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    Compositions comprising transition metals for treating and monitoring liquid systems
    2.
    发明授权
    Compositions comprising transition metals for treating and monitoring liquid systems 失效
    包含用于处理和监测液体体系的过渡金属的组合物

    公开(公告)号：US5200106A

    公开(公告)日：1993-04-06

    申请号：US585899

    申请日：1990-09-20

    申请人： John E. Hoots ,  Rodney H. Banks ,  Donald A. Johnson

    发明人： John E. Hoots ,  Rodney H. Banks ,  Donald A. Johnson

    IPC分类号： G01N33/18

    CPC分类号： G01N33/1813 ,  G01N33/182 ,  Y10T436/13

    摘要： Methods for utilizing transition metals as tracers in aqueous liquid systems are provided by this invention. Transition metals with low background levels in system waters are identified as preferred when soluble in said aqueous liquid systems. The transition metals show low levels of deposition on equipment scale and provide reliable information as to the process history of the liquid systems.

    摘要翻译： 在水性液体体系中利用过渡金属作为示踪剂的方法由本发明提供。 在可溶于所述含水液体体系中，在系统水中具有低背景水平的过渡金属被确定为优选的。 过渡金属在设备规模上显示出低沉积水平，并为液体系统的工艺历史提供可靠的信息。

    Monitoring performance of a treating agent added to a body of water
    3.
    发明授权
    Monitoring performance of a treating agent added to a body of water 失效
    监测添加到水体中的处理剂的性能

    公开(公告)号：US5006311A

    公开(公告)日：1991-04-09

    申请号：US497681

    申请日：1990-03-23

    申请人： John E. Hoots ,  Rodney H. Banks

    发明人： John E. Hoots ,  Rodney H. Banks

    IPC分类号： G01N33/18

    CPC分类号： G01N33/1893 ,  G01N33/1813 ,  Y10T436/13

    摘要： Analyzing the level of a treating agent and/or stress metals in a body of water containing an inert transition metal tracer added to the water proportionally with the treating agent by determining the absorbance (first absorbance value) of a reagent dye added to water, said dye producing a second absorbance value when reacted at the same concentration with the tracer and stress metals in a measure of said body of water, and said dye producing a third absorbance value when reacted at the same concentration with only the transition metal contained in a measure of said body of water; determining the second and third absorbance values and resolving their differences to determine the concentration of the tracer and, separately, the concentration of said stress metals.

    Monitoring performance of a water treating agent by measuring and resolving optical voltage analogs
    4.
    发明授权
    Monitoring performance of a water treating agent by measuring and resolving optical voltage analogs 失效
    通过测量和分辨光电压模拟量来监测水处理剂的性能

    公开(公告)号：US5132096A

    公开(公告)日：1992-07-21

    申请号：US619097

    申请日：1990-12-21

    申请人： John E. Hoots ,  Rodney H. Banks

    发明人： John E. Hoots ,  Rodney H. Banks

    IPC分类号： G01N33/18

    CPC分类号： G01N33/1813 ,  G01N33/1893 ,  Y10T436/13

    摘要： Analyzing the level of a treating agent and/or stress metals in a body of water containing an inert transition metal tracer added to the water proportionally with the treating agent by determining the absorbance (first absorbance value) of a reagent dye added to water, said dye producing a second absorbance value when reacted at the same concentration with the tracer and stress metals in a measure of said body of water, and said dye producing a third absorbance value when reacted at the same concentration with only the transition metal contained in a measure of said body of water; determining the second and third absorbance values and resolving their differences to determine the concentration of the tracer and, separately, the concentration of said stress metals.

    摘要翻译： 通过测定添加到水中的试剂染料的吸光度（第一吸光度值），分析加入到水中的惰性过渡金属示踪剂的处理剂和/或应力金属与处理剂成比例的水平， 当与所述示踪剂和应力金属以所述水体的量相同的浓度与所述示踪剂和应力金属反应时，所述染料产生第二吸光度值，并且当所述染料以相同浓度与仅包含在测量中的过渡金属反应时产生第三吸光度值 的水体; 确定第二和第三吸光度值并分辨它们的差异以确定示踪剂的浓度，并分别确定所述应力金属的浓度。

    Zinc stabilization with modified acrylamide based polymers and corrosion inhibition derived therefrom
    5.
    发明授权
    Zinc stabilization with modified acrylamide based polymers and corrosion inhibition derived therefrom 失效
    具有改性丙烯酰胺基聚合物的锌稳定化及其衍生的腐蚀抑制

