Cationic triphendioxazine dyes, methods for their manufacture and their
use for dyeing cellulosic substrates
    1.
    发明授权
    Cationic triphendioxazine dyes, methods for their manufacture and their use for dyeing cellulosic substrates 失效
    阳离子三苯并二恶嗪染料,其制造方法及其用于染色纤维素基质的用途

    公开(公告)号:US4512773A

    公开(公告)日:1985-04-23

    申请号:US493262

    申请日:1983-05-10

    IPC分类号: C09B19/02 D06P3/58

    CPC分类号: C09B19/02 Y10S8/918 Y10S8/919

    摘要: A dyestuff of formula: ##STR1## wherein: the groups X.sub.1 and X.sub.2 are independently hydrogen, halogen, alkyl, aryl, alkoxy, cyano, optionally substituted amino or carboxylic acid ester groups; (R).sub.n represents n substituents R each of which is independently halogen, lower alkyl, lower alkoxy or --COOH and n is 0 or 1; R.sub.1 is hydrogen, or optionally substituted lower alkyl; Y is an optionally substituted aliphatic or optionally substituted araliphatic group; R.sub.2 is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl; R.sub.3 is hydrogen or an optionally substituted alkyl or aralkyl group; A.sup.- is an anion; a is 0 or 1; and Z is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl.The dyes are useful for the coloration of materials such as textiles, leather, inks and lacquers.

    摘要翻译: 一种下式的染料:其中:基团X 1和X 2独立地是氢,卤素,烷基,芳基,烷氧基,氰基,任选取代的氨基或羧酸酯基团; (R)n表示n个取代基R,其各自独立地为卤素,低级烷基,低级烷氧基或-COOH,n为0或1; R1是氢或任选取代的低级烷基; Y是任选取代的脂族或任选取代的芳脂族基; R 2是氢,任选取代的低级烷基,任选取代的芳基或任选取代的芳烷基; R3是氢或任选取代的烷基或芳烷基; A-是阴离子; a是0或1; 且Z为氢,任选取代的低级烷基,任选取代的芳基或任选取代的芳烷基。 染料可用于纺织品,皮革,油墨和油漆等材料着色。

    Water soluble cationic azo dyestuffs
    2.
    发明授权
    Water soluble cationic azo dyestuffs 失效
    水溶性阳离子偶氮染料

    公开(公告)号:US4167509A

    公开(公告)日:1979-09-11

    申请号:US745777

    申请日:1976-11-29

    申请人: Brian Parton

    发明人: Brian Parton

    CPC分类号: C09B29/0003 C09B44/08

    摘要: Azo dyestuffs devoid of carboxylic acid and sulphonic acid groups and of the formula (I) ##STR1## wherein R is a hydrogen atom, halogen atom, cyano, nitro, hydroxy or amino group or an organic radical, R.sup.1 is a hydrogen atom, an optionally substituted hydrocarbon or heterocyclic radical or an amino group which may be substituted, Y is a group --COR.sup.2 or ##STR2## wherein R.sup.2 is an alkyl group having two or more carbon atoms, R.sup.3 is an alkyl group of more than three carbon atoms or an aralkyl group and R.sup.4 is hydrogen or an optionally substituted alkyl or aryl group, K.sup.+ is a cationic group, X.sup.- is an anion and the ring A may carry further substituents or have a benz ring fused thereon. Process for manufacture of the dyestuffs and their use for the coloration of synthetic polymers, in particular polyacrylonitrile and copolymers thereof.

    摘要翻译: 没有羧酸和磺酸基团和式(I)的偶氮染料其中R是氢原子,卤素原子,氰基,硝基,羟基或氨基或有机基团,R 1是氢 原子,任选取代的烃基或杂环基或可被取代的氨基,Y是基团-COR 2或者其中R 2是具有两个或更多个碳原子的烷基,R 3是大于3的烷基 碳原子或芳烷基,R 4是氢或任选取代的烷基或芳基,K +是阳离子基团,X是阴离子,环A可以携带另外的取代基或在其上稠合苯环。 用于制造染料的方法及其用于合成聚合物着色的用途,特别是聚丙烯腈及其共聚物。

