Process for production of highly polymerized aromatic polycarbonate resin
    3.
    发明授权
    Process for production of highly polymerized aromatic polycarbonate resin 有权
    生产高聚合芳族聚碳酸酯树脂的方法

    公开(公告)号:US08674053B2

    公开(公告)日:2014-03-18

    申请号:US13510780

    申请日:2010-11-18

    IPC分类号: C08G64/00 C08G63/02

    CPC分类号: C08G64/42 C08G64/305

    摘要: A method for highly polymerizing an aromatic polycarbonate resin, which enables the increase in molecular weight of the aromatic polycarbonate resin satisfactorily while keeping good quality of the resin. An aromatic polycarbonate is linked to an aliphatic diol compound having a boiling point of 240° C. or higher (preferably in an amount of 0.01 to 1.0 mole per mole of the total amount of the terminal of the aromatic polycarbonate) through a transesterification reaction in the presence of a transesterification catalyst under reduced pressure conditions (preferably at a reduced pressure ranging from 13 kPaA (100 torr) to 0.01 kPaA (0.01 torr)), thereby increasing the molecular weight of the resulting molecule. The weight average molecular weight (Mw) of the aromatic polycarbonate after the transesterification reaction can be increased preferably by 5,000 or more compared to that of the aromatic polycarbonate before the transesterification reaction.

    摘要翻译: 芳香族聚碳酸酯树脂的高度聚合的方法,能够令树脂的良好品质保持良好,能够令芳香族聚碳酸酯树脂的分子量提高。 通过酯交换反应将芳族聚碳酸酯与沸点为240℃以上的脂肪族二醇化合物(优选为每摩尔芳族聚碳酸酯的末端的总量为0.01〜1.0摩尔)连接, 在减压条件下(优选在13kPaA(100乇)至0.01kPa(0.01乇))的减压条件下存在酯交换催化剂,从而提高所得分子的分子量。 与酯交换反应前的芳香族聚碳酸酯相比,酯交换反应后的芳香族聚碳酸酯的重均分子量(Mw)优选提高5000以上。

    PROCESS FOR PRODUCTION OF HIGHLY POLYMERIZED AROMATIC POLYCARBONATE RESIN
    4.
    发明申请
    PROCESS FOR PRODUCTION OF HIGHLY POLYMERIZED AROMATIC POLYCARBONATE RESIN 有权
    生产高分子量芳族聚碳酸酯树脂的方法

    公开(公告)号:US20130197166A1

    公开(公告)日:2013-08-01

    申请号:US13510780

    申请日:2010-11-18

    IPC分类号: C08G64/42

    CPC分类号: C08G64/42 C08G64/305

    摘要: A method for highly polymerizing an aromatic polycarbonate resin, which enables the increase in molecular weight of the aromatic polycarbonate resin satisfactorily while keeping good quality of the resin. An aromatic polycarbonate is linked to an aliphatic diol compound having a boiling point of 240° C. or higher (preferably in an amount of 0.01 to 1.0 mole per mole of the total amount of the terminal of the aromatic polycarbonate) through a transesterification reaction in the presence of a transesterification catalyst under reduced pressure conditions (preferably at a reduced pressure ranging from 13 kPaA (100 torr) to 0.01 kPaA (0.01 torr)), thereby increasing the molecular weight of the resulting molecule. The weight average molecular weight (Mw) of the aromatic polycarbonate after the transesterification reaction can be increased preferably by 5,000 or more compared to that of the aromatic polycarbonate before the transesterification reaction.

    摘要翻译: 芳香族聚碳酸酯树脂的高度聚合的方法,能够令树脂的良好品质保持良好,能够令芳香族聚碳酸酯树脂的分子量提高。 通过酯交换反应将芳族聚碳酸酯与沸点为240℃以上的脂肪族二醇化合物(优选为每摩尔芳族聚碳酸酯的末端的总量为0.01〜1.0摩尔)连接, 在减压条件下(优选在13kPaA(100乇)至0.01kPa(0.01乇))的减压条件下存在酯交换催化剂,从而提高所得分子的分子量。 与酯交换反应前的芳香族聚碳酸酯相比,酯交换反应后的芳香族聚碳酸酯的重均分子量(Mw)优选提高5000以上。

    POLYCARBONATE RESIN COMPOSITION
    5.
    发明申请
    POLYCARBONATE RESIN COMPOSITION 有权
    聚碳酸酯树脂组合物

    公开(公告)号:US20120220737A1

    公开(公告)日:2012-08-30

    申请号:US13390190

    申请日:2010-08-11

    IPC分类号: C08L69/00

    摘要: To provide a polycarbonate resin composition having a high Abbe's number, high strength and excellent stainability.Disclosed is a polycarbonate resin composition prepared by blending a polycarbonate resin (A) prepared by forming carbonate bonds in tricyclo[5.2.1.02,6]decanedimethanol with a diester or phosgene, and a weight-averaged molecular weight (Mw) of the polycarbonate resin (A) being equal to or more than 25,000, and a polycarbonate resin (B) prepared by reacting 2,2-bis(4-hydroxyphenyl)propane and phosgene, and weight-averaged molecular weight (Mw) of the polycarbonate resin (B) being equal to or more than 30,000, wherein a ratio thereof, 100×(A)/((A)+(B)), is from 1 to 99% by weight.

