公开(公告)号：US4769225A

公开(公告)日：1988-09-06

申请号：US704113

申请日：1985-02-22

申请人： James J. Reilly ,  Edward W. Grohse ,  John R. Johnson ,  Warren E. Winsche, deceased

发明人： James J. Reilly ,  Edward W. Grohse ,  John R. Johnson ,  Warren E. Winsche, deceased

IPC分类号： C01B3/00 ,  C01B3/50

CPC分类号： C01B3/0057 ,  C01B3/0031 ,  C01B3/0068 ,  C01B3/0073 ,  C01B3/508 ,  Y02E60/327 ,  Y10S420/90

摘要： The reversible reaction M+x/2 H.sub.2 .rarw..fwdarw.MH.sub.x, wherein M is a reversible metal hydride former that forms a hydride MH.sub.x in the presence of H.sub.2, generally used to store and recall H.sub.2, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H.sub.2, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H.sub.2 through the liquid is dependent upon the H.sub.2 pressure in the gas phase at a given temperature. When the actual H.sub.2 pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particles. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

摘要翻译： 发现可逆反应M + x / 2 H2 + MHx，其中M是在H 2存在下形成氢化物MHx的可逆金属氢化物前体，通常用于储存和回收H 2，在惰性液体 ，从而减少污染，提供更好的温度控制，提供反应物的原位迁移率，并提高工艺设计的灵活性。 因此，将金属氢化物形成物与惰性溶剂的颗粒的浆料经受含有H 2的温度和压力控制的气氛，以储存氢气并释放预先储存的氢气。 通过液体的H 2流动的方向取决于在给定温度下气相中的H 2压力。 当实际的H2压力高于相应氢化物的平衡吸收压力时，反应进行到右侧，即形成金属氢化物，氢气储存在固体颗粒中。 当气相中的实际压力低于各自氢化物的平衡解离压力时，反应进行到左侧，金属氢化物被分解，氢气释放到气相中。