公开(公告)号：US08076465B2

公开(公告)日：2011-12-13

申请号：US10959069

申请日：2004-10-07

申请人： Kazuyoshi Kuroda ,  Masashi Yasumatsu ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata

发明人： Kazuyoshi Kuroda ,  Masashi Yasumatsu ,  Osamu Yamate ,  Kaori Sato ,  Jun Hikata

IPC分类号： C09B45/32

CPC分类号： G03G9/09783 ,  C09B45/14 ,  G03G9/091

摘要： A method for manufacturing a charge control agent comprising steps of: an initiative chelating step by reacting with a monoazo compound represented by the following chemical formula [1] (in the chemical formula [1], —Ar1— and —Ar2— are aromatic groups) and a metal chelating agent to prepare an azo-type metal complex salt intermediate; a subsequent ion-exchanging step by reacting with the azo-type metal complex salt intermediate and an ammonium counter ion forming agent including an inorganic ammonium salt and aqueous ammonia to prepare an azo-type metal complex salt having an ammonium ion of a counter ion represented by the following chemical formula [2] (in the chemical formula [2], —Ar1— and —Ar2— are the same as the chemical formula [1]; M is a trivalent metal; B+ is a cation except an ammonium ion; n is from 0.70 to 1.00).

摘要翻译： 一种电荷控制剂的制造方法，包括以下步骤：通过与由下列化学式[1]表示的单偶氮化合物（在化学式[1]中，-Ar 1和-Ar 2）反应的主动螯合步骤是芳族基团 ）和金属螯合剂以制备偶氮型金属络合盐中间体; 随后的离子交换步骤通过与偶氮型金属络合物盐中间体和包含无机铵盐和氨水的铵抗衡离子形成剂反应以制备具有代表性的抗衡离子的铵离子的偶氮型金属络合盐 通过以下化学式[2]（化学式[2]中，-Ar1-和-Ar2-与化学式[1]相同; M为三价金属; B +为除铵离子外的阳离子; n为0.70〜1.00）。

公开(公告)号：US20060280894A1

公开(公告)日：2006-12-14

申请号：US10544679

申请日：2004-01-31

申请人： Horst Berneth ,  Friedrich-Karl Bruder ,  Rainer Hagen ,  Karin Hassenruck ,  Sergusi Kostromine ,  Christa Kruger ,  Timo Meyer-Friedrichsen ,  Rafael Oser ,  Josef-Walter Stawitz

发明人： Horst Berneth ,  Friedrich-Karl Bruder ,  Rainer Hagen ,  Karin Hassenruck ,  Sergusi Kostromine ,  Christa Kruger ,  Timo Meyer-Friedrichsen ,  Rafael Oser ,  Josef-Walter Stawitz

IPC分类号： B32B3/02

CPC分类号： C09B45/20 ,  C09B45/14 ,  C09B45/18 ,  C09B45/22

摘要： The invention provides novel metal complexes for optical data carriers comprising a preferably transparent substrate which may, if desired, have previously been coated with one or more reflection layers and to whose surface a light-writable information layer, if desired one or more reflection layers and if desired a protective layer or a further substrate or a covering layer have been applied, which can be written on and read by means of blue or red light, preferably laser light, where the information layer comprises a light-absorbent compound and, if desired, a binder, characterized in that at least one of the abovementioned metal complexes is used as light-absorbent compound.

摘要翻译： 本发明提供了用于光学数据载体的新型金属络合物，其包括优选透明的基底，如果需要，其可以预先涂覆有一个或多个反射层，并且如果需要，其表面可光可写信息层一个或多个反射层和 如果需要，已经施加了保护层或另外的基底或覆盖层，其可以通过蓝色或红色光（优选激光）写入和读取，其中信息层包含吸光性化合物，并且如果需要 ，粘合剂，其特征在于，使用上述金属配合物中的至少一种作为吸光性化合物。

公开(公告)号：US06596446B2

公开(公告)日：2003-07-22

申请号：US09825322

申请日：2001-04-03

申请人： Mickey Wolf ,  Rolf Richter ,  Kent Faubion ,  Udo Herrmann ,  Josef Witt ,  Peter-Roger Nyssen

发明人： Mickey Wolf ,  Rolf Richter ,  Kent Faubion ,  Udo Herrmann ,  Josef Witt ,  Peter-Roger Nyssen

IPC分类号： G02B520

CPC分类号： C09D11/32 ,  C09B45/14 ,  C09B67/0033 ,  C09D11/328 ,  G03F7/0007

摘要： The invention relates to pigment preparations comprising a metal complex of a mono-, di-, tri-, or tetraanion of an azo compound that in its free acid form conforms to formula (I) or a tautomeric form thereof wherein R and R′ are independently OH, NH2, NH—CN, acylamino, or arylamino, and R1 and R1′ are independently —OH or —NH2, with a metal selected from the group consisting of Na, K, Ca, Sr, Ba, Zn, Fe, Ni, Cu, Mn, La, Li, Cs, Mg, Cd, Co, Al, Cr, Sn, and Pb, wherein the metal complex hosts at least one guest compound.

