公开(公告)号：US4994236A

公开(公告)日：1991-02-19

申请号：US311412

申请日：1989-02-15

申请人： John R. Mihalisin ,  Michelle K. Tripucka

发明人： John R. Mihalisin ,  Michelle K. Tripucka

IPC分类号： C22C1/02 ,  C22C1/03

CPC分类号： C22C1/03 ,  C22C1/023

摘要： A method of making high melting point alloys. The reactive and non-reactive charge materials are separately refined as initial alloys, generally as an alloy of a base element selected from the iron group of the Periodic Table, such as nickel, and at least one metallic element other than the base element. At least one first initial alloy and at least one second initial alloy are provided. The metallic elements other than the base element in the first initial alloys are relatively non-reactive in the molten state, whereas the metallic elements in the second initial alloys are relatively reactive in the molten state. Amounts of the first and second initial alloys are selected to yield a predetermined composition of the high melting point alloy upon melting. The selected amounts are melted to form a molten mixture having the predetermined composition, and then the molten mixture is solidified.

摘要翻译： 制造高熔点合金的方法。 反应性和非反应性电荷材料被分别精制为初始合金，通常作为选自元素周期表铁基的碱金属元素的合金，例如镍，以及至少一种除基体元素以外的金属元素。 提供至少一种第一初始合金和至少一种第二初始合金。 第一初始合金中除基体元件之外的金属元素在熔融状态下相对不反应，而第二初始合金中的金属元素在熔融状态下相对反应。 选择第一和第二初始合金的量，以在熔化时产生高熔点合金的预定组成。 将选择的量熔化以形成具有预定组成的熔融混合物，然后使熔融混合物固化。

公开(公告)号：US4140555A

公开(公告)日：1979-02-20

申请号：US849352

申请日：1977-11-07

申请人： Willard Garcia ,  Jerry A. Butzer ,  John R. Mihalisin ,  Gerald W. Hulit

发明人： Willard Garcia ,  Jerry A. Butzer ,  John R. Mihalisin ,  Gerald W. Hulit

IPC分类号： C22C19/05

CPC分类号： C22C19/055

摘要： A nickel-base casting superalloy consisting essentially (by weight of the alloy) of 7% to 25% chromium, 02.% to 7% aluminum, 0.2% to 6% titanium, 0.01% to 0.25% carbon, up to 0.2% zirconium, up to 0.15% boron, up to 3% hafnium, at least 5% of a matrix-strengthening element selected from the group consisting of 0 to 25% cobalt, 0 to 10% molybdenum, 0 to 13% tungsten to 6% tantalum, 0 to 5% columbium, and 0 to 1.5% vanadium, a carbide shape controller selected from 0.022% to 0.15% magnesium, 0.005% to 0.1% calcium, or mixtures thereof, and the balance nickel except for impurties, said alloy in the as-cast condition having a fine grain macrostructure in thick as well as thin sections, exhibiting a microstructure having precipitated carbide particles which are substantially equi-axed in shape and well-distributed through the alloy with a substantial portion of the magnesium and/or calcium content of the alloy concentrated in such particles and at grain boundaries, and displaying in its thick sections a tensile strength and elongation substantially higher than a corresponding thick-section alloy having a microstructure exhibiting script-like carbide particles substantially free internally and at grain boundaries of said carbide shape controller.

