公开(公告)号：US5504129A

公开(公告)日：1996-04-02

申请号：US164030

申请日：1993-12-08

申请人： Gary F. Dandreaux ,  John T. Geoghegan ,  Long S. Wang ,  Lori S. Slovik ,  John H. Hung

发明人： Gary F. Dandreaux ,  John T. Geoghegan ,  Long S. Wang ,  Lori S. Slovik ,  John H. Hung

IPC分类号： C09D193/04 ,  D21H19/44 ,  G03G7/00 ,  C08J11/24

CPC分类号： C09D193/04 ,  D21H19/44 ,  G03G7/0033 ,  G03G7/0046

摘要： The specification discloses an aqueous dispersion for coatings consisting essentially of water and a water dispersible component, wherein the water dispersible component is provided by reacting maleic anhydride with a rosin ester to provide a maleated rosin ester, adding wax and preferably also an ethylene vinyl acetate copolymer to the maleated rosin ester, and adding a tertiary amino alcohol to the mixture to yield the water dispersible component as a reaction product thereof. When used in a coating formulation for paper, clay and/or latex may be added to the formulation. In one preferred embodiment, the dispersion is applied as a coating to paper to enhance toner adhesion to the surface of the paper while also providing a relatively low friction surface.

摘要翻译： 该说明书公开了一种基本上由水和水分散性组分组成的涂料用水性分散体，其中水分散性组分是通过使马来酸酐与松香酯反应而提供的，以提供马来化松香酯，加入蜡，优选还包括乙烯 - 乙酸乙烯酯共聚物 向马来酸化松香酯中加入叔氨基醇，得到作为其反应产物的水分散性成分。 当用于纸的涂料制剂时，可以将粘土和/或胶乳加入制剂中。 在一个优选的实施方案中，分散体作为涂料施加到纸上以增强调色剂对纸表面的粘附性，同时还提供相对较低的摩擦表面。

公开(公告)号：US06274657B1

公开(公告)日：2001-08-14

申请号：US08189053

申请日：1994-01-27

申请人： John T. Geoghegan ,  Long S. Wang

发明人： John T. Geoghegan ,  Long S. Wang

IPC分类号： C08J524

CPC分类号： C08J3/03 ,  C08G65/322 ,  C08J2393/04 ,  C08L71/02 ,  C08L93/04 ,  C09F1/04 ,  C08L2666/04 ,  C08L71/00

摘要： A surfactant for forming stable dispersions of rosin esters compatible with elastomeric latexes, the surfactant having the formula R1—R2—R3. R1 and R3 are each rosin (i.e., rosin, rosin dimer or a mixture of rosin and rosin dimer). R2 is selected from the group consisting of polyethylene glycol and polyethylene glycol-R4-polyethylene glycol wherein R4 is rosin (i.e., rosin, rosin dimer or a mixture of rosin and rosin dimer). The surfactant is prepared by esterifying the rosin material with polyethylene glycol.

摘要翻译： 用于形成与弹性体胶乳相容的松香酯的稳定分散体的表面活性剂，表面活性剂具有式R1-R2-R3。 R1和R3各自是松香（即松香，松香二聚体或松香和松香二聚体的混合物）。 R2选自聚乙二醇和聚乙二醇-R4-聚乙二醇，其中R 4是松香（即松香，松香二聚体或松香和松香二聚体的混合物）。 表面活性剂通过用聚乙二醇酯化松香材料来制备。

公开(公告)号：US5567531A

公开(公告)日：1996-10-22

申请号：US519990

申请日：1995-08-28

申请人： Eric S. Gardiner ,  John T. Geoghegan

发明人： Eric S. Gardiner ,  John T. Geoghegan

IPC分类号： C08J5/00 ,  C08K5/5419 ,  C08L23/00 ,  C08L23/02 ,  C08L23/12 ,  C08L67/00 ,  C08L67/02 ,  B32B27/00

CPC分类号： C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  C08L23/12 ,  C08L67/02 ,  C08L93/04 ,  Y10T428/31663 ,  Y10T428/31855

摘要： A method for forming a polymer with a decreased surface energy. The method comprises the steps of mixing from about 99.5% to about 95.0% of a polymer selected from the group consisting of polyolefin and polyester with from about 0.5% to about 5.0% of a surface modifying agent having the structure R.sup.1 --A--Si (R.sup.2 R.sup.3)--O--[Si(R.sup.4 R.sup.5)--O].sub.n --Si--(R.sup.6 R.sup.7)--A--R.sup.8, and forming the mix of polymer and additive to a desired form. R.sup.1 and R.sup.8 are selected from the group consisting of derivatives of aliphatic or aliphatic/aromatic alcohols or mono-acids with a molecular weight of between about 250 to about 600 daltons, and A is selected from the group consisting of --O--, --NH--C(O)--NH--(CH.sub.2).sub.3 --, and --C(O)--NH--(CH.sub.2).sub.3 --. The agent is substantially intimately mixed with the polymer. The present invention also discloses a polymeric material with an increased surface energy prepared according to the method, a release liner, a method for forming injection molded or blow molded polymeric articles where the articles have a non-fugitive release agent, and a film extrusion processing aid comprising an additive for compounding with a polymeric composition being extruded.

