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公开(公告)号：US5145922A
公开(公告)日：1992-09-08
申请号：US736214
申请日：1991-07-26
IPC分类号： C08F10/00
CPC分类号： C08F10/00
摘要： A process for preparing an olefin polymerization catalyst which comprises halogenating a magnesium-di-(3- or 4-halo- or 3- or 4-C.sub.1 to C.sub.8 alkoxy-phenoxide) with a halide of tetravalent titanium in the presence of a halohydrocarbon, recovering the solid reaction product from the reaction mixture and combining the solid reaction product with an organo aluminium compound and an electron donor.
摘要翻译： 一种制备烯烃聚合催化剂的方法，该方法包括在卤代烃的存在下用四价钛的卤化物卤化二 - （3-或4-卤代或3-或4-甲氧基-C 8烷氧基 - 苯氧基） 从反应混合物中回收固体反应产物，并将固体反应产物与有机铝化合物和电子给体结合。
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2.发明授权Solid alkene polymerization catalyst components and process for their preparation 失效固体烯烃聚合催化剂组分及其制备方法
公开(公告)号：US5328877A
公开(公告)日：1994-07-12
申请号：US5956
申请日：1993-01-19
CPC分类号： C08F10/00
摘要： A solid catalyst component for alkene polymerization comprising a magnesium halide, an electron donor and a phenoxy-titanium halide, the latter being a dihalophenoxy-titanium halide or a dialkoxyphenoxy-titanium halide in which the alkoxy groups each have from 1 to 8 carbon atoms.
摘要翻译： 用于烯烃聚合的固体催化剂组分包括卤化镁，电子给体和苯氧基 - 卤化钛，后者是二卤代苯氧基 - 卤化钛或二烷氧基苯氧基 - 卤化钛，其中烷氧基各自具有1至8个碳原子。
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3.发明授权Solid alkene polymerization catalyst components and process for their preparation 失效固体烯烃聚合催化剂组分及其制备方法
公开(公告)号：US5225385A
公开(公告)日：1993-07-06
申请号：US892714
申请日：1992-05-29
CPC分类号： C08F10/00
摘要： A solid catalyst component for alkene polymerization comprising a magnesium halide, an electron donor and a phenoxy-titanium halide, the latter being a dihalophenoxy-titanium halide or a dialkoxyphenoxy-titanium halide in which the alkoxy groups each have from 1 to 8 carbon atoms.
摘要翻译： 用于烯烃聚合的固体催化剂组分包括卤化镁，电子给体和苯氧基 - 卤化钛，后者是二卤代苯氧基 - 卤化钛或二烷氧基苯氧基 - 卤化钛，其中烷氧基各自具有1至8个碳原子。
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公开(公告)号：US5081087A
公开(公告)日：1992-01-14
申请号：US599031
申请日：1990-10-17
CPC分类号： C08F10/00
摘要： A process for preparing an olefin polymerization catalyst which comprises halogenating a magnesium-di-(3-halo- or 3- C.sub.1 to C.sub.8 alkoxy-phenoxide) with a halide of tetravalent titanium in the presence of a halohydrocarbon, recovering the solid reaction product from the reaction mixture and combining the solid reaction product with an organo aluminium compound and an electron donor.
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公开(公告)号：US5061666A
公开(公告)日：1991-10-29
申请号：US513979
申请日：1990-04-24
申请人： John C. Chadwick , Bart J. Ruisch
发明人： John C. Chadwick , Bart J. Ruisch
CPC分类号： C08F10/00
摘要： A process for preparing a solid catalyst component which comprises halogenating a magnesium compound in the formula MgRR.sup.1.nCO.sub.2 l in which R and R.sup.1 are the same or different alkoxy or phenoxy groups and n is a number of from 0 to 2 with a halide of tetravalent titanium in the presence of dialkylester of a dihydric aromatic carboxylic acid and an inert hydrocarbon diluent by reacting at a temperature of from 120.degree. to 136.degree. C. and recovering the solid reaction product from the reaction mixture.
摘要翻译： 一种制备固体催化剂组分的方法，其包括使式MgRR1.nCO2I中的镁化合物卤化，其中R和R1是相同或不同的烷氧基或苯氧基，n是0至2的数，与四价卤化物 在二元芳族羧酸和惰性烃稀释剂的二烷基酯存在下，在120-136℃的温度下反应，并从反应混合物中回收固体反应产物。
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公开(公告)号：US4396749A
公开(公告)日：1983-08-02
申请号：US355083
申请日：1982-03-05
IPC分类号： C08F2/00 , C08F283/00 , C08G18/63 , C08L25/00
CPC分类号： C08F283/00 , C08G18/63
摘要： Composite polymers, especially composite polyols containing active hydrogen atoms can be prepared by polymerizing one or more olefinically unsaturated compounds in the presence of a liquid polymer containing active hydrogen atoms and a modified initiator; the modification comprising the reaction between a liquid polymer containing one or more groups which can react with isocyanato groups and a compound containing two or more isocyanato groups which has been partially converted by reacting it with an organic hydroperoxide or a free-radical initiator also containing additional active hydrogen atoms. The composite polymers exhibit a stable dispersed polymer phase and can be suitably applied as starting materials for polyurethane foams.
