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1.发明授权公开(公告)号：US06902846B2
公开(公告)日：2005-06-07
申请号：US10014250
申请日：2001-12-10
申请人： Kiyoshi Hayashi , Munehisa Ikoma , Jun Matsumura
发明人： Kiyoshi Hayashi , Munehisa Ikoma , Jun Matsumura
CPC分类号： H01M4/32 , H01M4/30 , H01M4/808 , H01M10/30 , Y02E60/124 , Y02P70/54 , Y10T29/49112
摘要： A positive electrode plate for alkaline storage battery that does not swell very much even after repeated charge-discharge cycles and can be manufactured easily, a method for manufacturing the same, and an alkaline storage battery using the same are provided. A conductive support (nickel foam) and an active material (nickel hydroxide particles) that is supported by the support are provided. An intermediate part of a positive electrode plate has a larger porosity than surface parts thereof.
摘要翻译： 一种碱性蓄电池用正极板，即使在重复的充放电循环后也不会膨胀，容易制造，其制造方法和使用其的碱性蓄电池。 提供由支撑体支撑的导电支撑（镍泡沫）和活性材料（氢氧化镍颗粒）。 正极板的中间部分的孔隙率比其表面部分大。
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公开(公告)号：US5968685A
公开(公告)日：1999-10-19
申请号：US135955
申请日：1998-08-18
申请人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
发明人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
CPC分类号： H01M4/801 , B22F3/1137 , B22F3/1143 , H01M4/667 , H01M4/80 , H01M4/808 , B22F2998/00 , B22F2998/10 , B22F2999/00 , H01M10/30 , H01M2300/0014 , H01M4/661 , Y10T428/31678
摘要： A battery electrode substrate which is constituted of a porous metallic body structure having communicating pores at a porosity of at least 90% and an Fe/Ni multilayer structure wherein the skeletal portion of the porous metallic body is composed mainly of Fe and has an Ni covering layer on the surface thereof while pores communicating with the inside and outside of Fe skeletal portion exist in the Fe skeletal portion and the inside of the pores is covered with Ni. The electrode substrate is produced by applying an iron oxide powder of at most 20 .mu.m in an average particle size on a porous resin core body; heat treating the core to remove an organic resin component while simultaneously sintering Fe to obtain a porous Fe body; and then covering the Fe skeletal portion with Ni by electroplating. In this process, the iron oxide can be used in combination with carbon powder. Further, a nickel porous sintered body can also be produced using nickel oxide in place of iron oxide.
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公开(公告)号：US5888658A
公开(公告)日：1999-03-30
申请号：US32508
申请日：1998-02-27
申请人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
发明人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
CPC分类号： H01M4/801 , B22F3/1137 , B22F3/1143 , H01M4/667 , H01M4/80 , H01M4/808 , B22F2998/00 , B22F2998/10 , B22F2999/00 , H01M10/30 , H01M2300/0014 , H01M4/661 , Y10T428/31678
摘要： A battery electrode substrate which is constituted of a porous metallic body structure having communicating pores at a porosity of at least 90% and an Fe/Ni multilayer structure wherein the skeletal portion of the porous metallic body is composed mainly of Fe and has an Ni covering layer on the surface thereof while pores communicating with the inside and outside of Fe skeletal portion exist in the Fe skeletal portion and the inside of the pores is covered with Ni. The electrode substrate is produced by applying an iron oxide powder of at most 20 .mu.m in an average particle size on a porous resin core body; heat treating the core to remove an organic resin component while simultaneously sintering Fe to obtain a porous Fe body; and then covering the Fe skeletal portion with Ni by electroplating. In this process, the iron oxide can be used in combination with carbon powder. Further, a nickel porous sintered body can also be produced using nickel oxide in place of iron oxide.