摘要翻译： 基本上由合金的重量比为7％至25％的铬，0.02％至7％的铝，0.2％至6％的钛，0.01％至0.25％的碳，至多0.2％的锆的镍基铸造超级合金 ，至多0.15％的硼，至多3％的铪，至少5％的选自0至25％的钴，0至10％的钼，0至13％的钨至6％的钽的基质强化元素 ，0〜5％的铌和0〜1.5％的钒，碳化物形状控制器，其选自0.022〜0.15％的镁，0.005〜0.1％的钙或其混合物，余量为镍以外的所述合金， 具有在厚的和薄的部分中具有细晶粒宏观结构的铸态条件，显示出具有沉积的碳化物颗粒的微观结构，所述沉积碳化物颗粒的形状基本上是等角的，并且通过合金分布有大部分的镁和/或钙 合金的含量集中在这种颗粒和晶界处，并在其中显示 ck截面的拉伸强度和伸长率显着高于具有基本上在内部和在所述碳化物形状控制器的晶界处自由度的脚本状碳化物微粒的相应的厚截面合金。

公开(公告)号：US20080163962A1

公开(公告)日：2008-07-10

申请号：US11197085

申请日：2005-08-04

申请人： John Corrigan ,  Russell G. Vogt ,  John R. Mihalisin ,  John K. Bennett ,  Uwe Paul ,  Christoph Mayr ,  Winfried Esser

发明人： John Corrigan ,  Russell G. Vogt ,  John R. Mihalisin ,  John K. Bennett ,  Uwe Paul ,  Christoph Mayr ,  Winfried Esser

IPC分类号： C22F1/10

CPC分类号： C22C19/056 ,  C22C19/057

摘要： Directionally solidified columnar grain nickel base alloy casting consisting essentially of, in weight %, of about 11.6% to 12.70% Cr, about 8.50 to 9.5% Co, about 1.65% to 2.15% Mo, about 3.5% to 4.10% W, about 4.80% to 5.20% Ta, about 3.40 to 3.80% Al, about 3.9% to 4.25% Ti, about 0.05% to 0.11% C, about 0.003% to 0.015% B, balance essentially Ni and having substantial transverse stress rupture strength and ductility as compared to a similar casting without boron present.

摘要翻译： 基本上由重量％，约11.6％至12.70％的Cr，约8.50至9.5％的Co，约1.65％至2.15％的Mo，约3.5％至4.10％的W，约4.80的重量％组成的定向凝固的柱状晶粒镍基合金铸件 ％至5.20％的Ta，约3.40至3.80％的Al，约3.9％至4.25％的Ti，约0.05％至0.11％的C，约0.003％至0.015％的B，余量基本上为Ni，具有显着的横向应力断裂强度和延展性 与没有硼存在的类似铸件相比。

公开(公告)号：US5759303A

公开(公告)日：1998-06-02

申请号：US701162

申请日：1996-08-21

申请人： John R. Mihalisin ,  John Corrigan ,  Robert J. Baker ,  Eric L. Leonard ,  Jay L. Vandersluis

发明人： John R. Mihalisin ,  John Corrigan ,  Robert J. Baker ,  Eric L. Leonard ,  Jay L. Vandersluis

IPC分类号： C22C19/05

CPC分类号： C22C19/057

摘要： A nickel base superalloy composition consisting essentially of, in weight %, 9.3-10.0% Co, 6.4-6.8% Cr, 0.5-0.7% Mo, 6.2-6.6% W, 6.3-6.7% Ta, 5.45-5.75% Al, 0.8-1.2% Ti, 0.07-0.12% Hf, 2.8-3.2% Re, and balance essentially Ni wherein a carbon concentration of about 0.01 to about 0.08 weight % is provided for improving the cleanliness of a single crystal investment casting produced therefrom.

公开(公告)号：US5549765A

公开(公告)日：1996-08-27

申请号：US390437

申请日：1995-02-16

申请人： John R. Mihalisin ,  John Corrigan ,  Robert J. Baker ,  Eric L. Leonard ,  Jay L. Vandersluis

发明人： John R. Mihalisin ,  John Corrigan ,  Robert J. Baker ,  Eric L. Leonard ,  Jay L. Vandersluis

IPC分类号： C22C19/05

CPC分类号： C22C19/057

摘要： A nickel base superalloy composition consisting essentially of, in weight %, 9.3-10.0% Co, 6.4-6.8% Cr, 0.5-0.7% Mo, 6.2-6.6% W, 6.3-6.7% Ta, 5.45-5.75% Al, 0.8-1.2% Ti, 0.07-0.12% Hf, 2.8-3.2% Re, and balance essentially Ni wherein a carbon concentration of about 0.01 to about 0.08 weight % is provided for improving the cleanliness of a single crystal investment casting produced therefrom.