    Colored polymers from azo dye monomers containing olefinic groups
    3.
    发明授权
    Colored polymers from azo dye monomers containing olefinic groups 失效
    含有烯烃基团的偶氮染料单体的着色聚合物

    公开(公告)号:US5188641A

    公开(公告)日:1993-02-23

    申请号:US819583

    申请日:1992-01-09

    申请人: Brian Parton

    发明人: Brian Parton

    IPC分类号: C09B69/10

    摘要: A colored polymer containing repeat units derived from at least one azo dye which is free from water-solubilizing groups and contains at least one polymerizable olefinically unsaturated group and has the formula:A--N.dbd.N--Ewherein A represents the residue of a carbocyclic or heterocyclic diazotisable amine containing at least one electron-withdrawing substituent and E represents the residue of a carbocyclic or heterocyclic coupling component with the proviso that when both A and E are carbocyclic, the residue of the diazotisable amine does not contain a nitro or chloro substituent except when another different electron-withdrawing substituent is also present, the or each polymerizable group being attached to a carbon atom forming part of residue A or E.

    摘要翻译: 含有衍生自至少一种偶氮染料的重复单元的着色聚合物,其不含水溶性基团并含有至少一个可聚合烯属不饱和基团,并具有下式:AN = NE其中A代表碳环或杂环重氮胺 含有至少一个吸电子取代基,E表示碳环或杂环偶合组分的残基,条件是当A和E均为碳环时,除重氮不饱和胺的残基不含硝基或氯取代基,除非另有不同之处 还存在吸电子取代基,该或每个可聚合基团连接到形成残基A或E的一部分的碳原子上。

    Coloration process for applying a colored polymer containing units
derived from an organic dye
    4.
    发明授权
    Coloration process for applying a colored polymer containing units derived from an organic dye 失效
    用于施加含有衍生自有机染料的单元的着色聚合物的着色方法

    公开(公告)号:US4763371A

    公开(公告)日:1988-08-16

    申请号:US870544

    申请日:1986-06-04

    申请人: Brian Parton

    发明人: Brian Parton

    IPC分类号: C09B69/10 D06P1/00

    CPC分类号: C09B69/10 D06P1/006 Y10S8/918

    摘要: A method for the coloration of textile materials which comprises applying thereto by a printing or continuous dyeing technique a colored polymer containing repeat units derived from at least one organic dye containing two or more polymerizable olefinically unsaturated groups.

    摘要翻译: 一种用于着色纺织材料的方法,其包括通过印刷或连续染色技术向其施加含有衍生自至少一种含有两个或多个可聚合烯属不饱和基团的有机染料的重复单元的着色聚合物。

    Arylazo-hydroxy pyridone dyes containing a pyridinium group
    5.
    发明授权
    Arylazo-hydroxy pyridone dyes containing a pyridinium group 失效
    含有吡啶鎓基的芳基 - 羟基吡啶酮染料

    公开(公告)号:US4124579A

    公开(公告)日:1978-11-07

    申请号:US745778

    申请日:1976-11-29

    申请人: Brian Parton

    发明人: Brian Parton

    摘要: Azo dyestuffs devoid of carboxylic acid and sulphonic acid groups and of the formula (I) ##STR1## wherein R is a hydrogen atom, halogen atom, cyano, nitro, hydroxy or amino group or an organic radical, R.sup.1 is a hydrogen atom, an optionally substituted hydrocarbon or heterocyclic radical or an amino group which may be substituted, Y is a group --OCOR.sup.2, --OSO.sub.2 R.sup.2 or --NHSO.sub.2 R.sup.2 wherein R.sup.2 is optionally substituted alkyl or aryl, K.sym. is a cationic group, X.crclbar. is an anion and the ring A may carry further substituents or have a benz ring fused thereon. Manufacture of such dyestuffs and use in the dyeing of synthetic polymeric materials.

