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公开(公告)号:US11180671B2
公开(公告)日:2021-11-23
申请号:US16626419
申请日:2018-06-29
Applicant: KAO CORPORATION
Inventor: Masashi Inoue , Daiki Kawata
IPC: C09D11/322 , B41M5/00 , B41M5/52 , C09D11/023 , C09D11/033 , C09D11/037 , C09D11/107
Abstract: The present invention relates to a water-based ink containing at least pigment-containing water-insoluble crosslinked polymer particles (A), a polymer emulsion (B) and water, in which a water-insoluble crosslinked polymer constituting the crosslinked polymer particles (A) is obtained by subjecting a polymer that contains a constitutional unit derived from a carboxylic acid monomer having an acid value of not less than 200 mgKOH/g and a constitutional unit derived from a hydrophobic monomer, to crosslinking reaction with an epoxy compound, and a polymer constituting the polymer emulsion (B) contains a constitutional unit derived from a carboxylic acid monomer and a constitutional unit derived from a hydrophobic monomer. The water-based ink of the present invention is excellent in ejection stability and fastness of the printed characters or images while maintaining good optical density.
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公开(公告)号:US11773278B2
公开(公告)日:2023-10-03
申请号:US17503816
申请日:2021-10-18
Applicant: KAO CORPORATION
Inventor: Masashi Inoue , Daiki Kawata
IPC: C09D11/322 , B41M5/00 , B41M5/52 , C09D11/023 , C09D11/033 , C09D11/037 , C09D11/107 , C09D11/106 , C09D11/326 , B41J2/21 , B41J2/01
CPC classification number: C09D11/322 , B41J2/01 , B41J2/2107 , B41M5/0023 , B41M5/5254 , C09D11/023 , C09D11/033 , C09D11/037 , C09D11/106 , C09D11/107 , C09D11/326
Abstract: The present invention relates to a water-based ink containing at least pigment-containing water-insoluble crosslinked polymer particles (A), a polymer emulsion (B) and water, in which a water-insoluble crosslinked polymer constituting the crosslinked polymer particles (A) is obtained by subjecting a polymer that contains a constitutional unit derived from a carboxylic acid monomer having an acid value of not less than 200 mgKOH/g and a constitutional unit derived from a hydrophobic monomer, to crosslinking reaction with an epoxy compound, and a polymer constituting the polymer emulsion (B) contains a constitutional unit derived from a carboxylic acid monomer and a constitutional unit derived from a hydrophobic monomer. The water-based ink of the present invention is excellent in ejection stability and fastness of the printed characters or images while maintaining good optical density.
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公开(公告)号:US11505709B2
公开(公告)日:2022-11-22
申请号:US16957189
申请日:2018-12-25
Applicant: KAO CORPORATION
Inventor: Daiki Kawata , Masashi Inoue , Tomoaki Il
IPC: C09D11/107 , B41M5/00 , C09D11/033 , C09D11/322 , B41J2/01 , B41J2/21
Abstract: The present invention relates to [1] a water-based ink containing water-insoluble polymer particles (A), an organic solvent (B) and water, in which a polymer constituting the water-insoluble polymer particles (A) is in the form of a crosslinked polymer; the organic solvent (B) contains a polyhydric alcohol ether; and a rate of change in viscosity of the organic solvent (B) as calculated according to the formula (1) is not more than 140%, and [2] a printing method of printing characters or images on a printing medium using the water-based ink described in the above [1], in which a water absorption of the printing medium per a unit surface area thereof as measured by contacting the printing medium with pure water for 100 milliseconds is not less than 0 g/m2 and not more than 10 g/m2.
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公开(公告)号:US09670374B2
公开(公告)日:2017-06-06
申请号:US15106965
申请日:2014-12-18
Applicant: KAO CORPORATION
Inventor: Yuki Wakabayashi , Hirotaka Takeno , Daiki Kawata
IPC: G01D11/00 , C09D11/36 , C09D11/322 , B41J2/01
CPC classification number: C09D11/36 , B41J2/01 , C09D11/322 , C09D11/38
Abstract: The present invention provides a water-based ink for ink-jet printing which is excellent in ejection stability and storage stability, in particular, excellent in quick-drying fixing properties and image uniformity when printing characters or images on a low-water absorbing recording medium, and an image forming method using the water-based ink. The present invention relates to [1] a water-based ink for ink-jet printing, including a pigment, a water-insoluble polymer, an organic solvent (C) and water, in which the organic solvent (C) includes diethylene glycol isopropyl ether (DEGPE) and an organic solvent (c2) having a 1-octanol/water partition coefficient that is smaller than that of DEGPE; a total content of the pigment, the water-insoluble polymer and DEGPE in the water-based ink is not less than 5.0% by mass; and a value obtained by multiplying a total content of the pigment and the water-insoluble polymer in the water-based ink by a content of DEGPE in the water-based ink is from 10 and 300; and [2] an image forming method including the steps of mounting a container filled with the water-based ink to an ink-jet printing apparatus equipped with an ink ejecting means; and ejecting the ink onto a recording medium having a water absorption of from 0 to 10 g/m2 as measured by contacting with pure water for 100 ms to print characters or images thereon.
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