公开(公告)号：US4260814A

公开(公告)日：1981-04-07

申请号：US59729

申请日：1979-07-23

申请人： Jar-lin Kao ,  Ming N. Sheng

发明人： Jar-lin Kao ,  Ming N. Sheng

IPC分类号： C07C395/00 ,  C07C67/00 ,  C07C69/14 ,  C07C69/24

CPC分类号： C07C395/00 ,  C07C67/00

摘要： A process for the preparation of bromoalkyl esters and vicinal glycol esters which comprises thermally decomposing at temperatures of from 100.degree. C. to 200.degree. C. a bis(2-bromoalkyl)tellurium dicarboxylate compound of the formula ##STR1## wherein at least one R is hydrogen or R is a methyl group and R' is hydrogen or an alkyl group having 1 to 3 carbon atoms in the presence of an aliphatic monocarboxylic acid selected from formic, acetic, propionic or butyric acid employed as solvent and to facilitate solvolysis in the reaction to give in addition to the bromoalkyl ester, the vicinal glycol ester. An inert acetonitrile solvent may be employed alone to give predominately the bromoalkyl ester or an admixture with the acid may be employed. Oxygen is preferably employed with the carboxylic acid solvent to provide an increase in the mole ratio of vicinal glycol ester to the bromoalkyl ester produced.

摘要翻译： 一种制备溴烷基酯和连环二醇酯的方法，其包括在100℃至200℃的温度下分解式（II）的双（2-溴烷基）碲二羧酸酯化合物，其中至少一个R 是氢或R是甲基，R'是氢或具有1至3个碳原子的烷基，在脂肪族单羧酸的存在下，用作溶剂的甲酸，乙酸，丙酸或丁酸，并促进溶剂分解 反应得到除溴代烷基酯，邻位二醇酯外。 可以单独使用惰性乙腈溶剂，主要得到溴烷基酯或与酸的混合物。 优选与羧酸溶剂一起使用氧气以提供邻位二醇酯与所产生的溴代烷基酯的摩尔比的增加。

公开(公告)号：US4247465A

公开(公告)日：1981-01-27

申请号：US68996

申请日：1979-08-23

申请人： Jar-Lin Kao ,  Gregory A. Wheaton ,  Harold Shalit ,  Ming N. Sheng

发明人： Jar-Lin Kao ,  Gregory A. Wheaton ,  Harold Shalit ,  Ming N. Sheng

IPC分类号： B01J27/00 ,  C07B61/00 ,  C07D317/36 ,  C07D317/38

CPC分类号： C07D317/36

摘要： A process for the preparation of a cyclic alkylene carbonate ester which comprises reacting in a liquid phase a cyclic or linear olefin having from 2 to 15 carbon atoms with carbon dioxide at a temperature of from 30.degree. to 160.degree. C., at a total pressure of from 100 to about 2,000 psig and a pH value of between about 4 and 8, in the presence of oxygen or an oxygen-containing gas and a catalytic amount of a mixture of (a) iodine or an iodide of a metal selected from Groups IA, IB, IIA, IIB, VB, VIIB and VIII of the Periodic Table of Elements, (b) a carbonate of a metal selected from Groups IB, IIA, IIB and VIII of the Periodic Table of Elements, (c) a catalytic iron compound and (d) a catalytic soluble cupric salt, and recovering resulting cyclic alkylene carbonate ester.

摘要翻译： 一种制备环状碳酸亚烷基酯的方法，该方法包括在液相中将具有2至15个碳原子的环状或线型烯烃与二氧化碳在30至160℃的温度下，以总压力 为100至约2,000psig，pH值为约4至8，在氧或含氧气体和催化量的（a）碘或选自以下的金属的碘化物的混合物的存在下， IA，IB，IIA，IIB，VB，VIIB和VIII，（b）选自元素周期表IB，IIA，IIB和VIII族的金属的碳酸盐，（c） 铁化合物和（d）催化可溶性铜盐，并回收所得环状碳酸亚烷基酯。

公开(公告)号：US4231937A

公开(公告)日：1980-11-04

申请号：US937294

申请日：1978-08-28

申请人： Jar-lin Kao ,  Ming N. Sheng

发明人： Jar-lin Kao ,  Ming N. Sheng

IPC分类号： C07D317/36 ,  C07D317/38

CPC分类号： C07D317/38 ,  C07D317/36

摘要： A process for the preparation of alkylene carbonates having from 3 to 31 carbon atoms per molecule of the general formula ##STR1## which comprises reacting in the liquid phase the corresponding alkylene iodohydrin having from 2 to 30 carbon atoms per molecule with carbon dioxide in the presence of oxygen or an oxygen-containing gas and an effective amount of a catalytic mixture of(1) an iodide of the metals selected from groups IA, IB, IIA, IIB and VIII of the Periodic Table of Elements and(2) a carbonate of the metals selected from the groups IB, IIA, and IIB of the Periodic Table of Elements,at a temperature of from 30.degree. C. to 120.degree. C., and at a total carbon dioxide and oxygen pressure between about atmospheric and 1400 psig, at a pH value of between 3 and 10.