    公开(公告)号：US5049310A

    公开(公告)日：1991-09-17

    申请号：US419567

    申请日：1989-10-10

    申请人： Donald A. Johnson ,  John E. Hoots ,  Dodd W. Fong ,  Guy A. Crucil

    发明人： Donald A. Johnson ,  John E. Hoots ,  Dodd W. Fong ,  Guy A. Crucil

    IPC分类号： C02F5/12 ,  C23F11/08

    CPC分类号： C02F5/125 ,  C23F11/08 ,  C23F11/173 ,  C23F14/02

    摘要： New zinc stabilizing polymers containing at least 5 mole percent of a monomer represented by the structure: ##STR1## wherein: R is independently, at each occurrence, chosen from H and lower (C.sub.1 -C.sub.4) alkyl groups;R' is a hydrocarbonaceous bridging group containing from 1-12 carbon atoms;X is chosen from --SO.sub.3 M, --OH, --COOM groups or mixtures thereof,M is hydrogen or some other cation species; andn ranges from 1-10,are described. Also, the use of these polymers in combination with zinc salts, and in further combination with phosphate salts, to inhibit corrosion of iron containing metals, and other metals, when these metals are exposed to industrial waters is demonstrated. Deposit control or scale inhibition on these metals exposed to industrial waters is also observed.

    摘要翻译： 含有至少5摩尔％的由以下结构表示的单体的新的锌稳定化聚合物：其中：R各自独立地选自H和低级（C 1 -C 4）烷基; R'是含有1-12个碳原子的烃基桥联基团; X选自-SO 3 M，-OH，-COOM基团或其混合物，M是氢或一些其它阳离子物质; 并描述n的范围为1-10。 此外，证明了当这些金属暴露于工业水中时，这些聚合物与锌盐的组合以及与磷酸盐的进一步组合用于抑制含铁金属和其它金属的腐蚀。 也观察到暴露于工业水域的这些金属的沉积物控制或垢垢抑制。

    Cooling water corrosion inhibition method
    8.
    发明授权
    Cooling water corrosion inhibition method 失效
    冷却水腐蚀抑制方法

    公开(公告)号：US4923634A

    公开(公告)日：1990-05-08

    申请号：US155393

    申请日：1988-02-12

    申请人： John E. Hoots ,  Donald A. Johnson ,  Dodd W. Fong ,  James F. Kneller

    发明人： John E. Hoots ,  Donald A. Johnson ,  Dodd W. Fong ,  James F. Kneller

    IPC分类号： C23F11/08

    CPC分类号： C23F11/08

    摘要： A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, where R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms,and substituted alkyl of from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide, (poly)carboxy and (poly)hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.

    摘要翻译： 一种通过用含有能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐的组合物给予水，并且含有至少为6.5的烃聚合物的含有硬度和pH至少为6.5的工业冷却水中的腐蚀的方法 具有酰胺结构的N-取代丙烯酰胺聚合物如下：其中R 2是氢或甲基，其中R 1是氢或烷基，R是亚烷基或亚苯基，X是磺酸根，（多）羟基，（聚） 羧基或羰基，及其组合; 或含有具有N-取代的马来酰胺酸单元，N-取代的马来酰亚胺单元和具有如下结构的马来酸（和盐）单元的衍生化马来酸酐均聚物，共聚物和三元共聚物：其中R 1，R 2和R 3各自为 独立地选自氢，羟基，羧基烷基，羧基酰胺，苯基，取代的苯基，1至10个碳原子的直链或支链烷基和1至10个碳原子的取代烷基，其中取代基是膦酸; 次膦酸 磷酸酯; 磺酸 硫酸酯，羧酰胺，（多）羧基和（多）羟基，烷氧基和羧酸酯基团; 及其组合。

    Cooling water corrosion inhibition method
    9.
    发明授权
    Cooling water corrosion inhibition method 失效
    冷却水腐蚀抑制方法

    公开(公告)号：US4929425A

    公开(公告)日：1990-05-29

    申请号：US155397

    申请日：1988-02-12

    申请人： John E. Hoots ,  Donald A. Johnson ,  Dodd W. Fong ,  James F. Kneller

    发明人： John E. Hoots ,  Donald A. Johnson ,  Dodd W. Fong ,  James F. Kneller

    IPC分类号： C23F11/08

    CPC分类号： C23F11/08

    摘要： A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, where R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms, and substituted alkyl or from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide, (poly)carboxy and (poly)hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.

    摘要翻译： 一种通过用含有能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐的组合物给予水，并且含有至少为6.5的烃聚合物的含有硬度和pH至少为6.5的工业冷却水中的腐蚀的方法 具有酰胺结构的N-取代丙烯酰胺聚合物如下：其中R 2是氢或甲基，其中R 1是氢或烷基，R是亚烷基或亚苯基，X是磺酸根，（多）羟基，（聚） 羧基或羰基，及其组合; 或含有具有N-取代的马来酰胺酸单元，N-取代的马来酰亚胺单元和具有以下结构的马来酸（和盐）单元的衍生化马来酸酐均聚物，共聚物和三元共聚物：其中R 1，R 2和R 3各自为 独立地选自氢，羟基，羧基烷基，羧基酰胺，苯基，取代的苯基，1至10个碳原子的直链或支链烷基和取代的烷基或1至10个碳原子，其中取代基是膦酸; 次膦酸 磷酸酯; 磺酸 硫酸酯，羧酰胺，（多）羧基和（多）羟基，烷氧基和羧酸酯基团; 及其组合。