公开(公告)号：US20180248223A1

公开(公告)日：2018-08-30

申请号：US15754630

申请日：2016-08-23

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Ho Sung KIM ,  Min-Young KIM ,  Seung Hoon YANG ,  Jinsub LIM ,  Duck Rye CHANG ,  Jong Ho LEE

IPC: H01M10/0562 ,  H01M10/0585 ,  H01M10/0525

CPC classification number: H01M10/0562 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0585 ,  H01M2300/0071

Abstract: Disclosed is a method of preparing a solid electrolyte, which includes (a) preparing a solid electrolyte precursor slurry by subjecting a mixed solution including a metal precursor solution, containing a lanthanum precursor, a zirconium precursor and an aluminum precursor, a complexing agent, and a pH controller to coprecipitation, (b) preparing a solid electrolyte precursor by washing and drying the solid electrolyte precursor slurry, (c) preparing a mixture by mixing the solid electrolyte precursor with a lithium source, and (d) preparing an aluminum-doped lithium lanthanum zirconium oxide (LLZO) solid electrolyte by calcining the mixture, and which is also capable of adjusting the aluminum content of a starting material to thus control sintering properties and of adjusting the composition of a precursor and a lithium source to thus control the crystal structure, thereby improving the ionic conductivity of the solid electrolyte. In addition, a method of manufacturing an all-solid-state lithium secondary battery, including a solid electrolyte having improved ion conductivity, can be provided using the method of preparing the solid electrolyte.