摘要翻译： 一种镍基超级合金组合物，主要由重量％，9.3-10.0％Co，6.4-6.8％Cr，0.5-0.7％Mo，6.2-6.6％W，6.3-6.7％Ta，5.45-5.75％Al，0.8 -1.2％Ti，0.07-0.12％Hf，2.8-3.2％Re，余量基本上为Ni，其中碳浓度为约0.01至约0.08重量％，用于改善由其制备的单晶熔模铸造的清洁度。

公开(公告)号：US4401622A

公开(公告)日：1983-08-30

申请号：US255357

申请日：1981-04-20

申请人： Raymond C. Benn ,  John R. Mihalisin ,  Leroy R. Curwick ,  Howard F. Merrick

发明人： Raymond C. Benn ,  John R. Mihalisin ,  Leroy R. Curwick ,  Howard F. Merrick

IPC分类号： C22C19/05

CPC分类号： C22C19/056

摘要： A nickel-chromium-iron alloy intended principally for automotive turbocharger applications, the alloy being characterized by good stress - rupture strength, ductility, tensile strength, etc. and containing, generally speaking, 10-15% Cr, 18-30% Fe, 3-4.25% Ti, 2.25-3.5% Al, Ti+Al from 6 to 7.25%, ratio of Ti to Al of at least 0.9 and up to 1.6, 4-6% Mo, 0.01-0.2% B, 0.03-0.3% C, balance essentially nickel.

摘要翻译： 主要用于汽车涡轮增压器应用的镍铬铁合金，该合金的特点是具有良好的应力 - 断裂强度，延展性，拉伸强度等，并且通常含有10-15％Cr，18-30％Fe， 3-4.25％的Ti，2.25-3.5％的Al，Ti + Al为6〜7.25％，Ti与Al的比例为0.9以上，1.6以下，4〜6％的Mo，0.01-0.2％的B，0.03〜0.3 ％C，平衡镍。

公开(公告)号：US08241560B2

公开(公告)日：2012-08-14

申请号：US10424589

申请日：2003-04-28

申请人： John Corrigan ,  Michael G. Launsbach ,  John R. Mihalisin

发明人： John Corrigan ,  Michael G. Launsbach ,  John R. Mihalisin

IPC分类号： C22C19/05

CPC分类号： C22C19/057 ,  F01D5/28 ,  F05C2201/0466 ,  F05D2300/131 ,  F05D2300/132 ,  F05D2300/133 ,  F05D2300/1723

摘要： A single crystal nickel base superalloy consists essentially of, in weight %, about 6.4% to about 6.8% Cr, about 9.3% to about 10.0% Co, above 6.7% to about 8.5% Ta, about 5.45% to about 5.75% Al, about 6.2% to about 6.6% W, about 0.5% to about 0.7% Mo, about 0.8% to about 1.2% Ti, about 2.8% to about 3.2% Re, up to about 0.12% Hf, about 0.01% to about 0.08% by weight C, up to about 0.10% B, and balance Ni and incidental impurities. The superalloy provides improved alloy cleanliness and castability while providing improved high temperature mechanical properties such as stress rupture life.

