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1.发明授权Arylidene compound, azomethine compound and silver halide photographic material 失效亚芳基化合物，偶氮甲碱化合物和卤化银照相材料公开(公告)号：US06235457B1
公开(公告)日：2001-05-22
申请号：US09499371
申请日：2000-02-07
申请人： Keizo Kimura , Masashi Ogiyama , Yoshiharu Yabuki , Toshio Kawagishi , Takeshi Nakamine , Yuki Mizukawa
发明人： Keizo Kimura , Masashi Ogiyama , Yoshiharu Yabuki , Toshio Kawagishi , Takeshi Nakamine , Yuki Mizukawa
IPC分类号： G03C183
CPC分类号： G03C1/832 , C07D471/04 , C09B23/0091 , C09B23/02 , C09B23/06 , C09B23/08 , C09B55/009 , Y10S430/145
摘要： An arylidene compound is represented by the formula (I). Each of L1 and L2 independently is a divalent aliphatic group, a divalent aromatic group or a divalent heterocyclic group. L3 is trimethine, pentamethine or heptamethine. Y is ═O, ═S or ═N—R10. R1 is hydrogen, a halogen atom, cyano, nitro, an aliphatic group, an aromatic group, a heterocyclic group, —O—R11, —S—R12, —CO—O—R13, —O—CO—R14, —NR15R16, —CO—NR17R18, —SO2—R19 or —SO2—NR20R21. Each of R2, R3, R6 and R7 independently is hydrogen, a halogen atom, cyano, an aliphatic group, an aromatic group, —O—R22, —CO—R23, —CO—O—R24, —NR25R26, —NHCO—R27, —NH—CO—O—R28, —SO2—R29 or —NH—SO2—R30. Each of R4 and R5 independently is hydrogen, an aliphatic group, an aromatic group, —CO—R31 or —SO2—R32. An azomethine compound and silver halide photographic materials are also disclosed.
摘要翻译： 亚芳基化合物由式（I）表示.L1和L2各自独立地为二价脂族基团，二价芳族基团或二价杂环基团。 L3是三甲基，五甲胺或七甲嘧啶。 Y是= O，= S或= N-R10。 R 1是氢，卤原子，氰基，硝基，脂族基，芳基，杂环基，-O-R 11，-S-R 12，-CO-O-R 13，-O-CO-R 14，-NR 15 R 16 ，-CO-NR 17 R 18，-SO 2 -R 19或-SO 2 -NR 20 R 21。 R2，R3，R6和R7各自独立地是氢，卤素原子，氰基，脂族基团，芳族基团，-O-R22，-CO-R23，-CO-O-R24，-NR25R26，-NHCO- R27，-NH-CO-O-R28，-SO2-R29或-NH-SO2-R30。 R 4和R 5各自独立地为氢，脂族基，芳基，-CO-R 31或-SO 2 -R 32。 还公开了偶氮甲碱化合物和卤化银照相材料。
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2.发明授权Silver halide color photographic light-sensitive material containing a development inhibitor releasing compound 失效含有显影抑制剂释放化合物的卤化银彩色照相感光材料
公开(公告)号：US5985531A
公开(公告)日：1999-11-16
申请号：US887931
申请日：1997-07-03
CPC分类号： G03C7/30576 , G03C7/30552 , Y10S430/158
摘要： A silver halide color photographic light-sensitive material containing a compound represented by formula (I) belowformula (I)A--O--C(.dbd.O)--N(X.sub.1)--C(X.sub.2)(X.sub.3)--DIwherein A represents a coupler residue, X.sub.1 represents a heterocyclic group or a --C(X.sub.4)(X.sub.5)--Y group, Y represents an --SO.sub.2 R.sup.1, --SO.sub.2 NR.sup.1 R.sup.2, --CONR.sup.1 R.sup.2, --CO.sub.2 Z, --CN, --CF.sub.3, --CCl.sub.3, or --NO.sub.2 group, each of R.sup.1 and R.sup.2 independently represents a hydrogen atom or a substituted or nonsubstituted alkyl, cycloalkyl, alkenyl, aryl, or heterocyclic group, Z represents a hydrogen atom or a substituted or nonsubstituted cycloalkyl, alkenyl, aryl, or heterocyclic group, each of X.sub.2, X.sub.3, X.sub.4, and X.sub.5 represents a hydrogen atom or a substituent group, and DI represents a development inhibitor residue which is bonded by a hetero atom and released to form mercaptoazole.
