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1.发明授权Supernucleophilic 4-substituted-pyridine catalysts, and processes useful for preparing same 有权超亲核性4-取代吡啶催化剂及其制备方法公开(公告)号：US06369230B1
公开(公告)日：2002-04-09
申请号：US09463902
申请日：2000-04-13
申请人： Joe W. Curtis , Marudai Balasubramanian , Joel R. Calvin , Eric F. V. Scriven , Charles R. Hopper , Ramiah Murugan , L. Mark Huckstep
发明人： Joe W. Curtis , Marudai Balasubramanian , Joel R. Calvin , Eric F. V. Scriven , Charles R. Hopper , Ramiah Murugan , L. Mark Huckstep
IPC分类号： C07D21362
CPC分类号： C07D213/73 , B01J31/0237 , B01J31/0244 , B01J35/023 , B01J37/0063 , B01J2231/4205 , C07D213/74 , C07D213/84
摘要： A process of preparing 4-substituted pyridine compounds via pyridine betaine compounds.
摘要翻译： 通过吡啶甜菜碱化合物制备4-取代的吡啶化合物的方法
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2.发明授权Supernucleophilic 4-substituted-pyridine catalysts, and processes useful for preparing same 失效超亲核性4-取代吡啶催化剂及其制备方法
公开(公告)号：US6046336A
公开(公告)日：2000-04-04
申请号：US127542
申请日：1998-07-31
申请人： Joe W. Curtis , Charles R. Hopper , Ramiah Murugan , L. Mark Huckstep , Marudai Balasubramanian , Joel R. Calvin , Eric F. V. Scriven
发明人： Joe W. Curtis , Charles R. Hopper , Ramiah Murugan , L. Mark Huckstep , Marudai Balasubramanian , Joel R. Calvin , Eric F. V. Scriven
IPC分类号： C07D213/74 , B01J31/02 , B01J35/02 , B01J37/00 , C07D213/73 , C07D213/84 , C07D213/02
CPC分类号： C07D213/73 , B01J31/0237 , B01J31/0244 , B01J35/023 , B01J37/0063 , C07D213/74 , C07D213/84 , B01J2231/4205
摘要： Described are preferred processes for producing extrusion-granulated supernucleophilic 4-amino-substituted pyridine catalysts, and granular products obtainable therefrom. Also described are preferred activation-substitution-deactivation processes for producing 4-aminopyridine compounds, which involve the use of acrylic acid or acrylamide or analogs thereof for activation, and substitution steps conducted under mild basic conditions in an excess of the amine reagent for 4-substitution. Such processes provide improved reacted masses which are more readily processed to recover the products in pure, heat-stable form. Further, described are processes for preparing 4-substituted-pyridines via pyridine betaines.
摘要翻译： 描述了用于生产挤出造粒的超亲核4-氨基取代的吡啶催化剂的优选方法和可从其获得的颗粒产物。 还描述了用于生产4-氨基吡啶化合物的优选的活化取代失活方法，其涉及使用丙烯酸或丙烯酰胺或其类似物进行活化，以及在温和的碱性条件下在过量的胺试剂中进行4-取代 - 代换。 这些方法提供改进的反应物质，其更容易加工以以纯的，热稳定的形式回收产物。 此外，描述了通过吡啶甜菜碱制备4-取代吡啶的方法。
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3.发明授权Supernucleophilic 4-substituted-pyridine catalysts, and processes useful for preparing same 有权超亲核性4-取代吡啶催化剂及其制备方法公开(公告)号：US06958400B2
公开(公告)日：2005-10-25
申请号：US10425504
申请日：2003-04-29
申请人： Marudai Balasubramanian , Joel R. Calvin , Eric F. V. Scriven , Charles R. Hopper , Ramiah Murugan , L. Mark Huckstep
发明人： Marudai Balasubramanian , Joel R. Calvin , Eric F. V. Scriven , Charles R. Hopper , Ramiah Murugan , L. Mark Huckstep
IPC分类号： C07D213/74 , B01J31/02 , B01J35/02 , B01J37/00 , C07D213/73 , C07D213/84 , C07D213/02
CPC分类号： C07D213/73 , B01J31/0237 , B01J31/0244 , B01J35/023 , B01J37/0063 , B01J2231/4205 , C07D213/74 , C07D213/84
摘要： Processes for preparing a 4-(secondary or tertiary)aminopyridine are provided. The processes comprise reacting a 4-substituted pyridine base having a leaving group as the 4-substituent, with an activating agent so as to form a corresponding 1,4-substituted pyridine; reacting the 1,4-substituted pyridine with a primary or secondary amine to substitute an amino group at the 4-position, and thereby form a corresponding 1-substituted-4-(secondary or tertiary) aminopyridine, wherein the reacting is conducted in a substitution reaction medium essentially free from strong base; and treating the 1-substituted-4-aminopyridine compound to remove the 1-substituent and thereby form a product medium including the 4-(secondary or tertiary) amino-pyridine.
