公开(公告)号：US20060257776A1

公开(公告)日：2006-11-16

申请号：US11407097

申请日：2006-04-20

申请人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

发明人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

IPC分类号： G03G9/08 ,  C07F15/02

CPC分类号： G03G9/091 ,  C09B45/22 ,  G03G9/09783

摘要： A charge control agent of the present invention comprises aggregate particles of an azo-type iron complex salt represented by the following chemical formula [I] in the chemical formula [I], R1—, R2—, R3—, R4—, R5— and R6— are same or different to each other, n is 0.7 to 0.99, the aggregate particles have an average particle size of 1 to 4 microns and an average particle size of a primary particulate crystalline, that is fined the aggregate particles with ultrasonic irradiation, is at most 3 microns. A toner for developing an electrostatic image comprises a resin for the toner and the charge control agent.

公开(公告)号：US08076465B2

公开(公告)日：2011-12-13

申请号：US10959069

申请日：2004-10-07

申请人： Kazuyoshi Kuroda ,  Masashi Yasumatsu ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata

发明人： Kazuyoshi Kuroda ,  Masashi Yasumatsu ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata

IPC分类号： C09B45/32

CPC分类号： G03G9/09783 ,  C09B45/14 ,  G03G9/091

摘要： A method for manufacturing a charge control agent comprising steps of: an initiative chelating step by reacting with a monoazo compound represented by the following chemical formula [1] (in the chemical formula [1], —Ar1— and —Ar2— are aromatic groups) and a metal chelating agent to prepare an azo-type metal complex salt intermediate; a subsequent ion-exchanging step by reacting with the azo-type metal complex salt intermediate and an ammonium counter ion forming agent including an inorganic ammonium salt and aqueous ammonia to prepare an azo-type metal complex salt having an ammonium ion of a counter ion represented by the following chemical formula [2] (in the chemical formula [2], —Ar1— and —Ar2— are the same as the chemical formula [1]; M is a trivalent metal; B+ is a cation except an ammonium ion; n is from 0.70 to 1.00).

摘要翻译： 一种电荷控制剂的制造方法，包括以下步骤：通过与由下列化学式[1]表示的单偶氮化合物（在化学式[1]中，-Ar 1和-Ar 2）反应的主动螯合步骤是芳族基团 ）和金属螯合剂以制备偶氮型金属络合盐中间体; 随后的离子交换步骤通过与偶氮型金属络合物盐中间体和包含无机铵盐和氨水的铵抗衡离子形成剂反应以制备具有代表性的抗衡离子的铵离子的偶氮型金属络合盐 通过以下化学式[2]（化学式[2]中，-Ar1-和-Ar2-与化学式[1]相同; M为三价金属; B +为除铵离子外的阳离子; n为0.70〜1.00）。

公开(公告)号：US07094513B2

公开(公告)日：2006-08-22

申请号：US10718637

申请日：2003-11-24

申请人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

发明人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

IPC分类号： G03G9/087

CPC分类号： G03G9/091 ,  C09B45/22 ,  G03G9/09783

摘要： A charge control agent of the present invention comprises aggregate particles of an azo-type iron complex salt represented by the following chemical formula [I] in the chemical formula [I], R1—, R2—, R3—, R4—, R5— and R6— are same or different to each other, n is 0.7 to 0.99, the aggregate particles have an average particle size of 1 to 4 microns and an average particle size of a primary particulate crystalline, that is fined the aggregate particles with ultrasonic irradiation, is at most 3 microns. A toner for developing an electrostatic image comprises a resin for the toner and the charge control agent.

摘要翻译： 本发明的电荷控制剂包括化学式[I]中R 1，R 2，R 0，...的化学式[I]表示的偶氮型铁络合盐的聚集体颗粒 R 2，R 3，R 4，R 5，R 6， - 彼此相同或不同，n为0.7至0.99，聚集颗粒的平均粒度为1至4微米，并且通过超声波照射对聚集体颗粒进行精细化的初级颗粒状晶体的平均粒径为 最多3微米。 用于显影静电图像的调色剂包括用于调色剂的树脂和电荷控制剂。

公开(公告)号：US20050250034A1

公开(公告)日：2005-11-10

申请号：US10718637

申请日：2003-11-24

申请人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

发明人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

IPC分类号： C09B45/22 ,  G03G9/09 ,  G03G9/097 ,  G03G9/087

CPC分类号： G03G9/091 ,  C09B45/22 ,  G03G9/09783

摘要： A charge control agent of the present invention comprises aggregate particles of an azo-type iron complex salt represented by the following chemical formula [1] in the chemical formula [I], R1—, R2—, R3—, R4—, R5— and R6— are same or different to each other, n is 0.7 to 0.99, the aggregate particles have an average particle size of 1 to 4 microns and an average particle size of a primary particulate crystalline, that is fined the aggregate particles with ultrasonic irradiation, is at most 3 microns. A toner for developing an electrostatic image comprises a resin for the toner and the charge control agent.