摘要翻译： 本发明涉及包含偶氮化合物的单，二，三或四阴离子的金属络合物的颜料制剂，其游离酸形式符合式（I）或其互变异构形式，其中R和R'独立地为OH ，NH 2，NH-CN，酰氨基或芳基氨基，R 1和R 1'独立地是-OH或-NH 2，选自Na，K，Ca，Sr，Ba，Zn，Fe，Ni，Cu ，Mn，La，Li，Cs，Mg，Cd，Co，Al，Cr，Sn和Pb，其中金属络合物含有至少一种客体化合物。

公开(公告)号：US06261358B1

公开(公告)日：2001-07-17

申请号：US09415171

申请日：1999-10-08

申请人： Richard Sommer ,  Frank Linke ,  Udo Herrmann ,  Gunther Stolp

发明人： Richard Sommer ,  Frank Linke ,  Udo Herrmann ,  Gunther Stolp

IPC分类号： C09B6700

CPC分类号： C09B45/14 ,  C09B67/0015 ,  C09B67/0029

摘要： Solid pigment preparations comprising as pigment at least one metal complex of an azo compound which in the form of its tautomeric structures conforms to the formula (I) wherein the rings X and Y may each independently bear one or two substituents selected from the group consisting of ═O, ═S, ═NR7, —NR6H7, —OR6, —SR6, —COOR6, —CN, —CONR6R7, —SO2R8, alkyl, cycloalkyl, aryl and aralkyl, the sum total of the endo- and exocyclic double bonds being three for each of the rings X and Y, R6 is hydrogen, alkyl, cycloalkyl, aryl or aralkyl, R7 is hydrogen, cyano, alkyl, cycloalkyl, aryl, aralkyl or acyl, R8 is alkyl, cycloalkyl, aryl or aralkyl, R1, R2, R3 and R4 are each independently hydrogen, alkyl, cycloalkyl, aryl or aralkyl and furthermore, as indicated by the broken lines in the formula (I), may form 5- or 6-membered rings to which further rings may be fused, R5 is —OH, —NR6R7, alkyl, cycloalkyl, aryl or aralkyl, the substituents mentioned for R1 to R8 which contain CH bonds may in turn be substituted, and m, n, o and p are each 1 or, if the ring nitrogen atoms are the starting points for double bonds, as indicated by the dotted lines in the formula (I), may also be zero, and which metal complex hosts at least one other compound as guest compound, characterized in that slurry of the solid pigment preparations with 20 times the amount of water has a pH of >6.5.

摘要翻译： 固体颜料制剂，其包含至少一种偶氮化合物的金属络合物，其以其互变异构结构的形式符合式（I），其中环X和Y可以各自独立地具有一个或两个选自以下的取代基： O，= S，= NR7，-NR6H7，-OR6，-SR6，-COOR6，-CN，-CONR6R7，-SO2R8，烷基，环烷基，芳基和芳烷基，内 - 和外环双键的总和为三 对于环X和Y中的每一个，R 6是氢，烷基，环烷基，芳基或芳烷基，R 7是氢，氰基，烷基，环烷基，芳基，芳烷基或酰基，R 8是烷基，环烷基，芳基或芳烷基 ，R 3和R 4各自独立地为氢，烷基，环烷基，芳基或芳烷基，此外，如式（I）中的虚线所示，可以形成其它环可以稠合的5或6元环，R 5 是-OH，-NR 6 R 7，烷基，环烷基，芳基或芳烷基，对于含有CH键的R1至R8所提及的取代基可以是不同的 并且m，n，o和p各自为1，或者如果环氮原子是双键的起始点，如式（I）中的虚线所示，也可以为零，哪些金属络合物 含有至少一种其它化合物作为客体化合物，其特征在于固体颜料制剂与20倍量的水的浆液的pH值> 6.5。

公开(公告)号：US20010004667A1

公开(公告)日：2001-06-21

申请号：US09729940

申请日：2000-12-06

申请人： Hodogaya Chemical Co.,Ltd.