摘要翻译： 复合聚合物，特别是含活性氢原子的复合多元醇可以通过在含有活性氢原子的液体聚合物和改性引发剂的存在下聚合一种或多种烯属不饱和化合物来制备; 该改性包括含有一个或多个可与异氰酸酯基团反应的基团的液体聚合物与含有两个或更多个异氰酸酯基的化合物之间的反应，所述化合物通过与有机氢过氧化物或自由基引发剂反应而部分转化， 活性氢原子。 复合聚合物表现出稳定的分散聚合物相，可适用作聚氨酯泡沫的原料。
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公开(公告)号：US5034361A
公开(公告)日：1991-07-23
申请号：US527804
申请日：1990-05-24
CPC分类号： C08F10/00
摘要： Normally sparingly soluble magnesium alkoxide is solubilized in alkanol by the additional presence of certain acidic materials. The resulting solution is used to produce a mixture of substantially spherical particles, substantially free of fines, containing an adduct magnesium alkoxide. The particles are converted by conventional methods to a procatalyst precursor of an olefin polymerization catalyst of good activity and good selectivity to stereoregular polymer whenever appropriate, which catalyst produces polymer product of good morphology.
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公开(公告)号：US5132379A
公开(公告)日：1992-07-21
申请号：US765885
申请日：1991-09-26
申请人： John C. Chadwick , Bart J. Ruisch
发明人： John C. Chadwick , Bart J. Ruisch
CPC分类号： C08F10/00
摘要： A process for preparing a solid catalyst component which comprises halogenating a magnesium compound in the formula MgRR.sup.1.nCO.sub.2 in which R and R.sup.1 are the same or different alkoxy or phenoxy groups and n is a number of from 0 to 2 with a halide of tetravalent titanium in the presence of dialkylester of a dihydric aromatic carboxylic acid and an inert hydrocarbon diluent by reacting at a temperature of from 120.degree. to 136.degree. C. and recovering the solid reaction product from the reaction mixture.
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公开(公告)号：US4728704A
公开(公告)日：1988-03-01
申请号：US14556
申请日：1987-02-13
IPC分类号： C07C29/70 , C07C27/00 , C07C31/30 , C07C67/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00
摘要： A process for preparing spherical particles of a compound with the general formula Mg(OR).sub.2-a (OR').sub.a is disclosed. In the process R is an alkyl group with from 2 to 8 carbon atoms, R' is an alkyl group with from 1 to 7 carbon atoms and a is a number of from 0 to 0.5. The process comprises preparing a homogeneous solution of a compound Mg(OR).sub.2 in an aliphatic alcohol with the general formula R'OH, spray-drying the solution at a temperature of from 15.degree. to 85.degree. C., suspending the spray-dried solid particles in an aliphatic alcohol with the formula ROH in which R is the same alkyl group as present in the said compound Mg(OR).sub.2, heating the suspension in order to remove an alcohol with the formula R'OH from the liquid phase by distillation and separating the solid particles from the liquid phase.
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公开(公告)号：US4663299A
公开(公告)日：1987-05-05
申请号：US885496
申请日：1986-07-14
IPC分类号： C07C29/70 , C07C27/00 , C07C31/30 , C07C67/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00
摘要： A process for preparing spherical particles of a compound with the general formula Mg(OR).sub.2-a (OR').sub.a is disclosed. In the process R is an alkyl group with from 2 to 8 carbon atoms, R' is an alkyl group with from 1 to 7 carbon atoms and a is a number of from 0 to 0.5. The process comprises preparing a homogeneous solution of a compound Mg(OR).sub.2 in an aliphatic alcohol with the general formula R'OH, spray-drying the solution at a temperature of from 15.degree. to 85.degree. C., suspending the spray-dried solid particles in an aliphatic alcohol with the formula ROH in which R is the same alkyl group as present in the said compound Mg(OR).sub.2, heating the suspension in order to remove an alcohol with the formula R'OH from the liquid phase by distillation and separating the solid particles from the liquid phase.
摘要翻译： 公开了制备具有通式Mg（OR）2-a（OR'）a的化合物的球形颗粒的方法。 在该方法中，R是具有2至8个碳原子的烷基，R'是具有1至7个碳原子的烷基，a是0至0.5的数。 该方法包括在通式为R'OH的脂族醇中制备化合物Mg（OR）2的均匀溶液，在15℃至85℃的温度下喷雾干燥该溶液，将喷雾干燥 在ROH中的脂族醇中的固体颗粒，其中R是与所述化合物Mg（OR）2中存在的相同的烷基，加热该悬浮液以便从液相中除去具有式R'OH的醇，由 蒸馏并从液相中分离固体颗粒。
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