摘要翻译： 本发明的电荷控制剂包括在化学式[I]中，R 1，R 2，R 2， R 2，R 3，R 4，R 5，R 6， - 彼此相同或不同，n为0.7至0.99，聚集颗粒的平均粒度为1至4微米，并且通过超声波照射对聚集体颗粒进行精细化的初级颗粒状晶体的平均粒径为 最多3微米。 用于显影静电图像的调色剂包括用于调色剂的树脂和电荷控制剂。

公开(公告)号：US07479360B2

公开(公告)日：2009-01-20

申请号：US10536404

申请日：2003-11-25

申请人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

发明人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

IPC分类号： G03G9/097 ,  C07F15/02

CPC分类号： G03G9/09783 ,  G03G9/091

摘要： The charge control agent comprises aggregate particles including an azo-type iron complex salt represented by the following chemical formula [VI] (in the chemical formula [VI], B+ is (H+)x(Na+) 1−x and x is mole ratio and 0.6 to 0.9, or B+ is (H+)y(Na+)1−y and y is mole ratio and 0 to 0.2) and the aggregate particles have 0.5 to 5.0 microns of an average particle size. A toner for developing an electrostatic image comprises a resin for the toner and the charge control agent. An image formation process of electrophotography comprises a step for developing an electrostatic latent image on an electrostatic latent image frame by a developer including the toner.

摘要翻译： 电荷控制剂包括由以下化学式[VI]表示的偶氮型铁络合物盐（在化学式[VI]中，B +为（H +）x（Na +）1-x，x为摩尔比 和0.6〜0.9，或B +为（H +）y（Na +）1-y，y为摩尔比，0〜0.2），骨料粒子的平均粒径为0.5〜5.0微米。 用于显影静电图像的调色剂包括用于调色剂的树脂和电荷控制剂。 电子照相术的图像形成方法包括通过包括调色剂的显影剂在静电潜像框上显影静电潜像的步骤。

公开(公告)号：US20060154165A1

公开(公告)日：2006-07-13

申请号：US10536404

申请日：2003-11-25

申请人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

发明人： Masashi Yasumatsu ,  Kazuyoshi Kuroda ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata ,  Heihachi Yushina

IPC分类号： G03G9/097 ,  C07F15/02

CPC分类号： G03G9/09783 ,  G03G9/091

摘要： The charge control agent comprises aggregate particles including an azo-type iron complex salt represented by the following chemical formula [VI] (in the chemical formula [VI], B+ is (H+)x(Na+)1-x and x is mole ratio and 0.6 to 0.9, or B+ is (H+)y(Na+)1-y and y is mole ratio and 0 to 0.2) and the aggregate particles have 0.5 to 5.0 microns of an average particle size. A toner for developing an electrostatic image comprises a resin for the toner and the charge control agent. An image formation process of electrophotography comprises a step for developing an electrostatic latent image on an electrostatic latent image frame by a developer including the toner.

摘要翻译： 电荷控制剂包括包含由以下化学式[VI]表示的偶氮型铁络合物的骨料颗粒（化学式[VI]中，B +）是（H + / SUP>）x 1（x + 1）x-x x，x是摩尔比，0.6-0.9，或B + 其中y是（H +），Y是摩尔比，Y是（H +） 0〜0.2），骨料粒子的平均粒径为0.5〜5.0微米。 用于显影静电图像的调色剂包括用于调色剂的树脂和电荷控制剂。 电子照相术的图像形成方法包括通过包括调色剂的显影剂在静电潜像框上显影静电潜像的步骤。

公开(公告)号：US20050084786A1

公开(公告)日：2005-04-21

申请号：US10959069

申请日：2004-10-07

申请人： Kazuyoshi Kuroda ,  Masahi Yasumatsu ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata

发明人： Kazuyoshi Kuroda ,  Masahi Yasumatsu ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata

IPC分类号： G03G9/087 ,  C09B45/14 ,  G03G9/08 ,  G03G9/09 ,  G03G9/097

CPC分类号： G03G9/09783 ,  C09B45/14 ,  G03G9/091

摘要： A method for manufacturing a charge control agent comprising steps of: an initiative chelating step by reacting with a monoazo compound represented by the following chemical formula [1] (in the chemical formula [1], —Ar1— and —Ar2— are aromatic groups) and a metal chelating agent to prepare an azo-type metal complex salt intermediate; a subsequent ion-exchanging step by reacting with the azo-type metal complex salt intermediate and an ammonium counter ion forming agent including an inorganic ammonium salt and aqueous ammonia to prepare an azo-type metal complex salt having an ammonium ion of a counter ion represented by the following chemical formula [2] (in the chemical formula [2], —Ar1— and —Ar2 are the same as the chemical formula [1]; M is a trivalent metal; B+ is a cation except an ammonium ion; n is from 0.70 to 1.00).

