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公开(公告)号:US4257972A
公开(公告)日:1981-03-24
申请号:US62357
申请日:1979-07-31
CPC分类号: B01J31/20 , B01J31/1845 , C07C29/15 , C12C11/02 , B01J2531/822 , Y02P20/52
摘要: A novel catalyst and process for the manufacture of polyhydric alcohol(s) from synthesis gas. This novel catalyst is a rhodium carbonyl phosphido cluster compound. In particular, the anion cluster of the rhodium carbonyl phosphido compound is of the following empirical formula:[Rh.sub.9 P (CO).sub.21 ].sup.-2
摘要翻译: 一种用于从合成气制造多元醇的新型催化剂和方法。 这种新型催化剂是羰基磷酰基簇化合物。 特别地,羰基铑化合物的阴离子簇具有以下经验式:[Rh 9 P(CO)21] -2
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公开(公告)号:US4180517A
公开(公告)日:1979-12-25
申请号:US958383
申请日:1978-11-07
IPC分类号: C07C27/06 , B01J31/00 , B01J31/18 , B01J31/20 , C07C27/00 , C07C29/15 , C07C29/151 , C07C29/158 , C07C31/18 , C07C67/00 , C07C31/06
CPC分类号: C07C29/158 , B01J31/20 , C07C29/1512 , C07C29/1514 , B01J2531/822 , Y02P20/52
摘要: A novel catalyst and process for the manufacture of polyhydric alcohol(s) from synthesis gas. This novel catalyst is a rhodium carbonyl phosphido cluster compound. In particular, the anion cluster of the rhodium carbonyl phosphido compound is of the following empirical formula:[Rh.sub.9 P (CO).sub.21 ].sup.-2
摘要翻译: 一种用于从合成气制造多元醇的新型催化剂和方法。 这种新型催化剂是羰基磷酰基簇化合物。 特别地,羰基铑化合物的阴离子簇具有以下经验式:[Rh 9 P(CO)21] -2
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公开(公告)号:US4199520A
公开(公告)日:1980-04-22
申请号:US919857
申请日:1978-06-28
申请人: Lowell A. Cosby , Rocco A. Fiato , Jose L. Vidal
发明人: Lowell A. Cosby , Rocco A. Fiato , Jose L. Vidal
IPC分类号: C01G55/00 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/06 , C07C29/15 , C07C29/151 , C07C29/158 , C07C31/04 , C07C31/18 , C07C67/00 , C07F15/00
CPC分类号: B01J31/0239 , B01J31/0204 , B01J31/0237 , B01J31/0271 , B01J31/20 , C07C29/151 , C07C29/1514 , C07C29/158 , B01J2231/641 , B01J2531/0211 , B01J2531/822 , B01J31/226 , Y02P20/52
摘要: A novel catalyst and process for the manufacture of polyhydric alcohols from synthesis gas. This novel catalyst is a rhodium carbonyl sulfur cluster compound. In particular, the anion cluster of the rhodium carbonyl sulfur compound is of the following empirical formula:[RH.sub.17 (S).sub.2 (CO).sub.32 ].sup.-3
摘要翻译: 用于从合成气制造多元醇的新型催化剂和方法。 这种新型催化剂是一种铑羰基硫簇化合物。 特别地,羰基铑羰基化合物的阴离子簇具有以下经验式:[RH17(S)2(CO)32]
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