    摘要翻译: 提供具有高阿贝数,高强度和优异染色性的聚碳酸酯树脂组合物。 公开了通过将通过在三环[5.2.1.0 2,6]癸二甲醇中形成碳酸酯键制备的聚碳酸酯树脂(A)与二酯或光气共混制备的聚碳酸酯树脂组合物和聚碳酸酯树脂的重均分子量(Mw) (A)等于或大于25,000,和通过2,2-双(4-羟基苯基)丙烷和光气反应制备的聚碳酸酯树脂(B)和聚碳酸酯树脂(B)的重均分子量(Mw) )等于或大于30,000,其中100×(A)/((A)+(B))的比例为1至99重量%。

    POLYCARBONATE RESIN COMPOSITION, PROCESS FOR PRODUCING MOLDED PRODUCTS USING THE SAME, AND OPTICAL LENS
    6.
    发明申请
    POLYCARBONATE RESIN COMPOSITION, PROCESS FOR PRODUCING MOLDED PRODUCTS USING THE SAME, AND OPTICAL LENS 审中-公开
    聚碳酸酯树脂组合物,使用其制造成型产品的方法和光学镜片

    公开(公告)号:US20120095139A1

    公开(公告)日:2012-04-19

    申请号:US13265232

    申请日:2010-04-19

    摘要: To provide a polycarbonate resin which is excellent in transparency, hue and ultraviolet-resistance of the molded product, is excellent in retention-stability at a high temperature, and causes sufficiently-reduced amount of the dirt on the metal mold during molding.A polycarbonate resin composition comprising A) a polycarbonate resin which is produced according to a melt method without adding any quencher, which comprises a constitution unit derived from 9,9-bis (4-(2-hydroxy ethoxy)phenyl)fluorene and a constitution unit derived from bisphenol A, B) a benzotriazole ultraviolet absorber, C) a mold release which is a partial ester formed of a C10-20 monovalent fatty acid and glycerol, and D) a hindered phenol antioxidant.

    摘要翻译: 为了提供模塑制品的透明性,色相和耐紫外线性优异的聚碳酸酯树脂,在高温下的保持稳定性优异,并且在模制期间使金属模具上的污垢量足够减少。 一种聚碳酸酯树脂组合物,其包含A)聚碳酸酯树脂,该聚碳酸酯树脂根据熔融法制备而不添加任何猝灭剂,其包含衍生自9,9-双(4-(2-羟基乙氧基)苯基)芴的构成单元和构成 衍生自双酚A的单元,B)苯并三唑紫外线吸收剂,C)作为由C10-20单价脂肪酸和甘油形成的偏酯的脱模剂,和D)受阻酚抗氧化剂。

    POLYCARBONATE RESIN AND PROCESS FOR PRODUCTION THEREOF
    9.
    发明申请
    POLYCARBONATE RESIN AND PROCESS FOR PRODUCTION THEREOF 审中-公开
    聚碳酸酯树脂及其生产方法

    公开(公告)号:US20130310535A1

    公开(公告)日:2013-11-21

    申请号:US13981702

    申请日:2012-01-23

    IPC分类号: C08G64/06

    摘要: The present invention provides a polycarbonate resin containing a structural unit represented by general formula (I). In formula (I), R's independently represent a halogen atom, an alkyl group having 1-9 carbon atoms, an aryl group having 6-12 carbon atoms, an alkenyl group having 2-5 carbon atoms, an alkoxy group having 1-5 carbon atoms, or an aralkyl group having 7-17 carbon atoms; n's independently mean the number of R's which substitute on the benzene ring and independently represent an integer of 0-4; Y represents an alkylene group having 1-4 carbon atoms; and p represents an integer of 0-4.

    摘要翻译: 本发明提供含有由通式(I)表示的结构单元的聚碳酸酯树脂。 式(I)中,R独立地表示卤素原子,具有1-9个碳原子的烷基,具有6-12个碳原子的芳基,具有2-5个碳原子的链烯基,具有1-5个 碳原子或具有7-17个碳原子的芳烷基; n独立地表示在苯环上取代的R的数目,独立地表示0-4的整数; Y表示具有1-4个碳原子的亚烷基; p表示0〜4的整数。

    Examination method, examination apparatus and examination program
    10.
    发明授权
    Examination method, examination apparatus and examination program 有权
    考试方法,考试机构和考试方案

    公开(公告)号:US08509512B2

    公开(公告)日:2013-08-13

    申请号:US12649997

    申请日:2009-12-30

    IPC分类号: G06K9/00

    摘要: This invention provides an examination method, an examination apparatus, and an examination program capable of performing the examination corresponding to the type or the like of the site to be examined and capable of reducing the examination time when examining the substrate. The X-ray is output from an X-ray source, and the X-ray that transmitted the substrate to be examined is photographed as an X-ray perspective image in an FPD (Flat Panel Detector). The photographing for generating the reconstruction data by X-ray CT is performed at the positions on the virtual circle having the optical axis of the X-ray source as an axis, similar to the photographing for generating the reconstruction data by tomosynthesis. Thus, in generating the reconstruction data by X-ray CT, the data is converted so that each image rotates using affine conversion with the center of each X-ray perspective image as an axis according to the rotation position on the virtual circle as if the X-ray perspective images obtained at the respective positions are photographed at the positions, and then the filtering process is performed.

    摘要翻译: 本发明提供一种检查方法,检查装置和检查程序,其能够进行与被检查部位的类型等相应的检查,并且能够减少检查基板时的检查时间。 从X射线源输出X射线,将被检查的基板的X射线作为FPD(平板检测器)中的X射线透视图像拍摄。 类似于通过层析合成生成重建数据的拍摄,通过X射线CT生成重建数据的拍摄在具有X射线源的光轴的虚拟圆上的位置处进行。 因此,在通过X射线CT生成重建数据时,转换数据,使得每个图像根据虚拟圆上的旋转位置以每个X射线透视图像的中心为基准,使用仿射变换旋转,就好像 在各位置拍摄在各位置获得的X射线透视图像,然后进行滤波处理。