发明人： Masaki Okubo ,  Hiroshi Nanaumi ,  Masataka Sawano

IPC分类号： G03G009/097 ,  G03G009/00 ,  C09B045/00

CPC分类号： C09B45/14 ,  G03G9/09783

摘要： A organic metal complex compound represented by the following formula (1), which has an electroconductivity of at most 110 nullS/cm when dispersed in ion-exchanged water in an amount of 1 wt %: 1 wherein M is a coordinated center metal selected from the group consisting of Sc, Ti, V, Cr, Co, Ni, Mn and Fe; Ar is an aryl group selected from the group consisting of a substituted or unsubstituted phenyl group and a substituted or unsubstituted naphthyl group, the substituents of which are selected from the group consisting of a C1-C18 alkyl group, a C1-C18 alkoxy group, a nitro group, a halogen group, an alkenyl group, a sulfonamide group, a sulfonalkyl group, a sulfonic acid group, a carboxyl group, a carboxyester group, a hydroxyl group, an acetylamino group, a benzoylamino group, a substituted or unsubstituted anilide group; X and Y are nullSnull, nullOnull, nullCOnull, nullCOOnull, nullNHnull or nullNRnull (R is a C1-C4 alkyl group); Knull is a hydrogen ion, a lithium ion, a sodium ion, a potassium ion, an ammonium ion, an organic ammonium ion, or a mixture thereof; m is a number of an azo compound coordinated to a metal M, and is 1,2,3 or 6; p is a valence of a metal M; n is 1,2 or 4; and q is 0 or an integer.

摘要翻译： 一种由下式（1）表示的有机金属络合物，当分散在离子交换水中时的电导率为至多110μS/ cm 3，其量为1wt％：其中M是选自 由Sc，Ti，V，Cr，Co，Ni，Mn和Fe组成的组; Ar是选自取代或未取代的苯基和取代或未取代的萘基的芳基，其取代基选自C1-C18烷基，C1-C18烷氧基， 硝基，卤素基，烯基，磺酰胺基，磺烷基，磺酸基，羧基，羧酸酯基，羟基，乙酰氨基，苯甲酰氨基，取代或未取代的酰苯胺 组; X和Y是-S - ， - O - ， - CO - ， - COO - ， - NH-或-NR-（R是C1-C4烷基）。 K +是氢离子，锂离子，钠离子，钾离子，铵离子，有机铵离子或其混合物; m是与金属M配位的偶氮化合物的数目，为1,2,3或6; p是金属M的化合价; n为1,2或4; q为0或整数。

公开(公告)号：US06242067B1

公开(公告)日：2001-06-05

申请号：US09420941

申请日：1999-10-19

申请人： Emiko Kambe ,  Atsushi Monden

发明人： Emiko Kambe ,  Atsushi Monden

IPC分类号： B32B302

CPC分类号： G11B7/2495 ,  C09B45/14 ,  C09B69/045 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/247 ,  G11B7/2472 ,  G11B7/2534 ,  G11B7/256 ,  G11B7/2575 ,  G11B7/2595 ,  Y10S428/913 ,  Y10S430/146 ,  Y10T428/21

摘要： In an optical recording medium using writing and reading light having a wavelength of up to 690 nm and having a recording layer and preferably a reflective layer, the recording layer contains a chelate compound having an azo compound of specific structure as a ligand (i.e., azo metal complex dye). This results in an optical recording medium of the heat mode having advantages including the dye's sufficient solubility in a coating solvent which does not attack polycarbonate substrates and improved write/read characteristics with light having a wavelength of up to 690 nm.

摘要翻译： 在使用具有高达690nm的波长的写入和读取光并且具有记录层并且优选地具有反射层的光学记录介质中，记录层含有具有特定结构的偶氮化合物作为配体的螯合化合物（即偶氮 金属络合染料）。 这导致热模式的光学记录介质具有包括染料在不侵蚀聚碳酸酯基底的涂层溶剂中的足够溶解性和具有高达690nm波长的光的改进的读/写特性的优点。

公开(公告)号：US6153735A

公开(公告)日：2000-11-28

申请号：US61567

申请日：1998-04-16

申请人： Kazuaki Sukata ,  Shuji Sugawara ,  Shun-ichiro Yamanaka ,  Tohru Tsuruhara ,  Masashi Yasumatsu