摘要翻译： 提供了制备4-（仲或叔）氨基吡啶的方法。 该方法包括使具有离去基团的4-取代吡啶碱作为4-取代基与活化剂反应，形成相应的1,4-取代的吡啶; 使1,4-取代的吡啶与伯胺或仲胺反应以代替4-位氨基，从而形成相应的1-取代-4-（仲或叔）氨基吡啶，其中反应在 取代反应介质基本上不含强碱; 并处理1-取代-4-氨基吡啶化合物以除去1-取代基，从而形成包含4-（仲或叔）氨基 - 吡啶的产物介质。
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4.发明授权Supernucleophilic 4-substituted-pyridine catalysts, and processes useful for preparing same 有权超亲核性4-取代吡啶催化剂及其制备方法公开(公告)号：US06603010B2
公开(公告)日：2003-08-05
申请号：US09993046
申请日：2001-11-06
IPC分类号： C07D21302
CPC分类号： C07D213/73 , B01J31/0237 , B01J31/0244 , B01J35/023 , B01J37/0063 , B01J2231/4205 , C07D213/74 , C07D213/84
摘要： Described are preferred processes for producing extrusion-granulated supernucleophilic 4-amino-substituted pyridine catalysts, and granular products obtainable thereform. Also described are preferred activation-substitution-deactivation processes for producing 4-aminopyridine compounds, which involve the use of acrylic acid or acrylamide or analogs thereof for activation, and substitution steps conducted under mild basic conditions in an excess of the amine reagent for 4-substitution. Such processes provide improved reacted masses which are more readily processed to recover the products in pure, heat-stable form. Further, described are processes for preparing 4-substituted-pyridines via pyridine betaines.
摘要翻译： 描述了用于生产挤压造粒的超亲核4-氨基取代的吡啶催化剂的优选方法，以及可获得的颗粒产品。 还描述了用于生产4-氨基吡啶化合物的优选的活化取代失活方法，其涉及使用丙烯酸或丙烯酰胺或其类似物进行活化，以及在温和的碱性条件下在过量的胺试剂中进行4-取代 - 代换。 这些方法提供改进的反应物质，其更容易加工以以纯的，热稳定的形式回收产物。 此外，描述了通过吡啶甜菜碱制备4-取代吡啶的方法。
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5.发明授权Process for the preparation of 3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 有权3,5-二乙基-1,2-二氢-1-苯基-2-丙基吡啶的制备方法公开(公告)号：US07151181B2
公开(公告)日：2006-12-19
申请号：US11351783
申请日：2006-02-10
IPC分类号： C07D211/02
CPC分类号： C07D211/82
摘要： Methods are provided for improving production of 3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine (DHP). In one illustrative embodiment, the methods involve controlling the rate of reaction and temperature of the reaction during formation of DHP. In another illustrative embodiment, the methods involve neutralizing the acid catalyst subsequent to DHP formation.
摘要翻译： 提供了用于改善3,5-二乙基-1,2-二氢-1-苯基-2-丙基吡啶（DHP）的生产的方法。 在一个说明性实施方案中，所述方法包括在形成DHP期间控制反应速率和反应温度。 在另一说明性实施方案中，所述方法包括在DHP形成之后中和酸催化剂。
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6.发明授权
公开(公告)号：US5403906A
公开(公告)日：1995-04-04
申请号：US142708
申请日：1993-10-25
CPC分类号： C08F26/08
摘要： Described are preferred processes for producing linear polyvinylpyridines. The processes involve the use of hydrogen peroxide to initiate polymerization of vinylpyridine monomers in an alcohol/water solvent. Processes of the invention provide good reaction rates and conversions, and are particularly advantageous in achieving control of the M.sub.w 's of the final product polymers.
