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    Method and composition for enhanced hydrocarbons recovery
    1.
    发明授权
    Method and composition for enhanced hydrocarbons recovery 有权
    增强烃回收的方法和组成

    公开(公告)号：US08759261B2

    公开(公告)日：2014-06-24

    申请号：US12366558

    申请日：2009-02-05

    申请人： Julian Richard Barnes ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    发明人： Julian Richard Barnes ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    IPC分类号： C09K8/584 ,  B23G1/06 ,  E21B43/22

    CPC分类号： C09K8/584

    摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.

    摘要翻译： 本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物 与含烃地层中的烃相互作用。 增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY
    2.
    发明申请
    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
    增强烃回收方法与组合

    公开(公告)号：US20090203557A1

    公开(公告)日：2009-08-13

    申请号：US12366558

    申请日：2009-02-05

    申请人： Julian Richard BARNES ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    发明人： Julian Richard BARNES ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    IPC分类号： C09K8/584 ,  C09K8/68

    CPC分类号： C09K8/584

    摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.

    摘要翻译： 本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物 与含烃地层中的烃相互作用。 增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY
    4.
    发明申请
    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
    增强烃回收方法与组合

    公开(公告)号：US20110021389A1

    公开(公告)日：2011-01-27

    申请号：US12866245

    申请日：2009-02-06

    申请人： Kirk Herbert Raney ,  Thomas Carl Semple

    发明人： Kirk Herbert Raney ,  Thomas Carl Semple

    IPC分类号： C09K8/58

    CPC分类号： C09K8/584

    摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the hydrocarbon recovery composition comprises a propoxylated composition which comprises (1) a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5, preferably from 3 to 12, moles of propylene oxide per mole of primary alcohol and (2) polypropylene glycol; provided that the primary alcohol is propoxylated by contacting the alcohol with propylene oxide in the presence of a catalytically effective amount of one or more of the phosphate salts of lanthanum series elements or the rare earth elements, preferably a carbonate salt thereof, wherein the propoxylated composition comprising the propoxylated alcohol and from 1 to 30 wt % of polypropylene glycol is produced; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

    摘要翻译： 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供烃回收组合物，其中所述烃回收组合物包含丙氧基化组合物，其包含（1）丙氧基化初级的甘油磺酸盐 具有平均碳数为10至24并且每个脂族基团的平均分支数为0.7至2.5并且每摩尔初级粒子具有至少0.5，优选3至12摩尔环氧丙烷的支链脂族基团的醇的醇， 醇和（2）聚丙二醇; 条件是通过在催化有效量的一种或多种镧系元素的磷酸盐或稀土元素，优选其碳酸盐的存在下，使醇与环氧丙烷接触，将伯醇丙氧基化，其中丙氧基化组合物 包括丙氧基化醇和1至30wt％的聚丙二醇; 和（b）允许组合物与含烃地层中的烃相互作用。

    Method and composition for enhanced hydrocarbons recovery
    6.
    发明授权
    Method and composition for enhanced hydrocarbons recovery 有权
    增强烃回收的方法和组成

    公开(公告)号：US08664167B2

    公开(公告)日：2014-03-04

    申请号：US12866245

    申请日：2009-02-06

    申请人： Kirk Herbert Raney ,  Thomas Carl Semple

    发明人： Kirk Herbert Raney ,  Thomas Carl Semple

    IPC分类号： C09K8/584

    CPC分类号： C09K8/584

    摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the hydrocarbon recovery composition comprises a propoxylated composition which comprises (1) a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5, preferably from 3 to 12, moles of propylene oxide per mole of primary alcohol and (2) polypropylene glycol; provided that the primary alcohol is propoxylated by contacting the alcohol with propylene oxide in the presence of a catalytically effective amount of one or more of the phosphate salts of lanthanum series elements or the rare earth elements, preferably a carbonate salt thereof, wherein the propoxylated composition comprising the propoxylated alcohol and from 1 to 30 wt % of polypropylene glycol is produced; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

    摘要翻译： 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供烃回收组合物，其中所述烃回收组合物包含丙氧基化组合物，其包含（1）丙氧基化初级的甘油磺酸盐 具有平均碳数为10至24并且每个脂族基团的平均分支数为0.7至2.5并且每摩尔初级粒子具有至少0.5，优选3至12摩尔环氧丙烷的支链脂族基团的醇的醇， 醇和（2）聚丙二醇; 条件是通过在催化有效量的一种或多种镧系元素的磷酸盐或稀土元素，优选其碳酸盐的存在下，使醇与环氧丙烷接触，将伯醇丙氧基化，其中丙氧基化组合物 包括丙氧基化醇和1至30wt％的聚丙二醇; 和（b）允许组合物与含烃地层中的烃相互作用。