发明人： Kazuaki Sukata ,  Shuji Sugawara ,  Shun-ichiro Yamanaka ,  Tohru Tsuruhara ,  Masashi Yasumatsu

IPC分类号： C09B45/14 ,  C09D5/03 ,  G03G9/09

CPC分类号： C09D5/034 ,  C09B45/14 ,  G03G9/091

摘要： Monoazo metal compound of formula [I] which is excellent in charge control or charge-enhancing property, and toner for developing electrostatic images and powdery paint for electrostatic painting incorporating thereof:D.sub.3 (Met).sub.2 [I]D is a ligand based on a monoazo compound of formula [II] or [III], Met is a metal atom, and the 3 molecules of D are coordinated to the 2 atoms of Met: ##STR1## R.sup.1 -R.sup.10, and R.sup.21 -R.sup.28 are each H, halogen, nitro, alkyl or haloalkyl, aryl, aralkyl, --SO.sub.2 N(R.sup.11).sub.2 (R.sup.11 is H, alkyl, aryl, aralkyl), --N(R.sup.12).sub.2 (R.sup.12 is H, lower alkyl, aryl, aralkyl, acyl), --CONH(R.sup.13) (R.sup.13 is H, a lower alkyl, aryl, aralkyl); 2 or more of R.sup.1 -R.sup.10 and/or R.sup.21 -R.sup.28 may bind together to form an aromatic or aliphatic ring.

摘要翻译： D3（Met）2 [I] D是一种配体，它是一种具有电荷控制或电荷增强性能的式[I]的单偶氮金属化合物，静电图像显影用调色剂和用于静电喷涂的粉末涂料 式[II]或[III]的单偶氮化合物，Met是金属原子，D的3个分子与Met：R1-R10的2个原子配位，R21-R28各自为H，卤素，硝基，烷基 或R 1为卤素，芳基，芳烷基，-SO 2 N（R 11）2（R 11为H，烷基，芳基，芳烷基），-N（R 12）2（R 12为H，低级烷基，芳基，芳烷基，酰基） ）（R 13为H，低级烷基，芳基，芳烷基）; R2-R10和/或R21-R28中的2个或更多个可以结合在一起以形成芳族或脂族环。

公开(公告)号：US5514783A

公开(公告)日：1996-05-07

申请号：US430794

申请日：1995-04-28

申请人： Jordi B. Barra ,  Jose R. Sorolla

发明人： Jordi B. Barra ,  Jose R. Sorolla

IPC分类号： C09B29/033 ,  C07D239/04 ,  C07D239/50 ,  C07D239/54 ,  C07D239/545 ,  C09B29/52 ,  C09B31/02 ,  C09B31/14 ,  C09B31/28 ,  C09B45/14 ,  C09B45/24 ,  C09B67/22 ,  D06P3/30 ,  D06P3/32

CPC分类号： C07D239/545 ,  C07D239/50 ,  C09B29/3669 ,  C09B31/02 ,  C09B31/28 ,  C09B45/14 ,  C09B45/24 ,  C09B67/0055

摘要： The invention provides a process for the production of azodyes and their derivatives by diazotization and coupling reactions and optionally further modification reactions, wherein a compound of formula ##STR1## in which E signifies an aromatic bivalent radical,X.sub.1 signifies hydroxy or a primary amino group,Y.sub.1 signifies hydroxy or a primary amino groupand in whichthe aminogroup linked to the --SO.sub.2 -bound phenyl radical may optionally be acylated,or a mixture of compounds of formula (I), is employed as a coupling component or/and--in the non-acylated form--as a diazo component,the invention in particular relates also to the novel dyes and their use and to the novel intermediates.

摘要翻译： 本发明提供了通过重氮化和偶联反应和任选的其它改性反应制备偶氮二异氰酸酯及其衍生物的方法，其中E表示芳族二价基团的式（I）化合物，X1表示羟基或伯 氨基，Y1表示羟基或伯氨基，其中与-SO 2键合的苯基连接的氨基可以任选地被酰化，或者使用式（I）的化合物的混合物作为偶联组分或/和 - 非酰化形式 - 作为重氮组分，本发明还特别涉及新型染料及其用途和新型中间体。

