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公开(公告)号：US4769173A
公开(公告)日：1988-09-06
申请号：US128256
申请日：1987-12-03
CPC分类号： C11D3/38627
摘要： The invention relates to the use of a certain class of lipases together with strong bleaching agents in detergent compositions. This class of lipases consists of fungal lipases ex Humicola lanuginosa or Thermomyces lanuginosus, and bacterial lipases which show a positive immunological cross-reaction with the antibody of the lipase produced by Chromobacter viscosum var. lipolyticum NRRL B-3673. The strong bleaching agents are stronger than the sodium perborate/TAED system, i.e. stronger than peracetic acid or they yield, on perhydrolysis, a peracid faster than the sodium perborate/TAED system.
摘要翻译： 本发明涉及某些类别的脂肪酶与强力漂白剂在洗涤剂组合物中的应用。 这类脂肪酶由来自Humicola lanuginosa或Thermomyces lanuginosus的真菌脂肪酶和细菌脂肪酶组成，其显示与Chromobacter viscosum var产生的脂肪酶的抗体的阳性免疫交叉反应。 脂肪分解素NRRL B-3673。 强的漂白剂比过硼酸钠/ TAED系统更强，即比过乙酸更强，或者它们在过水解时产生比过硼酸钠/ TAED系统更快的过酸。
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2.发明授权Enzymatic detergent and bleaching composition containing a specific rDNA technique cloned lipase 失效含有特定的RDNA技术克隆液的酶洗涤剂和漂白组合物
公开(公告)号：US5069809A
公开(公告)日：1991-12-03
申请号：US541184
申请日：1990-06-19
CPC分类号： C11D3/3907 , C11D3/38627 , C11D3/3945 , C12N9/20
摘要： An enzymatic detergent and bleaching composition contains a bleaching system which is stronger than the sodium perborate/TAED system. In such a composition a lipase is employed which is produced by cloning, by rDNA technique, the gene which encodes the lipase produced by the fungas Humicola lanuginosa and expressing that gene in Aspergillus oryzae as host. The lipase is used in an amount giving a lipolytic enzyme activity of from 100 to 0.005 lipolytic units/mg of the composition.
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公开(公告)号：US4873016A
公开(公告)日：1989-10-10
申请号：US57075
申请日：1987-06-03
申请人： David Thom , Ton Swarthoff , Jan Maat
发明人： David Thom , Ton Swarthoff , Jan Maat
CPC分类号： C11D3/38627
摘要： The invention relates to a detergent composition comprising lipases. By inclusion of a certain, immunologically defined class of lipases in a detergent composition which comprises a mixture of an anionic and a nonionic detergent, an improved overall detergency is obtained. Typical suitable lipases are obtained from certain Pseudomonas and Chromobacter strains.
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公开(公告)号：US4707291A
公开(公告)日：1987-11-17
申请号：US870252
申请日：1986-06-03
申请人： David Thom , Ton Swarthoff , Jan Maat
发明人： David Thom , Ton Swarthoff , Jan Maat
CPC分类号： C11D3/38627
摘要： The invention relates to a detergent composition comprising lipases. By inclusion of a certain, immunologically defined class of lipases in a detergent composition which comprises a mixture of an anionic and a nonionic detergent, an improved overall detergency is obtained. Typical suitable lipases are obtained from certain Pseudomonas and Chromobacter strains.
摘要翻译： 本发明涉及包含脂肪酶的洗涤剂组合物。 通过在包含阴离子和非离子洗涤剂的混合物的洗涤剂组合物中包含某些免疫限定类型的脂肪酶，获得了改进的总洗涤性。 典型的合适的脂肪酶是从某些假单胞菌属和Chromobacter菌株获得的。
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公开(公告)号：US5133893A
公开(公告)日：1992-07-28
申请号：US726639
申请日：1991-07-02
申请人： David Thom , Ton Swarthoff , Jan Maat
发明人： David Thom , Ton Swarthoff , Jan Maat
CPC分类号： C11D3/38627
摘要： The invention relates to a detergent composition comprising lipases. By inclusion of a certain immunologically defined class of lipases in a detergent composition which comprises as detergent-active material solely an anionic synthetic detergent, and as builder a water-soluble inorganic or organic builder salt, an improved overall detergency is obtained. The builder salt is typically sodium tripolyphosphate or sodium carbonate, and the lipase is typically obtained from certain Pseudomonas or Chromobacter strains.
