Precursor polyphenylene for and method of producing glassy carbon
    1.
    发明授权
    Precursor polyphenylene for and method of producing glassy carbon 失效
    前体聚苯乙烯和生产玻碳的方法

    公开(公告)号:US5334668A

    公开(公告)日:1994-08-02

    申请号:US13744

    申请日:1993-02-04

    IPC分类号: C04B35/524 C08G61/10

    CPC分类号: C04B35/524 C08G2261/312

    摘要: Polymeric carbon can be formed by a method comprising the steps of(a) polymerizing 1-bromo-4-lithiobenzene to form a brominated polyphenylene wherein the ratio of brominated to non-brominated residues in the polymer is 1:5 or greater;(b) functionalizing the brominated polyphenylene to replace the bromide groups with a substituted or unsubstituted acetylene group; and(c) heating the functionalized polymer to a temperature of 900.degree. C. to form polymeric carbon. Preferably, the brominated polyphenylene is formed in an ethereal solvent such as tetrahydrofuran and then functionalized using a palladium catalyst and a copper catalyst. When the acetylene substituent is phenylacetylene, the product of the method is glassy carbon.

    摘要翻译: 聚合碳可以通过包括以下步骤的方法形成:(a)聚合1-溴-4-锂苯以形成溴化聚亚苯基,其中聚合物中溴化与非溴化残基的比例为1:5或更大; (b)用取代或未取代的乙炔官能化溴代聚亚苯取代溴基; 和(c)将官能化聚合物加热到900℃的温度以形成聚合碳。 溴代聚亚苯基优选在醚溶剂如四氢呋喃中形​​成,然后使用钯催化剂和铜催化剂进行官能化。 当乙炔取代基是苯基乙炔时,该方法的产物是玻璃碳。

    Precursor polyphenylene for and method of producing glassy carbon
    2.
    发明授权
    Precursor polyphenylene for and method of producing glassy carbon 失效
    前体聚苯乙烯和生产玻璃碳的方法

    公开(公告)号:US5236686A

    公开(公告)日:1993-08-17

    申请号:US746714

    申请日:1991-08-19

    IPC分类号: C04B35/524

    CPC分类号: C04B35/524 C08G2261/312

    摘要: Polymeric carbon can be formed by a method comprising the steps of(a) polymerizing 1-bromo-4-lithiobenzene to form a brominated polyphenylene wherein the ratio of brominated to non-brominated residues in the polymer is 1:5 or greater;(b) functionalizing the brominated polyphenylene to replace the bromide groups with a substituted or unsubstituted acetylene group; and(c) heating the functionalized polymer to a temperature of 900.degree. C. to form polymeric carbon. Preferably, the brominated polyphenylene is formed in an ethereal solvent such as tetrahydrofuran and then functionalized using a palladium catalyst and a copper catalyst. When the acetylene substituent is phenylacetylene, the product of the method is glassy carbon.

    Colorant compositions
    5.
    发明申请
    Colorant compositions 有权
    着色剂组合物

    公开(公告)号:US20080108817A1

    公开(公告)日:2008-05-08

    申请号:US12006510

    申请日:2008-01-03

    IPC分类号: C07D401/02

    摘要: Colorant compositions are useful for a wide variety of product applications. For example, colorants are used in tinting of polymers, providing colors to aqueous solution(s), and affording color to solid or semi-solid products such as detergents. Disclosed herein are colorant compositions having a triphenylmethane (“TPM”) structure having improved stability to alkaline conditions. Thus, the colorant compositions resist decolorization, even at relatively high pH levels.

    摘要翻译: 着色剂组合物可用于各种产品应用。 例如,着色剂用于聚合物着色,为水溶液提供颜色,并为固体或半固体产品如洗涤剂提供颜色。 本文公开了具有对碱性条件具有改进的稳定性的三苯基甲烷(“TPM”)结构的着色剂组合物。 因此,即使在相对较高的pH值下,着色剂组合物抵抗脱色。

    Colorant compositions
    6.
    发明申请

    公开(公告)号:US20060101593A1

    公开(公告)日:2006-05-18

    申请号:US10992066

    申请日:2004-11-18

    IPC分类号: D06P5/13

    摘要: Colorant compositions are useful for a wide variety of product applications. For example, colorants are used in tinting of polymers, providing colors to aqueous solution(s), and affording color to solid or semi-solid products such as detergents. Disclosed herein are colorant compositions having a triphenylmethane (“TPM”) derived structure having improved stability to alkaline conditions. Thus, the colorant compositions resist decolorization, even at relatively high pH levels. The colorant compositions of the invention are useful as applied in polyolefins, such as polypropylene and polyethylene, as examples. These colorant compositions also may be employed in thermoplastics, such as PET, for example.