公开(公告)号：US5059683A

公开(公告)日：1991-10-22

申请号：US348340

申请日：1989-05-05

申请人： Helmut A. Moser ,  Roland Wald

发明人： Helmut A. Moser ,  Roland Wald

IPC分类号： C09B44/08 ,  C07D401/12 ,  C07D401/14 ,  C09B29/42 ,  C09B35/031 ,  C09B35/039 ,  C09B43/16 ,  C09B45/14

CPC分类号： C07D401/12 ,  C07D401/14 ,  C09B29/3626 ,  C09B35/031 ,  C09B35/039 ,  C09B43/16 ,  C09B45/14

摘要： Compounds of the formula ##STR1## and acid addition salts thereof whereinA.sub.1 is C.sub.1-8 alkylene; C.sub.2-8 alkylene substituted by 1 or 2 substituents selected from hydroxy, halo and cyano; C.sub.2-8 alkenylene; cyclohexylene; cyclohexylene substituted by 1 to 3 C.sub.1-4 alkyl groups; phenylene or phenylene substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy,B.sub.1 is ##STR2## wherein the quaternized nitrogen atom is bound to a carbon atom of A.sub.1,R is hydrogen, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl or phenylethyl,T is hydrogen, cyano, --COOR.sub.1, --CON(R.sub.2).sub.2, --SO.sub.2 N(R.sub.2).sub.2, ##STR3## wherein R.sub.1 is C.sub.1-6 alkyl or phenyl(C.sub.1-3 alkyl),each R.sub.3 is independently hydrogen, C.sub.1-4 alkyl, --CON(R.sub.2).sub.2 or --N(R.sub.5).sub.2, andX.sub.1 is --S--, --O-- or --N(R.sub.5)--,Y is hydrogen or a chromophoric group, andZ is ##STR4## wherein R.sub.11 is ##STR5## wherein W is --NR.sub.6 R.sub.7 or --.sup..sym. NR.sub.8 R.sub.9 R.sub.10 A.sup..crclbar.,R.sub.12 is ##STR6## --O--R.sub.14, --O--A.sub.2 --O--R.sub.14 or --NR.sub.6 R.sub.7, whereinW is as defined above,R.sub.13 is hydrogen, halo, C.sub.1-4 alkyl, --O--R.sub.14, --O--A.sub.2 --O--R.sub.14 or --NR.sub.6 R.sub.7, andR.sub.15 is hydrogen or halo,with the proviso that the compounds are free of sulfo groups. The compounds wherein Y is other than hydrogen are useful for dyeing and printing substrates such as natural and regenerated cellulose, acid-modified polyamide, leather and paper.

公开(公告)号：US4962191A

公开(公告)日：1990-10-09

申请号：US399202

申请日：1989-08-28

申请人： Alois Puntener ,  Kurt Burdeska

发明人： Alois Puntener ,  Kurt Burdeska

IPC分类号： C07D239/47 ,  C07D239/48 ,  C07D405/04 ,  C09B45/14 ,  D06P1/10 ,  D06P3/24 ,  D06P3/32 ,  D06P3/60 ,  D06P3/79

CPC分类号： D06P1/10 ,  C09B45/14

摘要： Dyes suitable for dyeing a wide range of textile and non-textile materials, in particular for dyeing leather and pelts, having, in the form of the free acid, the formula ##STR1## wherein D.sub.1 and D.sub.2 are each independently of the other the radical of a diazo component of the benzene or naphthalene series which carries a hydroxy or carboxy in ortho-position to the azo group and which may or may not be further substituted,K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series which carries the group X in ortho-position to the azo group and which may or may not be further substituted,Me is chromium or cobalt,Q is an unsubstituted or substituted phenyl or naphthyl radical or an unsubstituted or substituted aromatic-heterocyclic radical,R.sub.1 is unsubstituted or substituted C.sub.1 -C.sub.6 alkyl or unsubstituted or substituted phenyl,R.sub.2 is hydrogen or independently has the meaning of R.sub.1, X is --O-- or --NR.sub.3,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, andp and q are each independently of the other 0 or 1.

摘要翻译： 适用于染色各种纺织和非纺织材料的染料，特别是染色皮革和毛皮，具有游离酸形式的式（1），其中D1和D2各自独立地为 另一个苯或萘系列的重氮组分的基团，其在偶氮基的邻位带有羟基或羧基，并且可以被进一步取代，K是苯或萘的偶联组分的基团 系列或杂环系列，其携带基团X在偶氮基上邻位并且可以被进一步取代，Me是铬或钴，Q是未取代或取代的苯基或萘基或未取代或取代的 芳基 - 杂环基，R 1是未取代的或取代的C 1 -C 6烷基或未取代或取代的苯基，R 2是氢或独立地具有R 1，X是-O-或-NR 3，R 3是氢或C 1 -C 4烷基，p和 q 各自独立于0或1。