摘要翻译： 单晶镍基超级合金基本上由重量％，约6.4％至约6.8％的Cr，约9.3％至约10.0％的Co，高于6.7％至约8.5％的Ta，约5.45％至约5.75％的Al， 约6.2％至约6.6％的W，约0.5％至约0.7％的Mo，约0.8％至约1.2％的Ti，约2.8％至约3.2％的Re，至多约0.12％的Hf，约0.01％至约0.08％ 的C，高达约0.10％的B，并且平衡Ni和附带的杂质。 超耐热合金提供改善的合金清洁度和铸造性，同时提供改善的高温机械性能，如应力断裂寿命。

公开(公告)号：US06231692B1

公开(公告)日：2001-05-15

申请号：US09239358

申请日：1999-01-28

申请人： Russell G. Vogt ,  John Corrigan ,  John R. Mihalisin ,  Ursula Pickert ,  Winfried Esser

发明人： Russell G. Vogt ,  John Corrigan ,  John R. Mihalisin ,  Ursula Pickert ,  Winfried Esser

IPC分类号： C22C1905

CPC分类号： C22C19/056

摘要： Machineable nickel base alloy casting, consisting essentially of, in weight %, about 12.5% to 15% Cr, about 9.00% to 10.00% Co, about 3.70% to 4.30% Mo, about 3.70% to 4.30% W, about 2.80% to 3.20% Al, about 4.80% to 5.20% Ti, about 0.005% to 0.02% B, up to about 0.10% Zr, and balance essentially Ni and carbon below about 0.08 weight % to improve machinability while retaining alloy strength properties after appropriate heat treatment.

摘要翻译： 可机加工的镍基合金铸件，主要由重量％，约12.5％至15％的Cr，约9.00％至10.00％的Co，约3.70％至4.30％的Mo，约3.70％至4.30％的W，约2.80％ 3.20％Al，约4.80％至5.20％的Ti，约0.005％至0.02％的B，至多约0.10％的Zr，余量基本上为Ni和低于约0.08重量％的碳，以提高机械加工性，同时在合适的热处理后保持合金强度性能 。

公开(公告)号：US5922148A

公开(公告)日：1999-07-13

申请号：US805801

申请日：1997-02-25

申请人： Jeffrey D. Irvine ,  Russell G. Vogt ,  Donald L. Bierstine ,  Christine M. Stabile ,  John R. Mihalisin ,  Jeffery S. Smith ,  John P. Kunkle ,  Gail R. Cole ,  Thomas W. Nielsen

发明人： Jeffrey D. Irvine ,  Russell G. Vogt ,  Donald L. Bierstine ,  Christine M. Stabile ,  John R. Mihalisin ,  Jeffery S. Smith ,  John P. Kunkle ,  Gail R. Cole ,  Thomas W. Nielsen

IPC分类号： C21C5/52 ,  C21C7/064 ,  C21C7/10 ,  C22C1/02

CPC分类号： C22C1/02 ,  C21C7/064 ,  C21C5/5241 ,  C21C7/0645 ,  C21C7/10 ,  Y02P10/216 ,  Y02P10/253

摘要： Directionally solidified superalloy components having a bulk sulfur concentration of less than 1 part per million by weight are provided by vacuum melting a charge to form a superalloy melt, desulfurizing the melt by contact with a calcium-bearing desulfurizing agent for a time to reduce sulfur concentration of the melt to less than 1 ppm by weight, casting the melt directly or following solidification and remelting in a ceramic investment mold, and directionally solidifying the melt as cast components without adverse bulk sulfur pick-up subsequent to desulfurization to provide castings having a sulfur content below 1 ppm, such as in the range of hundreds of parts per billion to provide significantly improved oxidation resistance.

摘要翻译： 体积硫浓度小于1重量百万分之一的定向凝固的超合金组分通过真空熔炼电荷形成超合金熔体，通过与含钙脱硫剂接触一段时间来硫化熔体，从而降低硫浓度 的熔体至少于1重量ppm，直接浇注熔体或在陶瓷投资模具中固化和再熔融之后，并将熔体定向凝固成铸造组分，而在脱硫之前不会产生不利的体积硫吸附，以提供具有硫的铸件 含量低于1ppm，例如在百亿分之几的范围内提供显着改善的抗氧化性。