公开(公告)号：US4981569A

公开(公告)日：1991-01-01

申请号：US334999

申请日：1989-04-07

申请人： Karl Schugerl ,  Wilfried Gutknecht

发明人： Karl Schugerl ,  Wilfried Gutknecht

IPC分类号： B01D17/06 ,  B01D61/40 ,  B01F17/52 ,  C01G17/00 ,  C01G28/00

CPC分类号： C01G28/001 ,  B01D61/40 ,  C01G17/003 ,  Y10S423/14 ,  Y10S516/915

摘要： An apparatus for effecting a coalescence in enriched aqueous solutions which contain germanium and/or arsenic is disclosed, said apparatus comprising an emulsion-breaking unit consisting of a breaking cell providing with two electrodes, which are disposed on opposite sides outside cell walls adjacent thereto, and terminals for electric power, the electrodes and the breaking cell being contained in a container which is filled with an insulating medium and surrounded by a Faraday cage, a line for supplying emulsion to the breaking cell, a settling tank, a line for withdrawing the coalesced liquid and for transferring it to the settling tank, a line for withdrawing the membrane-forming organic phase from the settling tank, and means for recycling noncoalesced emulsion from the settling tank to the breaking cell.

公开(公告)号：US4775479A

公开(公告)日：1988-10-04

申请号：US109981

申请日：1987-10-16

申请人： Karl Schugerl ,  Wilfried Gutknecht

发明人： Karl Schugerl ,  Wilfried Gutknecht

IPC分类号： B01D17/06 ,  B01D61/40 ,  B01F17/52 ,  C01G17/00 ,  C01G28/00 ,  B01D17/05

CPC分类号： C01G28/001 ,  B01D61/40 ,  C01G17/003 ,  Y10S423/14 ,  Y10S516/915

摘要： A process for extracting germanium and/or arsenic from an aqueous solution is described. In order to increase the yield and to perform a highly specific separating process, the liquid membrane technology is employed, in which the starting solution is adjusted by means of hydrochloric acid to a concentration in excess of 6 and up to 10 moles HCl/1, a polyisobutylenesuccinic anhydride/polyamine condensation product is used as a surfactant in the organic outer phase of the liquid membrane emulsion is adjusted to a pH value from 0 to 14 while a supply of chlorine ions is precluded.

摘要翻译： 描述了从水溶液中提取锗和/或砷的方法。 为了提高产量并进行高度特异性的分离处理，采用液膜技术，其中通过盐酸将起始溶液调节至浓度超过6和高达10摩尔HCl / 1， 将聚异丁烯基琥珀酸酐/多胺缩合物作为表面活性剂用于液膜乳液的有机外相，调节至pH值为0至14，同时排除氯离子供应。

公开(公告)号：US4904412A

公开(公告)日：1990-02-27

申请号：US204378

申请日：1988-06-09

申请人： Karl Schugerl ,  Wilfried Gutknecht

发明人： Karl Schugerl ,  Wilfried Gutknecht

IPC分类号： B01D17/06 ,  B01D61/40 ,  B01F17/52 ,  C01G17/00 ,  C01G28/00

CPC分类号： C01G28/001 ,  B01D61/40 ,  C01G17/003 ,  Y10S423/14 ,  Y10S516/915

摘要： An emulsion-forming composition for forming an emulsion for use in a process for selectively recovering germanium or arsenic from an aqueous solution thereof by liquid membrane technology is disclosed, said composition consisting essentially of: a solvent mixture consisting essentially of specified amounts of a hydrocarbon which is a predominantly straight-chain saturated C.sub.16 -C.sub.20 hydrocarbon or kerosine, a mononuclear aromatic hydrocarbon (pref. xylene), and a halogenated C.sub.1 -C.sub.5 hydrocarbon (pref. CCl.sub.4); and more than 0.1% by weight of an oil-soluble polyisobutylene-succinic anhydride/polyamine condensation product.

