particular the present invention relates to the use of the said catalytic system for the enantioselective hydrogenation of prochiral ketimines to asymmetric amines leading to the formation of herbicides.
摘要翻译： 本发明涉及在催化剂体系的存在下，在升高的压力下用氢气对不饱和氢化亚胺的方法。 特别地，本发明涉及所述催化体系用于将前手性酮亚胺对映异构氢化成不对称胺，导致形成除草剂的用途。
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