摘要翻译： 本发明涉及包含脂肪酶的洗涤剂组合物。 通过在洗涤剂组合物中包含某些免疫学定义类别的脂肪酶，其仅包含作为洗涤剂活性物质的阴离子合成洗涤剂，并且作为助洗剂是水溶性无机或有机助洗剂盐，获得了改善的总洗涤性。 助洗剂盐通常是三聚磷酸钠或碳酸钠，并且脂肪酶通常从某些假单胞菌属或Chromobacter菌株获得。
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公开(公告)号：US07049278B2
公开(公告)日：2006-05-23
申请号：US10645657
申请日：2003-08-22
CPC分类号： C11D3/38654 , C11D3/168 , C11D3/3932 , C11D3/3942 , C11D3/3945 , C11D17/041
摘要： The invention relates to catalytically bleaching substrates, especially laundry fabrics, with atmospheric oxygen and a peroxyl species. A method of bleaching a substrate is provided that comprises applying to the substrate, in an aqueous medium, a specified organic substance which forms a complex with a transition metal, the complex catalysing bleaching of the substrate by atmospheric oxygen and a peroxyl species. Also provided is a bleaching composition comprising, in an aqueous medium, atmospheric oxygen and an organic substance which forms a complex with a transition metal, the complex catalysing bleaching of the substrate by the atmospheric oxygen, wherein the aqueous medium is provided with a peroxygen bleach or a peroxy-based or peroxy-generating bleach system.
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公开(公告)号：US06380146B1
公开(公告)日：2002-04-30
申请号：US09596994
申请日：2000-06-20
申请人： Greta Johanna Breel , Daniel Convents , Willem Van Liemt , Ton Swarthoff , Robin Stefan Twisker
发明人： Greta Johanna Breel , Daniel Convents , Willem Van Liemt , Ton Swarthoff , Robin Stefan Twisker
IPC分类号： C11D742
CPC分类号： C11D3/30 , C11D3/26 , C11D3/349 , C11D3/38609 , C11D3/3942
摘要： There is provided a bleaching detergent composition comprising one or more surfactants, a phenol oxidizing enzyme and a compound which acts as enhancer for the phenol oxidizing enzyme, said composition having an Enhancer Index as herein defined of at least 12 and prefereably in the range of 15-50.
摘要翻译： 提供了一种漂白洗涤剂组合物，其包含一种或多种表面活性剂，酚氧化酶和充当酚氧化酶的增强剂的化合物，所述组合物具有如本文所定义的至少12并且优选在15范围内的增强子指数 -50。
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公开(公告)号：US06323014B1
公开(公告)日：2001-11-27
申请号：US09596998
申请日：2000-06-20
申请人： Greta Johanna Breel , Daniel Convents , Willem Van Liemt , Ton Swarthoff , Robin Stefan Twisker
发明人： Greta Johanna Breel , Daniel Convents , Willem Van Liemt , Ton Swarthoff , Robin Stefan Twisker
IPC分类号： C12N996
CPC分类号： C11D3/26 , C11D3/30 , C11D3/349 , C11D3/38609 , C11D3/3942
摘要： There is provided a process for enhancing the activity of a phenol oxidizing enzyme, comprising adding to the enzyme, as an enhancer for the activity of the enzyme, one or more compounds having the formula: wherein: A is an optionally substituted electron-withdrawing group, chosen from the group consisting of nitrile, carboxyl, and esters and salts thereof, amides, aldehydes, ketones, sulfoxides, sulfones, or sulphonates, and B is an optionally substituted electron-donating group, chosen from the group consisting of the oxide anion, sulfide anion, oxides, amines, imines, hydroxides, sulfides, ethers, carboxylic acids, and halogen substituents, and R1-R5 may each independently represent hydrogen, hydroxy, halogen, nitroso, formyl, carboxyl, and esters and salts thereof, carbamoyl, sulfo, and esters and salts hereof, sulfamoyl, nitro, amino, phenyl, C1-C20 alkyl, C1-C8 alkoxy, carbonyl-C1-C6-alkoxy, aryl-C1-C6-alkyl, and R2 and R5 together may form an alkylene group or an alkenylene group.