摘要翻译： 一种形成具有降低的表面能的聚合物的方法。 该方法包括以下步骤：将约99.5％至约95.0％的选自聚烯烃和聚酯的聚合物与约0.5％至约5.0％的具有结构R1-A-Si的表面改性剂 R2R3）-O- [Si（R4R5）-O] n-Si-（R6R7）-A-R8，并将聚合物和添加剂的混合物形成所需形式。 R 1和R 8选自脂族或脂族/芳族醇的衍生物或分子量为约250至约600道尔顿的单酸，A选自-O - ， - NH -C（O）-NH-（CH 2）3 - 和-C（O）-NH-（CH 2）3 - 。 该试剂基本上与聚合物密切混合。 本发明还公开了一种根据该方法制备的具有增加的表面能的聚合物材料，一种剥离衬垫，一种用于形成注塑或吹塑聚合物制品的方法，其中制品具有非防泼离解剂，以及膜挤出加工 辅助剂包括与被挤出的聚合物组合物混合的添加剂。

公开(公告)号：US5281438A

公开(公告)日：1994-01-25

申请号：US899998

申请日：1992-06-17

申请人： Eric S. Gardiner ,  John T. Geoghegan

发明人： Eric S. Gardiner ,  John T. Geoghegan

IPC分类号： C08K5/103 ,  C08L23/02 ,  C09J7/02 ,  B32B7/00

CPC分类号： C09J7/0271 ,  C08K5/103 ,  C08L23/02

摘要： A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 200 to about 500 daltons, A and A.sup.1 are selected from the group consisting of O, and S, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.

摘要翻译： 公开了一种用于增加有机聚合物材料，特别是聚烯烃表面的表面能的方法。 该方法包括以约99.5重量％至约90.0重量％的聚合物材料混合，约0.5重量％至约10.0重量％的具有式RA（CHR2（CH2）nA1）mR1的两亲物，其中R和 R1选自分子量为约200至约500道尔顿的脂族或脂族/芳族单酸的烷基，芳基，烷芳基，酰基和芳基酰基衍生物，A和A1选自 由O和S组成，R2选自H，CH 3和C 2 H 5，n为0至3，m为2至20。

公开(公告)号：US5635128A

公开(公告)日：1997-06-03

申请号：US651358

申请日：1996-05-22

申请人： Eric S. Gardiner ,  John T. Geoghegan

发明人： Eric S. Gardiner ,  John T. Geoghegan

IPC分类号： C08J5/00 ,  C08K5/5419 ,  C08L23/00 ,  C08L23/02 ,  C08L23/12 ,  C08L67/00 ,  C08L67/02 ,  B29B15/00

CPC分类号： C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  C08L23/12 ,  C08L67/02 ,  C08L93/04 ,  Y10T428/31663 ,  Y10T428/31855

摘要： A method for forming a polymer with a decreased surface energy. The method comprises the steps of mixing from about 99.5% to about 95.0% of a polymer selected from the group consisting of polyolefin and polyester with from about 0.5% to about 5.0% of a surface modifying agent having the structure R.sup.1 --A--Si(R.sup.2 R.sup.3)--O--[Si(R.sup.4 R.sup.5)--O].sub.n --Si--(R.sup.6 R.sup.7)--A--R.sup.8, and forming the mix of polymer and additive to a desired form. R.sup.1 and R.sup.8 are selected from the group consisting of derivatives of aliphatic or aliphatic/aromatic alcohols or mono-acids with a molecular weight of between about 250 to about 600 daltons, and A is selected from the group consisting of --O--, --NH--C(O)--NH--(CH.sub.2).sub.3 --, and --C(O)--NH--(CH.sub.2).sub.3 --. The agent is substantially intimately mixed with the polymer. The present invention also discloses a polymeric material with an increased surface energy prepared according to the method, a release liner, a method for forming injection molded or blow molded polymeric articles where the articles have a non-fugitive release agent, and a film extrusion processing aid comprising an additive for compounding with a polymeric composition being extruded.