摘要翻译： 一种制备每分子具有3至31个碳原子的碳酸亚烷基酯的方法，该通式包括在液相中使每分子具有2-30个碳原子的相应亚烷基碘醇与二氧化碳反应， 的氧气或含氧气体和有效量的（1）选自元素周期表的IA，IB，IIA，IIB和VIII族的金属的碘化物的催化混合物和（2）碳酸盐 选自元素周期表IB，IIA和IIB族的金属，温度为30℃至120℃，总二氧化碳和氧气压力约为大气压至1400psig， pH值在3和10之间。

公开(公告)号：US4237314A

公开(公告)日：1980-12-02

申请号：US73050

申请日：1979-09-06

申请人： Ming N. Sheng ,  Jar-Lin Kao

发明人： Ming N. Sheng ,  Jar-Lin Kao

IPC分类号： C07C51/353 ,  C07C57/30

CPC分类号： C07C51/353

摘要： Phenyl acetic acid is prepared by the reaction of molecular oxygen and the combination of acetic acid and benzene in the presence of a catalytic system featuring both tellurium and halide, the unit atomic ratio of halide to tellurium being within a range from about 3 to about 20, at a temperature within a range from about 100.degree. C. to about 200.degree. C. at a pressure within a range from about 1 to about 15 atmospheres.

摘要翻译： 苯乙酸通过分子氧与乙酸和苯的组合在具有碲和卤化物特征的催化体系的存在下反应制备，卤化物与碲的单位原子比在约3至约20的范围内 在约100℃至约200℃的温度范围内，在约1至约15个大气压的范围内。

公开(公告)号：US4144399A

公开(公告)日：1979-03-13

申请号：US780564

申请日：1977-03-23

申请人： Ming N. Sheng ,  Jar-lin Kao

发明人： Ming N. Sheng ,  Jar-lin Kao

IPC分类号： C07C51/25 ,  C07C409/24 ,  C07C409/38 ,  C07C51/00 ,  C07C57/04

CPC分类号： C07C51/252 ,  C07C407/00

摘要： A process for the preparation of acrylic acid or methacrylic acid by the ruthenium and/or osmium catalyzed conversion of peroxide (peroxy) intermediate compounds, derived from the autoxidation of acrolein or methacrolein, to the corresponding .alpha.,.beta.-unsaturated carboxylic acid, particularly the conversion of permethacrylic acid and methacrolein monopermethacrylate to methacrylic acid.

摘要翻译： 通过钌和/或锇催化转化来自丙烯醛或甲基丙烯醛自氧化的过氧化物（过氧）中间体化合物转化为相应的α，β-不饱和羧酸，特别是用于制备丙烯酸或甲基丙烯酸的方法， 甲基丙烯酸和甲基丙烯醛单甲基丙烯酸酯转化成甲基丙烯酸。

公开(公告)号：US4258208A

公开(公告)日：1981-03-24

申请号：US59730

申请日：1979-07-23

申请人： Jar-lin Kao ,  Ming N. Sheng

发明人： Jar-lin Kao ,  Ming N. Sheng

IPC分类号： C07C67/00 ,  C07C69/14 ,  C07C69/24

CPC分类号： C07C67/00

摘要： A process for the preparation of 2-bromoalkyl esters and vicinal glycol esters which comprises thermally decomposing at temperatures of from 100.degree. C. to 200.degree. C. an organic bromoalkyl tellurium compound selected from 2-bromoalkyltellurium tribromide or bis(2-bromoalkyl)tellurium dibromide, wherein the alkyl group is ethyl, propyl or butyl, in a carboxylic acid having from 1 to 4 carbon atoms which is employed as solvent as well as to supply the ester moiety to the esters produced. The esters may be converted to the respective glycol with water or an aqueous base.

摘要翻译： 一种制备2-溴烷基酯和邻二醇酯的方法，其包括在100℃至200℃的温度下热分解。选自2-溴代三溴化碲或二（2-溴烷基）碲的有机溴烷基碲化合物 二溴化物，其中烷基是乙基，丙基或丁基，在具有1至4个碳原子的羧酸中用作溶剂，以及将酯部分供应到所生产的酯上。 酯可以用水或碱水溶液转化成相应的二醇。

公开(公告)号：US4224223A

公开(公告)日：1980-09-23

申请号：US68997

申请日：1979-08-23

申请人： Gregory A. Wheaton ,  Jar-lin Kao ,  Ming N. Sheng

发明人： Gregory A. Wheaton ,  Jar-lin Kao ,  Ming N. Sheng

IPC分类号： C07C29/03 ,  C07C29/64 ,  C07C29/66 ,  C07C45/00 ,  C07C45/35 ,  C07C49/00 ,  C07C67/00 ,  C07D301/02 ,  C07D303/04 ,  C07D317/36 ,  C07D317/38