    摘要翻译: 没有羧酸和磺酸基团和式(I)的偶氮染料其中R是氢原子,卤素原子,氰基,硝基,羟基或氨基或有机基团,R 1是氢 原子,任选取代的烃或杂环基或可被取代的氨基,Y是基团-OCOR 2,-OSO 2 R 2或-NHSO 2 R 2,其中R 2是任选取代的烷基或芳基,K(+)是阳离子基团X( - )是阴离子,环A可以携带另外的取代基或在其上稠合苯环。 这种染料的制造和用于合成聚合物材料的染色。

    Ink-jet printing
    6.
    发明授权
    Ink-jet printing 失效
    喷墨打印

    公开(公告)号:US5102448A

    公开(公告)日:1992-04-07

    申请号:US439622

    申请日:1989-11-21

    CPC分类号: C09D11/32 C09D11/34

    摘要: A method of printing in which a solid ink composition is melted and ejected from a small orifice in the form of small drops directed towards a substrate on which an image is to be formed, characterized in that the solid ink composition comprises either a solution or a dispersion of a dye or a finely divided pigment in a halogenated hydrocarbon having a melting point of at least 50.degree. C. ("Ink A"), or a colored condensation polymer obtained by reacting a polymerizable lactone or a hydroxyalkanoic acid with a dye containing at least one active hydrogen atom ("Ink B").

    Quaternized azo dyestuffs
    8.
    发明授权
    Quaternized azo dyestuffs 失效
    季铵化偶氮染料

    公开(公告)号:US4113717A

    公开(公告)日:1978-09-12

    申请号:US648568

    申请日:1976-01-12

    申请人: Brian Parton

    发明人: Brian Parton

    CPC分类号: C09B44/08 C09B44/103

    摘要: Azo dyestuffs devoid of carboxylic acid and sulphonic acid groups and of the formula I: ##STR1## wherein A.sym. is a positively-charged aromatic or heterocyclic group, X.crclbar. is an anion; R is hydrogen or an optionally-substituted alkyl, aryl, aralkyl or cycloalkyl group, R.sup.1 is hydrogen, or an optionally-substituted alkyl or aralkyl group and the quinoline ring may be further substituted, and processes for the manufacture of such dyestuffs which are useful for the coloration of synthetic polymeric materials such as acrylonitrile polymers and copolymers.

    摘要翻译: 没有羧酸和磺酸基团且具有式I的偶氮染料:其中A(+)是带正电荷的芳族或杂环基团,X( - )是阴离子; R是氢或任选取代的烷基,芳基,芳烷基或环烷基,R 1是氢或任选取代的烷基或芳烷基,喹啉环可以被进一步取代,以及制备这种有用的染料的方法 用于合成聚合物材料如丙烯腈聚合物和共聚物的着色。

    Dyestuffs
    9.
    发明授权
    Dyestuffs 失效
    染料

    公开(公告)号:US3996221A

    公开(公告)日:1976-12-07

    申请号:US539744

    申请日:1975-01-09

    CPC分类号: C09B62/0025 C09B19/02

    摘要: Dyestuffs of the formula ##STR1## WHEREIN (R).sub.n represents n substituents R each of which may be independently halogen, lower alkyl, lower alkoxy or COOHR.sup.1 is H, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl,n is 0-3,(a+b) is 0-4,X is O, S or NR.sup.2, where R.sup.2 is H or optionally substituted lower alkyl,Y is an optionally substituted aliphatic or optionally substituted araliphatic linking group, andEach Z is independently a H or a cellulose-reactive group, and when (a+b) is O there is at least one SO.sub.3 H group as substituent on the groups R.sup.1, X or Y.The dyestuffs when both Z are H are valuable acid dyes, e.g. for wool, and when one or both Z are reactive groups the dyestuffs are valuable reactive dyestuff especially for cellulose fibers.

    摘要翻译: 下式的染料n表示n个取代基R,其各自独立地为卤素,低级烷基,低级烷氧基或COOH R 1为H,任选取代的低级烷基,任选取代的芳基或任选取代的芳烷基,N IS 0-3,(A + B)IS 0-4,X为O,S或NR2,其中R2为H或任选取代的低级烷基,Y为任选取代的脂族或任选取代的芳脂族连接基团,EACH Z独立地为 H或纤维素反应性基团,当(a + b)为O时,在基团R 1,X或Y上存在至少一个SO 3 H基团作为取代基。