摘要翻译： 含有由式（I）表示的化合物（I）表示的化合物的卤化银彩色照相感光材料AOC（= O）-N（X1）-C（X2）（X3）-DI其中A表示成色剂残基X1 表示杂环基或-C（X 4）（X 5）-Y基，Y表示-SO 2 R 1，-SO 2 NR 1 R 2，-CONR 1 R 2，-CO 2 Z，-CN，-CF 3，-CCl 3或-NO 2基， R 2独立地表示氢原子或取代或未取代的烷基，环烷基，烯基，芳基或杂环基，Z表示氢原子或取代或未取代的环烷基，烯基，芳基或杂环基，X， X4和X5表示氢原子或取代基，DI表示通过杂原子键合并释放形成巯基唑的显影抑制剂残基。
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公开(公告)号：US5605788A
公开(公告)日：1997-02-25
申请号：US556141
申请日：1995-11-09
IPC分类号： G03C7/00 , C07D487/04 , G03C7/38
CPC分类号： C07D487/04 , G03C7/3835
摘要： A silver halide color photographic material containing a pyrazolotriazole coupler represented by the following formula (I) or (II): ##STR1## wherein R.sub.1 represents a hydrogen atom, a halogen atom, or a substituent; X represents a hydrogen atom, a halogen atom, or a group capable of being splitted off by the reaction with an oxidation product of a developing agent; L.sub.1 represents an (n+1)-valent linking group; L.sub.2 represents a group represented by the following formula (III); and n represents 1 or 2, and when n is 2, two L.sub.2 's may be the same or different;--[(A.sub.1).sub.a (B.sub.1).sub.b (A.sub.2).sub.c (B.sub.2).sub.d (A.sub.3).sub.e (B.sub.3).sub.f (A.sub.4).sub.g (B.sub.4).sub.h ](III)wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represents --O--, --S--, --NR.sub.2 --, --N(R.sub.2)CO--, --CON(R.sub.2)--, --N(R.sub.2)SO.sub.2 --, --SO.sub.2 N(R.sub.2)--, --CO.sub.2 --, --OCO--, --N(R.sub.2)CON(R.sub.3)--, --OCON(R.sub.2)-- or --N(R.sub.2)CO.sub.2 --; R.sub.2 and R.sub.3 each represents a hydrogen atom, an alkyl group, an aryl group, an acyl group, an alkanesulfonyl group or an arenesulfonyl group; B.sub.1, B.sub.2 and B.sub.3 each represents an alkylene group or an arylene group; B.sub.4 represents an alkyl group or an aryl group; a, b, c, d, e, f and g each represents 0 or 1, and h represents 1, provided that a-b=0, c-d=0 and e-f=0; and at least one group represented by R.sub.2, R.sub.3, B.sub.1, B.sub.2, B.sub.3 and B.sub.4 in the substituents represented by L.sub.2 has a group represented by the following formula (IV):--A--NH--R.sub.4 (IV)wherein A represents --CO-- or --SO.sub.2 --; and R.sub.4 represents a hydrogen atom or an alkyl group.
摘要翻译： 含有由下式（I）或（II）表示的吡唑并三唑成色剂的卤化银彩色照相材料：其中R 1表示氢原子，卤素原子或取代基; X表示氢原子，卤素原子或能够通过与显影剂的氧化产物反应而分裂的基团; L1表示（n + 1）价连接基团; L2表示由下式（III）表示的基团。 - （A1）a（B1）b（A2）c（B2）d（A3）e（B3）f（A4）其中n为1或2，当n为2时，两个L2可以相同或不同; ）g（B4）h]（III）其中A1，A2，A3和A4各自表示-O - ， - S - ， - NR2-，-N（R2）CO-，-CON（R2） - ， - N（ R2）SO2-，-SO2N（R2） - ，-COO2-，-OCO-，-N（R2）CON（R3） - ， - OCON（R2） - 或-N（R2）CO2-; R2和R3各自表示氢原子，烷基，芳基，酰基，链烷磺酰基或芳烃磺酰基; B1，B2和B3各自表示亚烷基或亚芳基; B4表示烷基或芳基; a，b，c，d，e，f和g各自表示0或1，h表示1，条件是a-b = 0，c-d = 0，e-f = 0; 在由L2表示的取代基中的R2，R3，B1，B2，B3和B4表示的至少一个基团具有下式（IV）表示的基团：-A-NH-R4（IV）其中A表示-CO - 或-SO 2 - ; R4表示氢原子或烷基。
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公开(公告)号：US06423484B1
公开(公告)日：2002-07-23
申请号：US09736391
申请日：2000-12-15
申请人： Yasuhiro Yoshioka , Takehiko Sato , Osamu Takahashi , Toshio Kawagishi , Kozo Sato , Yuki Mizukawa
发明人： Yasuhiro Yoshioka , Takehiko Sato , Osamu Takahashi , Toshio Kawagishi , Kozo Sato , Yuki Mizukawa
IPC分类号： G03C7305
摘要： There is disclosed a silver halide color photographic light-sensitive material which excels in a color reproduction and an image fastness and which has an excellent color developability. The above silver halide color photographic light-sensitive material comprises a support and provided thereon a yellow color-developing light-sensitive silver halide emulsion layer, a magenta color-developing light-sensitive silver halide emulsion layer and a cyan color-developing light-sensitive silver halide emulsion layer each having a different color-sensitivity, wherein the above magenta color-developing light-sensitive silver halide emulsion layer contains at least one of the non-diffusible dye-forming couplers represented by the following Formula (M), a high boiling organic solvent having a dielectric constant of 6.0 or less and a refraction index of 1.50 or less, and at least one of the water insoluble polymers which are obtained by polymerizing at least one of the monomers having an aromatic group: wherein R1 represents a hydrogen atom or a substituent; Z represents a non-metal atomic group which is necessary to form a 5-membered azole ring containing 2 to 4 nitrogen atoms and the above azole ring may contain a substituent (including a condensed ring); and X represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with an oxidation product of a developing agent.