CPC分类号： C07C45/35 ,  C07C29/03 ,  C07C29/64 ,  C07C29/66 ,  C07D301/02 ,  C07D317/36

摘要： A process for the preparation of a cyclic alkylene carbonate ester which comprises reacting in a liquid phase a cyclic or linear olefin having from 2 to 15 carbon atoms with carbon dioxide at a temperature of from 50 to 160.degree. C., at a total pressure of from 200 to about 2,000 psig and a pH value of between about 4 and 8, in the presence of oxygen or an oxygen-containing gas and a catalytic amount of a mixture of (a) iodine or an iodide of a metal selected from Groups IA, IB, IIA, IIB, VB, VIIB and VIII of the Periodic Table of Elements and (b) a catalytic iron compound, copper compound of mixture thereof deposited on an inert supporting material, and recovering resulting cyclic alkylene carbonate ester.

摘要翻译： 一种制备环状碳酸亚烷基酯的方法，该方法包括在液相中将具有2至15个碳原子的环状或线性烯烃与二氧化碳在50至160℃的温度下反应， 从约200psi至约2000psig，pH值为约4-8，在氧气或含氧气体和催化量的（a）碘或选自IA组中的金属碘化物的混合物 ，IB，IIA，IIB，VB，VIIB和VIII和（b）催化铁化合物，沉积在惰性负载材料上的混合物的铜化合物，并回收所得环状碳酸亚烷基酯。

公开(公告)号：US4147884A

公开(公告)日：1979-04-03

申请号：US679958

申请日：1976-04-26

申请人： Ming N. Sheng ,  Jar-Lin Kao

发明人： Ming N. Sheng ,  Jar-Lin Kao

IPC分类号： C07C51/25 ,  C07C51/32 ,  C07C57/04

CPC分类号： C07C51/252

摘要： Process for the liquid phase oxidation of an unsaturated lower aliphatic aldehyde to the corresponding carboxylic acid wherein the oxidation is carried out by passage of an oxygen-containing gas through a liquid medium containing the unsaturated aldehyde and a fluorine-containing organic compound.

摘要翻译： 将不饱和低级脂族醛液相氧化成相应羧酸的方法，其中氧化通过含氧气体通过含有不饱和醛和含氟有机化合物的液体介质进行。

公开(公告)号：US4263465A

公开(公告)日：1981-04-21

申请号：US74190

申请日：1979-09-10

申请人： Ming N. Sheng ,  Mary T. Arnold

发明人： Ming N. Sheng ,  Mary T. Arnold

IPC分类号： C10G50/02 ,  C10G69/12 ,  C10M107/02 ,  C07C9/00 ,  C07C2/74

CPC分类号： C10M107/02 ,  C10G50/02 ,  C10G69/126 ,  C10G2400/10 ,  C10M2205/00

摘要： A low viscosity synthetic lubricant is prepared by polymerizing 1-butene to an oligomer containing a number average of about 8 to 18 carbon atoms and copolymerizing the oligomer with an alpha-monoolefin having 8 to 18 carbon atoms to produce a copolymer having an average of about 20 to 40 carbon atoms. Both polymerization reactions are catalyzed by a combination of boron trifluoride and a proton donor promoter. The synthetic lubricant is preferably stripped to remove lower boiling components, such as oligomers having 20 carbon atoms or less, and optionally hydrogenated for improved stability.

摘要翻译： 通过将1-丁烯聚合到含有约8至18个碳原子的数均分子的低聚物并使低聚物与具有8至18个碳原子的α-单烯烃共聚以制备平均约为 20至40个碳原子。 两种聚合反应均由三氟化硼和质子供体启动子的组合催化。 优选汽提合成润滑剂以除去低沸点组分，例如具有20个碳原子或更少碳原子的低聚物，并任选地氢化以提高稳定性。

公开(公告)号：US3983143A

公开(公告)日：1976-09-28

申请号：US521324

申请日：1974-11-06

申请人： Ming N. Sheng ,  John G. Zajacek ,  Thomas N. Baker, III

发明人： Ming N. Sheng ,  John G. Zajacek ,  Thomas N. Baker, III

IPC分类号： C07D301/20

CPC分类号： C07D301/19

摘要： Method for the molybdenum-catalyzed epoxidation of less reactive olefins such as the alpha-olefins and alpha-substituted olefins with the less stable organic hydroperoxides to give good yields of the epoxide by employing a critical amount of a stabilizing agent consisting of a C.sub.3 to C.sub.9 secondary or tertiary monohydric alcohol.

摘要翻译： 用较少反应性烯烃（如α-烯烃和α-取代烯烃）进行钼催化环氧化的方法，其中较不稳定的有机氢过氧化物可通过使用临界量的由C3至C9组成的稳定剂来提供良好的环氧化物产率 仲或叔一元醇。