摘要翻译： 描述的是制备直链聚乙烯吡啶的优选方法。 该方法涉及使用过氧化氢引发乙烯基吡啶单体在醇/水溶剂中的聚合。 本发明的方法提供良好的反应速率和转化率，并且在实现对最终产物聚合物的Mw的控制方面特别有利。
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公开(公告)号：US07687513B1
公开(公告)日：2010-03-30
申请号：US11254782
申请日：2005-10-21
申请人： Mark Muldoon , Joan F. Brennecke , Edward J. Maginn , Eric F. V. Scriven , Colin H. McAteer , Ramiah Murugan
发明人： Mark Muldoon , Joan F. Brennecke , Edward J. Maginn , Eric F. V. Scriven , Colin H. McAteer , Ramiah Murugan
IPC分类号： A01N43/40 , A61K31/435
CPC分类号： A61K31/435 , C07D213/20 , C07D213/74 , C07D213/80 , C07D401/04 , C10M133/40 , C10M171/00 , C10M2201/081 , C10M2201/082 , C10M2201/087 , C10M2207/122 , C10M2215/16 , C10M2215/221 , C10M2219/04 , C10M2219/042 , C10N2220/04 , C10N2230/08 , C10N2230/72 , C10N2240/10 , C10N2240/14
摘要： Disclosed herein are aminopyridinium cations and compositions containing these cations. Piperidino pyridinium cations and compositions containing these cations are also described. Ionic compositions, particularly liquid ionic compositions that contain the aminopyridinium cation or piperidino pyridinium cation are also described. Methods of enhancing the thermal stability of a compound, particularly an ionic compound, using the aminopyridinium or piperidino pyridinium cations, are also presented. Compositions having an expanded liquidus range of from about −73° C. to about 444° C. are also described. Solvents, heat transfer fluids, and lubricants having improved thermal stability characteristics and an expanded and improved liquidus range are also disclosed.
摘要翻译： 本文公开了氨基吡啶鎓阳离子和含有这些阳离子的组合物。 还描述了哌啶子基吡啶鎓阳离子和含有这些阳离子的组合物。 还描述了离子组合物，特别是含有氨基吡啶鎓阳离子或哌啶子基吡啶鎓阳离子的液体离子组合物。 还提出了使用氨基吡啶鎓或哌啶子基吡啶鎓阳离子增强化合物，特别是离子化合物的热稳定性的方法。 还描述了具有约-73℃至约444℃的扩大液相线范围的组合物。 还公开了具有改进的热稳定性特征和膨胀和改善的液相线范围的溶剂，传热流体和润滑剂。
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8.发明授权
公开(公告)号：US5824756A
公开(公告)日：1998-10-20
申请号：US615309
申请日：1996-08-02
CPC分类号： C08F26/06 , C08F8/06 , C08F8/44 , C08F2800/10 , C08F2800/20
摘要： Described are preferred processes for producing linear polyvinylpyridines. The processes involve the use of hydrogen peroxide to initiate polymerization of vinylpyridine monomers in an aqueous solvent. Processes of the invention provide good reaction rates and conversions, and are particularly advantageous in achieving control of the M.sub.w 's of the final product polymers.
摘要翻译： PCT No.PCT / US94 / 12150 Sec。 371日期：1996年8月2日 102（e）日期1996年8月2日PCT 1994年10月25日PCT PCT。 公开号WO95 / 11926 日期1995年5月4日描述了制备直链聚乙烯吡啶的优选方法。 该方法涉及使用过氧化氢引发乙烯基吡啶单体在水性溶剂中的聚合。 本发明的方法提供良好的反应速率和转化率，并且在实现对最终产物聚合物的Mw的控制方面特别有利。
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公开(公告)号：US06365738B1
公开(公告)日：2002-04-02
申请号：US09342294
申请日：1999-06-29
申请人： Ramiah Murugan , Eric F. V. Scriven
发明人： Ramiah Murugan , Eric F. V. Scriven
IPC分类号： C07D23936
CPC分类号： C07D213/80 , C07D213/61 , C07D215/04 , C07D239/36 , C07D239/38
摘要： Described are preferred processes for preparing heterocycles having one or more nitrogen and/or oxygen heteroatoms, utilizing a 1,3-dihalopropene as an effective 3-carbon fragment. Preferred processes yield pyridines, quinolines, oxazoles, pyrimidines and pyrazoles, depending upon the other reactant or reactants utilized with the 1,3-dihalopropene.
摘要翻译： 描述的是制备具有一个或多个氮和/或氧杂原子的杂环的优选方法，利用1,3-二卤代丙烯作为有效的3-碳片段。 取决于与1,3-二卤丙烯一起使用的其它反应物或反应物，优选的方法产生吡啶，喹啉，恶唑，嘧啶和吡唑。
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公开(公告)号：US06391995B1
公开(公告)日：2002-05-21
申请号：US09781095
申请日：2001-02-09
IPC分类号： C08F12606
摘要： Described are preferred processes for preparing quaternary amine polymers of good color, comprising preparing a free base amine polymer by polymerizing a free base amine monomer in the presence of a water-soluble azo initiator, and subjecting the resultant polymer to quaternization conditions. Also described are unique, water-soluble quaternary amine polymers obtainable by such processes, and dye complexing polymer blends useful in the manufacture of detergents.
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