摘要翻译： 公开了一种在色彩再现和图像牢度方面优异并且具有优异的显色性的卤化银彩色照相感光材料。 上述卤化银彩色照相感光材料包括支持体，并在其上提供黄色显色感光卤化银乳剂层，品红色显色感光卤化银乳剂层和青色显色光敏感材料 卤化银乳剂层各自具有不同的颜色敏感性，其中上述品红显色感光卤化银乳剂层含有由下式（M）表示的至少一种不扩散染料形成成色剂，高 介电常数为6.0以下，折射率为1.50以下的沸点有机溶剂，以及至少一种通过聚合至少一种具有芳基的单体得到的水不溶性聚合物：其中R1表示氢 原子或取代基; Z表示形成含有2〜4个氮原子的5元唑环所必需的非金属原子团，上述唑环可以含有取代基（包括稠环）。 X表示氢原子或与显影剂的氧化物进行偶联反应时能够分解的基团。
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公开(公告)号：US06770431B2
公开(公告)日：2004-08-03
申请号：US10329466
申请日：2002-12-27
IPC分类号： G03C108
CPC分类号： G03C7/3835 , G03C7/301 , G03C7/39268
摘要： A silver halide color photosensitive material comprising a 1H-pyrazolo[3,2-c]-1,2,4-triazole type coupler having, in its molecule, at least one substituent represented by the following general formula (I): wherein R1 represents a substituent; m represents an integer of 0 to 4; and R2 represents an alkyl group, alkenyl group or aryl group.
摘要翻译： 一种卤化银色感光材料，其包含1H-吡唑并[3,2-c] -1,2,4-三唑型成色剂，其分子中具有至少一个由以下通式（I）表示的取代基：其中R 1 表示取代基; m表示0〜4的整数， 并且R 2表示烷基，烯基或芳基。
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公开(公告)号：US5858635A
公开(公告)日：1999-01-12
申请号：US803373
申请日：1997-02-20
CPC分类号： G03C7/3835
摘要： A silver halide color photographic material is described, containing a 1H-pyrazolo�5,1-c!-1,2,4-triazole magenta coupler represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.4 each represent a substituent; R.sub.2 and R.sub.3 each represent a hydrogen atom, an alkyl group, an aryl group, a hydroxyl group or an alkyl group substituted with at least one hydroxyl group; R.sub.9 represents a hydrogen atom, an alkyl group, an aryl group, an acyl group or a sulfonyl group; L represents --SO.sub.2 --, --CO--, --SO.sub.2 NR.sub.10 --, --CONR.sub.10 -- or --COO--; R.sub.10 represents a hydrogen atom, an alkyl group or an aryl group; A.sub.1, A.sub.2, and A.sub.3 each represent --O--, --NR.sub.5 --, --NR.sub.5 CO--, --CONR.sub.5 --, --NR.sub.5 SO.sub.2 --, --SO.sub.2 NR.sub.5 --, --COO--, --OCO--, --NR.sub.5 CONR.sub.5 --, --OCONR.sub.5 -- or --NHCOO--; R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group or an alkyl group substituted with at least one hydroxyl group; B.sub.1, B.sub.2, and B.sub.3 each represent an alkyl group, an alkylene group, an aryl group, an arylene group, an alkyl group substituted with at least one hydroxyl group or an alkylene group substituted with at least one hydroxyl group; s represents 0 or an integer of 1 to 3; X represents a hydrogen atom or a group releasable on coupling with an oxidized aromatic primary amine developing agent; k represents 0 or an integer of 1 to 3; u, m, n, t, and p each represent 0 or 1, provided that m-n+t-p=0; q represents 1; r represents 1 or 2; and at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, B.sub.1, B.sub.2, and B.sub.3 has a hydroxyl group, provided that the hydroxyl group is not the one directly bonded to an aryl group.