摘要翻译： 一种形成具有降低的表面能的聚合物的方法。 该方法包括以下步骤：将约99.5％至约95.0％的选自聚烯烃和聚酯的聚合物与约0.5％至约5.0％的具有结构R1-A-Si的表面改性剂 R2R3）-O- [Si（R4R5）-O] n-Si-（R6R7）-A-R8，并将聚合物和添加剂的混合物形成所需形式。 R 1和R 8选自脂族或脂族/芳族醇的衍生物或分子量为约250至约600道尔顿的单酸，A选自-O - ， - NH -C（O）-NH-（CH 2）3 - 和-C（O）-NH-（CH 2）3 - 。 该试剂基本上与聚合物密切混合。 本发明还公开了一种根据该方法制备的具有增加的表面能的聚合物材料，一种剥离衬垫，一种用于形成注塑或吹塑聚合物制品的方法，其中制品具有非防泼离解剂，以及膜挤出加工 辅助剂包括与被挤出的聚合物组合物混合的添加剂。

公开(公告)号：US5473002A

公开(公告)日：1995-12-05

申请号：US126382

申请日：1993-09-23

申请人： Eric S. Gardiner ,  John T. Geoghegan

发明人： Eric S. Gardiner ,  John T. Geoghegan

IPC分类号： C08J5/00 ,  C08K5/5419 ,  C08L23/00 ,  C08L23/02 ,  C08L23/12 ,  C08L67/00 ,  C08L67/02 ,  C08K5/54

CPC分类号： C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  C08L23/12 ,  C08L67/02 ,  C08L93/04 ,  Y10T428/31663 ,  Y10T428/31855

摘要： A method for forming a polymer with a decreased surface energy. The method comprises the steps of mixing from about 99.5% to about 95.0% of a polymer selected from the group consisting of polyolefin and polyester with from about 0.5% to about 5.0% of a surface modifying agent having the structure R.sup.1 --A--Si(R.sup.2 R.sup.3)--O--[Si(R.sup.4 R.sup.5)--O].sub.n --Si--(R.sup.6 R.sup.7)--A--R.sup.8, and forming the mix of polymer and additive to a desired form. R.sup.1 and R.sup.8 are selected from the group consisting of derivatives of aliphatic or aliphatic/aromatic alcohols or mono-acids with a molecular weight of between about 250 to about 600 daltons, and A is selected from the group consisting of --O--, --NH--C(O)--NH(CH.sub.2).sub.3 --, and --C(O)--NH--(CH.sub.2).sub.3 --. The agent is substantially intimately mixed with the polymer. The present invention also discloses a polymeric material with an increased surface energy prepared according to the method, a release liner, a method for forming injection molded or blow molded polymeric articles where the articles have a non-fugitive release agent, and a film extrusion processing aid comprising an additive for compounding with a polymeric composition being extruded.

摘要翻译： 一种形成具有降低的表面能的聚合物的方法。 该方法包括以下步骤：将约99.5％至约95.0％的选自聚烯烃和聚酯的聚合物与约0.5％至约5.0％的具有结构R1-A-Si的表面改性剂 R2R3）-O- [Si（R4R5）-O] n-Si-（R6R7）-A-R8，并将聚合物和添加剂的混合物形成所需形式。 R 1和R 8选自脂族或脂族/芳族醇的衍生物或分子量为约250至约600道尔顿的单酸，A选自-O - ， - NH -C（O）-NH（CH 2）3 - 和-C（O）-NH-（CH 2）3 - 。 该试剂基本上与聚合物密切混合。 本发明还公开了一种根据该方法制备的具有增加的表面能的聚合物材料，一种剥离衬垫，一种用于形成注塑或吹塑聚合物制品的方法，其中制品具有非防泼离解剂，以及膜挤出加工 辅助剂包括与被挤出的聚合物组合物混合的添加剂。

公开(公告)号：US5271991A

公开(公告)日：1993-12-21

申请号：US909145

申请日：1992-07-06

申请人： Eric S. Gardiner ,  John T. Geoghegan

发明人： Eric S. Gardiner ,  John T. Geoghegan

IPC分类号： C08K5/103 ,  C08L23/02 ,  C09J7/02 ,  B32B5/00

CPC分类号： C09J7/0271 ,  C08K5/103 ,  C08L23/02 ,  Y10T428/24802 ,  Y10T428/31855

摘要： A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 200 to about 500 daltons, A and A.sup.1 are selected from the group consisting of O, and S, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.

摘要翻译： 公开了一种用于增加有机聚合物材料，特别是聚烯烃表面的表面能的方法。 该方法包括以约99.5重量％至约90.0重量％的聚合物材料混合，约0.5重量％至约10.0重量％的具有式RA（CHR2 [CH2] nA1）mR1的两亲物，其中R和 R1选自分子量为约200至约500道尔顿的脂族或脂族/芳族单酸的烷基，芳基，烷芳基，酰基和芳基酰基衍生物，A和A1选自 由O和S组成，R2选自H，CH 3和C 2 H 5，n为0至3，m为2至20。