摘要翻译： 一种电荷控制剂的制备方法，包括以下步骤：主动螯合步骤，通过与由下列化学式[1]表示的单偶氮化合物（化学式[1]，-Ar 1 - 和-Ar 2 - 是芳族基团）和金属螯合剂以制备偶氮型金属络盐中间体; 随后的离子交换步骤通过与偶氮型金属络合物盐中间体和包含无机铵盐和氨水的铵抗衡离子形成剂反应以制备具有代表性的抗衡离子的铵离子的偶氮型金属络合盐 通过以下化学式[2]（化学式[2]中，-Ar 1和 - 2）与化学式[1]相同。 M是三价金属; B +是除了铵离子以外的阳离子，n为0.70〜1.00）。

公开(公告)号：US20070231726A1

公开(公告)日：2007-10-04

申请号：US11730446

申请日：2007-04-02

申请人： Osamu Yamate ,  Masashi Yasumatsu

发明人： Osamu Yamate ,  Masashi Yasumatsu

IPC分类号： G03G9/08

CPC分类号： G03G9/09741 ,  C07F7/045 ,  G03G9/09758

摘要： A positive electrified charge control agent comprising a silicon complex compound of an effective component represented by the following chemical formula (I) and/or chemical formula (II) (in the formula (I) and formula (II), [D-(SO3)2]2− is a bivalent anion of an organic acid having at least two sulfonic acid groups, p is 0 or 1, B is a bonding line when p is 0, B is a carbon atom or a nitrogen atom when p is 1, J is a carbon atom or a nitrogen atom, A is an organic group which forms a ring with (B)p and J, both of R are same or different to each other and are an organic group, and these both of R are independent or form a heterocyclic ring). A positive electrified toner for developing an electrostatic image comprises the positive electrified charge control agent. A charge control method of the positive electrified toner for developing the electrostatic image comprises a step for making the toner positively electrified by friction.

摘要翻译： 一种正电荷电荷控制剂，其包含由以下化学式（I）和/或化学式（II）（式（I）和式（II）表示的有效成分的硅配位化合物，[D-（SO 2 - 是具有至少两个磺酸基的有机酸的二价阴离子，p是0或1，B 是当p为0时的键合线，当p为1时，B为碳原子或氮原子，J为碳原子或氮原子时，A为与（B）形成环的有机基团 R，R均相同或不同，为有机基团，R均为独立或形成杂环）。 用于显影静电图像的正极带电调色剂包括正电荷电荷控制剂。 用于显影静电图像的正带电调色剂的电荷控制方法包括通过摩擦使调色剂带正电的步骤。

公开(公告)号：US07875412B2

公开(公告)日：2011-01-25

申请号：US11730446

申请日：2007-04-02

申请人： Osamu Yamate ,  Masashi Yasumatsu

发明人： Osamu Yamate ,  Masashi Yasumatsu

IPC分类号： G03G9/097

CPC分类号： G03G9/09741 ,  C07F7/045 ,  G03G9/09758

摘要： A positive electrified charge control agent comprising a silicon complex compound of an effective component represented by the following chemical formula (I) and/or chemical formula (II) (in the formula (I) and formula (II), [D-(SO3)2]2− is a bivalent anion of an organic acid having at least two sulfonic acid groups, p is 0 or 1, B is a bonding line when p is 0, B is a carbon atom or a nitrogen atom when p is 1, J is a carbon atom or a nitrogen atom, A is an organic group which forms a ring with (B)p and J, both of R are same or different to each other and are an organic group, and these both of R are independent or form a heterocyclic ring). A positive electrified toner for developing an electrostatic image comprises the positive electrified charge control agent. A charge control method of the positive electrified toner for developing the electrostatic image comprises a step for making the toner positively electrified by friction.

摘要翻译： 一种正电荷电荷控制剂，其包含由以下化学式（I）和/或化学式（II）（式（I）和式（II）表示的有效成分的硅配位化合物，[D- ）2] 2-是具有至少两个磺酸基团的有机酸的二价阴离子，p为0或1，B为p为0时的键合线，当p为1时，B为碳原子或氮原子 ，J为碳原子或氮原子，A为与（B）p和J形成环的有机基团，R均相同或不同，为有机基团，R均为 独立或形成杂环）。 用于显影静电图像的正极带电调色剂包括正电荷电荷控制剂。 用于显影静电图像的正带电调色剂的电荷控制方法包括通过摩擦使调色剂带正电的步骤。

公开(公告)号：US20070037083A1

公开(公告)日：2007-02-15

申请号：US11475150

申请日：2006-06-27

申请人： Osamu Yamate ,  Masashi Yasumatsu

发明人： Osamu Yamate ,  Masashi Yasumatsu

IPC分类号： C07F7/04

CPC分类号： C07F7/07

摘要： A positive electrified charge control agent comprises a silicon complex compound represented by the following chemical formula (1) (in the formula (1), [A]− is a sulfate anion). A positive electrified toner for developing an electrostatic image comprises the positive electrified charge control agent. A charge control method of the positive electrified toner for developing the electrostatic image comprises a step for making the toner positively electrified by friction.

摘要翻译： 正电荷电荷控制剂包括由以下化学式（1）表示的硅络合物（在式（1）中，[A] 是硫酸根阴离子）。 用于显影静电图像的正极带电调色剂包括正电荷电荷控制剂。 用于显影静电图像的正带电调色剂的电荷控制方法包括通过摩擦使调色剂带正电的步骤。