摘要翻译： 描述了含有由式（I）代表的1H-吡唑并[5,1-c] -1,2,4-三唑品红成色剂取代基的卤化银彩色照相材料; R2和R3各自表示氢原子，烷基，芳基，羟基或被至少一个羟基取代的烷基; R9表示氢原子，烷基，芳基，酰基或磺酰基; L表示-SO 2 - ， - CO - ， - SO 2 NR 10 - ， - CONR 10 - 或-COO-; R 10表示氢原子，烷基或芳基; A1，A2和A3各自表示-O-，-NR5-，-NR5CO-，-CONR5-，-NR5SO2-，-SO2NR5-，-COO-，-OCO-，-NR5CONR5-，-OCONR5-或-NHCOO - ; R5表示氢原子，烷基，芳基或被至少一个羟基取代的烷基; B1，B2和B3各自表示烷基，亚烷基，芳基，亚芳基，被至少一个羟基取代的烷基或被至少一个羟基取代的亚烷基; s表示0或1〜3的整数， X表示氢原子或与氧化芳族伯胺显影剂偶联可释放的基团; k表示0或1〜3的整数， u，m，n，t和p各自表示0或1，条件是m-n + t-p = 0; q表示1; r表示1或2; R 1，R 2，R 3，R 4，R 5，B 1，B 2和B 3中的至少一个具有羟基，条件是羟基不是直接与芳基键合的羟基。
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公开(公告)号：US5656418A
公开(公告)日：1997-08-12
申请号：US524846
申请日：1995-09-07
IPC分类号： G03C7/38
CPC分类号： G03C7/3835
摘要： A silver halide color photographic material is described, containing a 1H-pyrazolo[5,1-c]-1,2,4-triazole magenta coupler represented by formula (I) or (II): ##STR1## wherein all variables are defined in the specification, which photographic material exhibits satisfactory magenta color developability to form a dye image having a high density and excellent storage stability.
摘要翻译： 描述了含有由式（I）或（II）表示的1H-吡唑并[5,1-c] -1,2,4-三唑品红成色剂的卤化银彩色照相材料：图像 >（II）其中所有变量在本说明书中定义，该照相材料表现出令人满意的品红色显影性以形成具有高密度和优异储存稳定性的染料图像。
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公开(公告)号：US4774172A
公开(公告)日：1988-09-27
申请号：US935987
申请日：1986-11-28
IPC分类号： C07D487/04 , G03C7/38
CPC分类号： C07D487/04 , G03C7/3825
摘要： Silver halide color photographic materials are described, which comprise at least one silver halide emulsion layer coated on a support and which are characterized by the incorporation of a pyrazoloazole type coupler of the following general formula (I) into the silver halide emulsion layer(s) or the adjacent layer(s) thereto: ##STR1## wherein Za and Zb each may represent ##STR2## R.sup.1 and R.sup.2 each may represent a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being removed upon a coupling reaction with an oxidized form of an aromatic primary amine type developing agent; when Za.dbd.Zb is a carbon-carbon double bond, this may be a part of the aromatic ring in the formula: with the proviso that at least one of R.sup.1 and R.sup.2 is a group represented by general formulae (II) or (III): ##STR3## wherein R.sup.3 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sup.4 represents a hydrogen atom or a substituent; R.sup.5 represents a halogen atom, a substituted or unsubstituted alkoxy, aryloxy, amino, alkylthio or arylthio group; Ar represents an aryl group; Y represents an alkylene group or an arylene group; l' is an integer of 0 or 1; n is an integer of 0 or 1; and m is an integer of 1 to 3; and that when R.sup.1 represents an alkyl group or Y represents an alkylene group, the alkyl or alkylene group is a group of which the carbon atom directly bonded to the pyrazoloazole nucleus is a primary carbon.The pyrazoloazole type magenta couplers of general formula (I) may form azomethine dyes with improved color reproducibility and high light fastness. The present silver halide color photographic materials containing the coupler of general formula (I) have excellent colorability and excellent light fastness.