    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY
    7.
    发明申请
    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
    增强烃回收方法与组合

    公开(公告)号：US20090203558A1

    公开(公告)日：2009-08-13

    申请号：US12366554

    申请日：2009-02-05

    申请人： Julian Richard BARNES ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit

    发明人： Julian Richard BARNES ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit

    IPC分类号： C09K8/84

    CPC分类号： C09K8/58 ,  C09K8/584

    摘要： A method of treating a hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein (i) when the salinity of the brine is from about 2 wt % to about 4 wt %, the composition comprises a blend of a C20-24 internal olefin sulfonate and a C24-28 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C24-28 internal olefin sulfonate is from about 90:10 to about 70:30 and (ii) when the salinity of the brine is greater than about 4 wt % up to about 13 wt % the composition comprises a blend of a C20-24 internal olefin sulfonate and a C15-18 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C15-18 internal olefin sulfonate is from about 90:10 to about 70:30; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

    摘要翻译： 描述了处理含烃地层的方法。 该方法包括（a）向含烃地层的至少一部分提供烃回收组合物，其中（i）当盐水的盐度为约2重量％至约4重量％时，该组合物包含 C20-24内烯烃磺酸盐和C24-28内烯烃磺酸盐，其中C20-24内烯烃磺酸盐与C24-28内烯烃磺酸盐的重量比为约90:10至约70:30，（ii） 当盐水的盐度大于约4重量％至多约13重量％时，组合物包含C20-24内烯烃磺酸盐和C15-18内烯烃磺酸盐的共混物，其中C20-24内部的重量比 烯烃磺酸盐与C15-18内烯烃磺酸盐的摩尔比为约90:10至约70:30; 和（b）允许组合物与含烃地层中的烃相互作用。

    Method and composition for enhanced hydrocarbons recovery
    8.
    发明授权
    Method and composition for enhanced hydrocarbons recovery 有权
    增强烃回收的方法和组成

    公开(公告)号：US08664166B2

    公开(公告)日：2014-03-04

    申请号：US12866249

    申请日：2009-02-06

    申请人： Kirk Herbert Raney ,  Thomas Carl Semple

    发明人： Kirk Herbert Raney ,  Thomas Carl Semple

    IPC分类号： C09K8/584 ,  B01F17/00

    CPC分类号： C09K8/584

    摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises a derivative selected from the group consisting of a carboxylate or a sulfate or glycerol sulfonate of an ethoxylated/propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5 moles of propylene oxide per mole of primary alcohol and having at least 0.5 moles of ethylene oxide per mole of primary alcohol; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

    摘要翻译： 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供组合物，其中所述组合物包含选自乙氧基化物的羧酸盐或硫酸盐或甘油磺酸盐的衍生物 具有平均碳数为10〜24的支链脂族基团的丙氧基化伯醇，每个脂肪族基团的平均分支数为0.7〜2.5，并且每摩尔伯醇具有至少0.5摩尔环氧丙烷，并具有 每摩尔伯醇至少0.5摩尔环氧乙烷; 和（b）允许组合物与含烃地层中的烃相互作用。

    Method and composition for enhanced hydrocarbons recovery
    9.
    发明授权
    Method and composition for enhanced hydrocarbons recovery 有权
    增强烃回收的方法和组成

    公开(公告)号：US09102862B2

    公开(公告)日：2015-08-11

    申请号：US12866246

    申请日：2009-02-06

    申请人： Kirk Herbert Raney ,  Thomas Carl Semple

    发明人： Kirk Herbert Raney ,  Thomas Carl Semple

    IPC分类号： C09K8/60 ,  C09K8/584

    CPC分类号： C09K8/584

    摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5 moles of propylene oxide per mole of primary alcohol; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.

    摘要翻译： 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供组合物，其中所述组合物包含具有平均碳数的支链脂族基团的丙氧基化伯醇的甘油磺酸盐， 10至24，并且每个脂族基团的平均支链数为0.7至2.5，并且每摩尔伯醇具有至少0.5摩尔环氧丙烷; 和（b）允许组合物与含烃地层中的烃相互作用。