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    Catalytic trimerization and tetramerization of olefinic monomers
    3.
    发明授权
    Catalytic trimerization and tetramerization of olefinic monomers 失效
    烯烃单体的催化三聚和四聚

    公开(公告)号：US07381857B2

    公开(公告)日：2008-06-03

    申请号：US11770520

    申请日：2007-06-28

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C07C2/08

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/10 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/02 ,  C07C11/107

    摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I): (R1)(R2)P-X-P(R3)(R4)  (I) where X is a bivalent organic bridging group, R1 and R3 are hydrocarbyl groups, and R2 and R4 are aromatic groups; and c) a second ligand having the general formula (II): (R1′)(R2′)P-X′-P(R3′)(R4′)  (II) where X′ is a bridging group containing nitrogen and R1′, R2′, R3′ and R4′ are hydrocarbyl groups. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.

    摘要翻译： 一种催化剂前体组合物，其包含a）铬，钼或钨的源; b）具有通式（I）的第一配体：<？in-line-formula description =“In-line formula”end =“lead”？>（R 1 SUP） （2）PXP（R 3）（R 4）（I）<βin-line-formula description =“In-line Formulas”end = “尾”→>其中X是二价有机桥基，R 1和R 3是烃基，R 2和R 2， SUP> 4是芳基; 和（c）具有通式（II）的第二配位体：<？in-line-formula description =“In-line formula”end =“lead”→（R 1> （二）'P-X'-P（R 3'）（R 4'）（II）<β在线式 description =“In-line Formulas”end =“tail”？>其中X'是含有氮和R 1'的桥连基团，R 2'，R“ > 3'和R 4'是烃基。 本发明还涉及包含本发明的催化剂前体组合物和助催化剂的催化剂体系。

    Catalytic trimerization and tetramerization of olefinic monomers
    4.
    发明授权
    Catalytic trimerization and tetramerization of olefinic monomers 有权

    公开(公告)号：US07259123B2

    公开(公告)日：2007-08-21

    申请号：US11398777

    申请日：2006-04-06

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： B01J31/00 ,  C07C2/08

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/10 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/02 ,  C07C11/107

    摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I); (R1)(R2)P—X—P(R3)(R4)  (I) wherein X is a bivalent organic bridging group; R1 and R3 are independently selected from, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, with the proviso that when R1 and R3 are aromatic groups they do not contain a polar substituent at any of the ortho-positions; R2 and R4 are independently selected from optionally substituted aromatic groups, each R2 and R4 bearing a polar substituent on at least one of the ortho-positions; and c) a second ligand having the general formula (II); (R1′)(R2′)P—X′—P(R3′)(R4′)  (II) wherein X′ is a bridging group of the formula —N(R5′)—, wherein R5′ is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; and R1′, R2′, R3′ and R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups of which at least one of R1′, R2′, R3′ and R4′ is substituted with a polar substituent, or R1′, R2′, R3′ and R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, wherein any substituents on one or more of R1′, R2′, R3′ and R4′ are non-polar. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.

    Method and composition for enhanced hydrocarbons recovery
    5.
    发明授权
    Method and composition for enhanced hydrocarbons recovery 有权
    增强烃回收的方法和组成

    公开(公告)号：US08759261B2

    公开(公告)日：2014-06-24

    申请号：US12366558

    申请日：2009-02-05

    申请人： Julian Richard Barnes ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    发明人： Julian Richard Barnes ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    IPC分类号： C09K8/584 ,  B23G1/06 ,  E21B43/22

    CPC分类号： C09K8/584

    摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.

    摘要翻译： 本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物 与含烃地层中的烃相互作用。 增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    6.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20100311932A1

    公开(公告)日：2010-12-09

    申请号：US12859337

    申请日：2010-08-19

    申请人： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/22 ,  C07F9/08 ,  B01J31/12

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY
    7.
    发明申请
    METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
    增强烃回收方法与组合

    公开(公告)号：US20090203557A1

    公开(公告)日：2009-08-13

    申请号：US12366558

    申请日：2009-02-05

    申请人： Julian Richard BARNES ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    发明人： Julian Richard BARNES ,  Kirk Herbert Raney ,  Thomas Carl Semple ,  Paul Gregory Shpakoff ,  Johan Paul Smit ,  Jasper Roelf Smit

    IPC分类号： C09K8/584 ,  C09K8/68

    CPC分类号： C09K8/584

    摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.

    摘要翻译： 本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物 与含烃地层中的烃相互作用。 增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    9.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 有权
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20100317814A1

    公开(公告)日：2010-12-16

    申请号：US12859327

    申请日：2010-08-19

    申请人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    发明人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    IPC分类号： C08F4/78 ,  C07F9/06 ,  B01J31/18

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (II); P(R1)(R2)—P(R4)═N(R3)  (II) wherein: the R1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R2 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及配体及其在烯烃单体低聚催化剂中的用途，具有通式（II）的配体; P（R 1）（R 2）-P（R 4）= N（R 3）（II）其中：R 1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
    10.
    发明授权
    Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers 有权
    用于催化低聚烯烃单体的配体及其催化剂体系

    公开(公告)号：US07803886B2

    公开(公告)日：2010-09-28

    申请号：US11961638

    申请日：2007-12-20

    申请人： Eric Johannes Maria De Boer ,  Harry Van der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/22 ,  C07F9/535 ,  B01J31/02

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R4)—P(R1)(R2)═N(R3)  (I) wherein: the R1 group and R2 group are independently selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（I）的配体; P（R 4）-P（R 1）（R 2）= N（R 3）（I）其中：R 1基团和R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。