摘要翻译： 描述了卤化银彩色照相材料，其包含涂覆在载体上的至少一种卤化银乳剂层，其特征在于将以下通式（I）的吡唑并唑型成色剂加入到卤化银乳剂层中， 或其相邻的层：其中Za和Zb各自可以表示R 1和R 2各自可以表示氢原子或取代基; X表示氢原子或能够与氧化形式的芳族伯胺型显影剂偶联反应时除去的基团; 当Za = Zb是碳 - 碳双键时，其可以是下式中的芳环的一部分：条件是R 1和R 2中的至少一个是由通式（II）或（III）表示的基团， （III）其中R3表示氢原子或取代或未取代的烷基; R4代表氢原子或取代基; R5表示卤素原子，取代或未取代的烷氧基，芳氧基，氨基，烷硫基或芳硫基; Ar表示芳基; Y表示亚烷基或亚芳基; l'是0或1的整数; n为0或1的整数; m为1〜3的整数。 当R 1表示烷基或Y表示亚烷基时，烷基或亚烷基是与吡唑并唑核直接键合的碳原子为伯碳的基团。 通式（I）的吡唑并噻唑型品红色成色剂可以形成具有改善的颜色再现性和高耐光性的偶氮甲碱染料。 含有通式（I）的成色剂的本发明的卤化银彩色照相材料具有优异的着色性和优异的耐光性。
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公开(公告)号：US20050210605A1
公开(公告)日：2005-09-29
申请号：US10996376
申请日：2004-11-26
IPC分类号： A61K8/00 , A61K8/362 , A61K8/365 , A61K8/40 , A61K8/49 , A61Q5/10 , D06P1/04 , D06P1/653 , D06P1/673 , D06P3/30 , D06P5/04 , A61K7/13
CPC分类号： A61K8/4946 , A61K8/362 , A61K8/365 , A61K8/40 , A61K8/49 , A61K8/4926 , A61Q5/10
摘要： The present invention relates to a method to achieve a reversible change of the colour of hair dyed with an azo dye wherein the change of the colour can be effected by, for example, the salonist or the consumer in a simple manner. The colour of the hair thus dyed may be changed simply by treating the dyed hair with an acid treatment composition at any time after the first dyeing treatment. If desired by the consumer, the colour may be returned to substantially the original post dye colour by treating the hair further with an alkaline treatment composition.
摘要翻译： 本发明涉及一种通过偶氮染料染色的毛发的颜色的可逆变化的方法，其中颜色的变化可以由例如沙龙或消费者以简单的方式进行。 这样染色的毛发的颜色可以简单地通过在第一次染色处理之后的任何时间用酸处理组合物处理染色的毛发来改变。 如果消费者需要，通过用碱处理组合物进一步处理毛发，可以将颜色返回到基本上原始的后染料颜色。
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公开(公告)号：US6074810A
公开(公告)日：2000-06-13
申请号：US168171
申请日：1998-10-08
申请人： Toshio Kawagishi , Hideaki Naruse
发明人： Toshio Kawagishi , Hideaki Naruse
CPC分类号： G03C7/3825 , G03C8/408 , G03C7/383 , G03C7/3835
摘要： There is disclosed a silver halide color light-sensitive material, which comprises a coupler of the formula (1), (2), or (3) in at least one layer on a base: ##STR1## wherein R.sub.1 is a hydrogen atom, a halogen atom, or a substituent, R.sub.2 is a group of formula (4), R.sub.3 and R.sub.4 each are a hydrogen atom, a halogen atom, or a substituent, with the proviso that at least one of R.sub.3 and R.sub.4 is a group of the formula (4), R.sub.5 and R.sub.6 each are an alkyl group, an amino group, a carbonamido group, an alkoxycarbonylamino group, a sulfonamido group, and the like, R.sub.7 represents a group capable of substitution on a benzene ring; n is an integer of 0 to 3. This light-sensitive material can give a magenta image excellent in discrimination, and it is excellent in preservability before and after processing.
摘要翻译： 公开了一种卤化银色感光材料，其在碱的至少一层中包含式（1），（2）或（3）的成色剂：其中R1是氢原子，卤素原子 或取代基，R 2为式（4）的基团，R 3和R 4各自为氢原子，卤素原子或取代基，条件是R 3和R 4中的至少一个为式 4）中，R 5和R 6各自为烷基，氨基，碳酰氨基，烷氧基羰基氨基，亚磺酰氨基等，R 7表示可在苯环上取代的基团。 n为0〜3的整数。这种感光材料可以赋予鉴定性优异的品红色图像，加工前后的保存性优异。
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