Modified vinyl alcohol polymer, method for producing same, dispersion stabilizer for suspension polymerization, and method for producing vinyl polymer

    公开(公告)号:US11414507B2

    公开(公告)日:2022-08-16

    申请号:US17256843

    申请日:2019-07-04

    申请人: KURARAY CO., LTD.

    IPC分类号: C08F216/06

    摘要: The present invention provides a modified vinyl alcohol polymer having a side chain with an ethylenic double bond, and having reduced a water-insoluble content and superior storage stability in the form of an aqueous solution, methods of making thereof, a modified vinyl alcohol polymer (A) having a degree of saponification of 68 mol % or more and less than 99.9 mol %, and a viscosity-average degree of polymerization of 200 or more and less than 3,000, and comprising a side chain with 0.01 mol % or more and less than 0.50 mol % of a double bond derived from an esterification agent, the esterification agent being one or more selected from the group consisting of (i) itaconic acid and/or derivatives thereof, and (ii) methacrylic acid and/or derivatives thereof, and the modified vinyl alcohol polymer (A) having a peak width W0.05h of at least 2.85 minutes and less than 3.70 minutes at a height of 5% from the baseline in a peak measured by HPLC.

    Polyvinyl acetal composition
    2.
    发明授权

    公开(公告)号:US10392495B2

    公开(公告)日:2019-08-27

    申请号:US14779179

    申请日:2013-03-22

    申请人: KURARAY CO., LTD.

    摘要: A composition including 100 parts by mass of a polyvinyl acetal and 30 to 70 parts by mass of a plasticizer including 0.5 to 100% by mass of a plasticizer containing a polar group and 0 to 99.5% by mass of a plasticizer containing no polar group, a total of the plasticizer containing a polar group and the plasticizer containing no polar group being 100% by mass. When the polyvinyl acetal is analyzed by HPLC using an ODS column having an inner diameter of 4 mm and a length of 1 cm, the polyvinyl acetal exhibits a first peak and a second peak derived from polyvinyl acetals. In addition, a laminated product of a layer including a polyvinyl acetal and a layer including a hydrocarbon-based polymer.