公开(公告)号：US5326441A

公开(公告)日：1994-07-05

申请号：US890602

申请日：1992-07-13

申请人： Ioannis Kirgios ,  Karl Schugerl ,  Wolfgang Degener

发明人： Ioannis Kirgios ,  Karl Schugerl ,  Wolfgang Degener

IPC分类号： B01D61/40 ,  C01G15/00 ,  B01D17/06 ,  B03C5/00 ,  C02F1/48

CPC分类号： C01G15/003

摘要： Process for separating and concentrating gallium from an aqueous solution containing gallium, together with aluminium, zinc and/or copper, charactrized by the following combination of features: (a) preparation of a water-in-oil emulsion consisting of a neutral or alkaline aqueous phase and an organic phase containing an oil-soluble reactant in a homogenizer in a volume ratio of aqueous phase to organic phase of 2:2 to 3:2; (b) dispersion of the water-in-oil emulsion in the aqueous solution containing gallium, which is adjusted to at least 4 mol/l of HCI, in an extractor in a volume ratio of aqueous phase to water-in-oil emulsion of 30:1 to 10:1 until droplets of the water-in-oil emulsion with a diameter less than or equal to 1 mm are obtained; (c) separation of the water-in-oil emulsion from the aqueous continuum and splitting of the emulsion in a reactor with coaxial, double-insulated electrodes in a high-voltage kV/cm and a frequency greater than 50 Hz, the unsplit portion of the water-in-oil emulsion being recycled into step (b); (d) separation of the electrocoalesced organic phase of the water-in-oil emulsion in a gravity separator and recycling of the same into step (a).

摘要翻译： PCT No.PCT / EP90 / 02321 Sec。 371日期：1992年7月13日 102（e）日期1992年7月13日PCT 1990年1月19日PCT PCT。 公开号WO91 / 10621 日期：1991年7月25日。通过以下特征组合，从含有镓的水溶液中分离和浓缩镓的方法以及铝，锌和/或铜特征：（a）制备油包水乳液 由中性或碱性水相和在均化器中含有油溶性反应物的水相与有机相的体积比为2：2至3：2的有机相组成; （b）在萃取器中将油包水乳液分散在含镓的水溶液中，该水溶液被调节至至少4mol / l的HCl，水相体积比与油包水乳液的体积比 30：1至10：1，直到获得直径小于或等于1mm的油包水乳液的液滴; （c）从水相连续体中分离油包水乳液并在具有高压kV / cm和频率大于50Hz的同轴双电绝缘电极的反应器中分离乳液，非分离部分 的油包水乳液被再循环到步骤（b）中; （d）在重力分离器中分离油包水乳液的电聚结有机相，并将其再循环到步骤（a）中。

公开(公告)号：US4777269A

公开(公告)日：1988-10-11

申请号：US44260

申请日：1987-04-30

申请人： Thomas Scheper ,  Martina Weiss ,  Karl Schugerl

发明人： Thomas Scheper ,  Martina Weiss ,  Karl Schugerl

IPC分类号： C07D311/16 ,  C12Q1/34 ,  G01N21/64 ,  G01N21/76 ,  G01N33/52

CPC分类号： C12Q1/34 ,  C07D311/16 ,  C12Q2337/22 ,  C12Q2337/24 ,  G01N2333/948

摘要： 7-Phenylacetic acid-4-alkyl-coumarinyl amides having the formula ##STR1## wherein R is alkyl having 1 to 4, in particular 1 to 2 carbon atoms, optionally substituted by one or more halogen atoms, in particular fluorine atoms, especially methyl or trifluoromethyl, are suitable substances for the fluorometric determination of the activity of hydrolases, in particular of penicillin G-acylase, since by the enzymatic reaction they provide cleavage products which in regard to their fluorescence properties differ drastically from those of the substrate. They can be used in processes for the fluorometric determination of the activity of hydrolases, in particular of penicillin G-acylase.

摘要翻译： 具有式（I）的7-苯基乙酸-4-烷基 - 香豆素酰胺其中R是具有1至4个，特别是1至2个碳原子的烷基，任选地被一个或多个卤素原子，特别是氟原子 特别是甲基或三氟甲基是用于荧光测定水解酶，特别是青霉素G酰基转移酶的活性的合适物质，因为通过酶反应，它们提供裂解产物，其关于它们的荧光特性与底物的荧光特性大不相同 。 它们可用于荧光测定水解酶，特别是青霉素G酰化酶的活性的方法。