摘要翻译： 提供了一种增强酚氧化酶的活性的方法，包括向酶中加入作为酶活性的增强剂，一种或多种具有下式的化合物：其中：A是任选取代的吸电子基团 选自腈，羧基及其酯和盐，酰胺，醛，酮，亚砜，砜或磺酸盐，B是任选取代的给电子基团，其选自氧化物阴离子， 硫化物阴离子，氧化物，胺，亚胺，氢氧化物，硫化物，醚，羧酸和卤素取代基，R 1 -R 5可各自独立地表示氢，羟基，卤素，亚硝基，甲酰基，羧基及其酯和盐，氨基甲酰基， ，和其酯和盐，氨磺酰，硝基，氨基，苯基，C 1 -C 20烷基，C 1 -C 8烷氧基，羰基-C 1 -C 6 - 烷氧基，芳基-C 1 -C 6烷基和R 2和R 5一起可以形成亚烷基 基团或亚烯基。
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公开(公告)号：US6107264A
公开(公告)日：2000-08-22
申请号：US991328
申请日：1997-12-16
申请人： Marcel van der Helm , Monique van der Heiden , Dirk Herman Hondmann , Annelies Smits , Ton Swarthoff , Cornelis Theodorus Verrips
发明人： Marcel van der Helm , Monique van der Heiden , Dirk Herman Hondmann , Annelies Smits , Ton Swarthoff , Cornelis Theodorus Verrips
CPC分类号： C11D3/38654
摘要： There is provided an enzymatic bleach composition comprising one or more surfactants and an enzyme of extracellular origin, capable of oxidizing substrates by the build-in of one or more oxygen atoms into the substrate using molecular oxygen, in particular a dioxygenase from extracellular origin, and a process for bleaching stains present on fabrics comprising treating the stained fabrics with said composition.
摘要翻译： 提供了包含一种或多种表面活性剂和细胞外起始酶的酶促漂白组合物，其能够通过使用分子氧（特别是来自细胞外起始物的双加氧酶）将一个或多个氧原子内置到底物中来氧化底物，以及 用于漂白织物上存在的污渍的方法，包括用所述组合物处理染色的织物。
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10.发明授权
公开(公告)号：US5244594A
公开(公告)日：1993-09-14
申请号：US703555
申请日：1991-05-21
申请人： Thomas L. F. Favre , Ronald Hage , Karin Van der Helm-Rademaker , Jean H. Koek , Rudolf J. Martens , Ton Swarthoff , Marten R. P. van Vliet
发明人： Thomas L. F. Favre , Ronald Hage , Karin Van der Helm-Rademaker , Jean H. Koek , Rudolf J. Martens , Ton Swarthoff , Marten R. P. van Vliet
IPC分类号： B01J31/18 , B01J31/28 , B01J31/32 , C07B61/00 , C07D255/02 , C07D341/00 , C07F13/00 , C11D3/39 , C11D3/395 , C11D7/54 , D06L3/00 , D06L3/02
CPC分类号： C11D3/3932
摘要： Novel bleach and oxidation catalysts, a method of bleaching substrates using these catalysts and bleaching (detergent) compositions containing the catalysts are reported.The catalysts are a manganese-based co-ordination complex of the general formula:[L.sub.n Mn.sub.m X.sub.p ].sup.z Y.sub.qwherein Mn is manganese in the IV-oxidation state; n and m are independent integers from 2-8; X represents a co-ordination or bridging species; p is an integer from 0-32; Y is a counter-ion, the type of which is dependent on the charge z of the complex which can be positive, zero or negative; q=z/[charge Y]; and L is a ligand which is an organic molecule containing a number of hetero-atoms selected from N, P, O, and S, which co-ordinates via all or some of its hetero-atoms and/or carbon atoms to the Mn.sup.(IV) -center(s), which latter are anti-ferromagnetically coupled.
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