公开(公告)号：US07601761B2

公开(公告)日：2009-10-13

申请号：US11710788

申请日：2007-02-26

申请人： Jan L. Clatty ,  Timothy R. Whelan ,  Susanne Whelan, legal representative ,  Michael T. Wellman ,  John W. Liddle ,  Marie W. Urick

发明人： Jan L. Clatty ,  Timothy R. Whelan ,  Michael T. Wellman ,  John W. Liddle ,  Marie W. Urick

IPC分类号： C08L75/04

CPC分类号： C08G18/4018 ,  C08G18/4812 ,  C08G18/4829 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08L27/04

摘要： The present invention provides a rigid polyurethane foam made from the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate, and a polyol component containing about 20 to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1000 Daltons (Da), about 80 to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a molecular weight of from about 350 to less than about 1,000, and about 0 to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da, in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.1 to about 200 microns, and glass beads having a diameter of from about 40 to about 400 microns (about 270 to about 45 mesh), and optionally, in the presence of at least one of carbon dioxide, surfactants, flame retardants, pigments and catalysts, wherein the rigid polyurethane foam with a density of about 10 to about 25 pcf has a heat sag measured at 102 mm overhang at 121° C. and one hour of less than about 8 mm. The inventive rigid polyurethane foams exhibit increased heat performance (decreased heat sag) while also maintaining impact and rebound strengths.

摘要翻译： 本发明提供由异氰酸酯指数为约90至约400的反应产物制成的多异氰酸酯和包含约20至约80重量％的多元醇组分的多元醇组分的硬质聚氨酯泡沫。 基于多元醇组分的重量，数均分子量大于约1000道尔顿（Da）的双金属氰化物（DMC）催化的聚醚多元醇的含量为约80至约20wt。 基于多元醇组分的重量，官能度为约2.5至约6，分子量为约350至小于约1,000，约0至约40重量％的蔗糖基多元醇。 在数均分子量小于约600Da的低分子量有机化合物的基础上，基于多元醇组分的重量％，在水的存在下，直径为约0.1〜 约200微米的玻璃珠和直径为约40至约400微米（约270至约45目）的玻璃珠，以及任选在二氧化碳，表面活性剂，阻燃剂，颜料和催化剂中的至少一种存在下， 其中密度为约10至约25pff的硬质聚氨酯泡沫具有在121℃突出的102mm处测量的热下垂和小于约8mm的1小时。 本发明的刚性聚氨酯泡沫体表现出增加的热性能（减少热量下垂），同时还保持冲击和回弹强度。

公开(公告)号：US20080207787A1

公开(公告)日：2008-08-28

申请号：US11710788

申请日：2007-02-26

申请人： Jan L. Clatty ,  Timothy R. Whelan ,  Michael T. Wellman ,  John W. Liddle ,  Marie W. Urick ,  Susanne Whelan

发明人： Jan L. Clatty ,  Timothy R. Whelan ,  Michael T. Wellman ,  John W. Liddle ,  Marie W. Urick ,  Susanne Whelan

IPC分类号： C08G18/48

CPC分类号： C08G18/4018 ,  C08G18/4812 ,  C08G18/4829 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08L27/04

摘要： The present invention provides a rigid polyurethane foam made from the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate, and a polyol component containing about 20 to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1000 Daltons (Da), about 80 to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a molecular weight of from about 350 to less than about 1,000, and about 0 to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da, in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.1 to about 200 microns, and glass beads having a diameter of from about 40 to about 400 microns (about 270 to about 45 mesh), and optionally, in the presence of at least one of carbon dioxide, surfactants, flame retardants, pigments and catalysts, wherein the rigid polyurethane foam with a density of about 10 to about 25 pcf has a heat sag measured at 102 mm overhang at 121° C. and one hour of less than about 8 mm. The inventive rigid polyurethane foams exhibit increased heat performance (decreased heat sag) while also maintaining impact and rebound strengths.

摘要翻译： 本发明提供由异氰酸酯指数为约90至约400的反应产物制成的多异氰酸酯和包含约20至约80重量％的多元醇组分的多元醇组分的硬质聚氨酯泡沫。 基于多元醇组分的重量，数均分子量大于约1000道尔顿（Da）的双金属氰化物（DMC）催化的聚醚多元醇的含量为约80至约20wt。 基于多元醇组分的重量，官能度为约2.5至约6，分子量为约350至小于约1,000，约0至约40重量％的蔗糖基多元醇。 在数均分子量小于约600Da的低分子量有机化合物的基础上，基于多元醇组分的重量％，在水的存在下，直径为约0.1〜 约200微米的玻璃珠和直径为约40至约400微米（约270至约45目）的玻璃珠，以及任选在二氧化碳，表面活性剂，阻燃剂，颜料和催化剂中的至少一种存在下， 其中密度为约10至约25pff的硬质聚氨酯泡沫具有在121℃突出的102mm处测量的热下垂和小于约8mm的1小时。 本发明的刚性聚氨酯泡沫体表现出增加的热性能（减少热量下垂），同时还保持冲击和回弹强度。