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公开(公告)号：US5851599A
公开(公告)日：1998-12-22
申请号：US717191
申请日：1996-09-20
申请人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
发明人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
CPC分类号： H01M4/801 , B22F3/1137 , B22F3/1143 , H01M4/667 , H01M4/80 , H01M4/808 , B22F2998/00 , B22F2998/10 , B22F2999/00 , H01M10/30 , H01M2300/0014 , H01M4/661 , Y10T428/31678
摘要： A battery electrode substrate which is constituted of a porous metallic body structure having communicating pores at a porosity of at least 90% and an Fe/Ni multilayer structure wherein the skeletal portion of the porous metallic body is composed mainly of Fe and has an Ni covering layer on the surface thereof while pores communicating with the inside and outside of Fe skeletal portion exist in the Fe skeletal portion and the inside of the pores is covered with Ni. The electrode substrate is produced by applying an iron oxide powder of at most 20 .mu.m in an average particle size on a porous resin core body; heat treating the core to remove an organic resin component while simultaneously sintering Fe to obtain a porous Fe body; and then covering the Fe skeletal portion with Ni by electroplating. In this process, the iron oxide can be used in combination with carbon powder. Further, a nickel porous sintered body can also be produced using nickel oxide in place of iron oxide.
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5.发明授权公开(公告)号：US06358648B2
公开(公告)日：2002-03-19
申请号：US09255583
申请日：1999-02-22
IPC分类号： H01M432
CPC分类号： H01M4/52 , C01G53/04 , C01P2002/74 , C01P2006/40 , C01P2006/80 , H01M4/32 , H01M10/345 , Y02E60/124 , Y10T29/49108
摘要： Disclosed is an active material for constituting a nickel electrode for alkaline storage batteries which has a high utilization at high ambient temperatures and therefore realizes a battery of higher energy density and a longer cycle life. The nickel electrode active material comprises a nickel hydroxide powder prepared from nickel sulfate and contains SO42− at 0.4 wt % or less in the crystal of the powder. The nickel hydroxide is preferably solid solution nickel hydroxide incorporating therein at least one element selected from the group consisting of cobalt, cadmium, zinc and magnesium.
摘要翻译： 公开了一种用于构成用于碱性蓄电池的镍电极的活性材料，其在高环境温度下具有高利用率，因此实现了更高能量密度和更长循环寿命的电池。 镍电极活性材料包括由硫酸镍制备的氢氧化镍粉末，并且在粉末晶体中含有0.4重量％以下的SO42-。 氢氧化镍优选为其中结合有至少一种选自钴，镉，锌和镁的元素的固体氢氧化镍。
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公开(公告)号：US06340453B1
公开(公告)日：2002-01-22
申请号：US09613754
申请日：2000-07-11
IPC分类号： C01G5300
摘要： The instant specification discloses a method for producing nickel hydroxide from an aqueous solution containing an ammonium ion and dissolved nickel hydroxide in an alkaline state, which is characterized in that pH of the solution is controlled by supplying a hydroxide ion generated by water electrolysis thereto. The method of the invention is an environmentally friendly one for producing nickel hydroxide, which enables an easy control of physical properties of nickel hydroxide.
摘要翻译： 本说明书公开了一种从碱性状态的含有铵离子和溶解的氢氧化镍的水溶液中制造氢氧化镍的方法，其特征在于，通过向其中供给水电解产生的氢氧根离子来控制溶液的pH。 本发明的方法是用于生产氢氧化镍的环保型方法，其能够容易地控制氢氧化镍的物理性能。
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公开(公告)号：US5707761A
公开(公告)日：1998-01-13
申请号：US732186
申请日：1996-10-17
CPC分类号： H01M10/288 , H01M4/32 , H01M4/52 , H01M4/62 , H01M10/30 , H01M10/345 , Y02E60/124
摘要： An improved non-sintered type nickel positive electrode comprising a nickel hydroxide powder as an active material and a cobalt hydroxide powder for improving the utilization of the active material, and an alkaline storage battery configured with the positive electrode are disclosed. In the non-sintered type nickel positive electrode, at least part of the surfaces of the particles of the cobalt hydroxide powder is covered with a stabilizing agent of at least one member selected from the group consisting of a higher carboxylic acid, an ester of carboxylic acid, an aldehyde, a phenol and a vitamin.
摘要翻译： 公开了一种改进的非烧结型镍正极，其包含作为活性物质的氢氧化镍粉末和用于提高活性物质利用率的氢氧化钴粉末，以及配置有正极的碱性蓄电池。 在非烧结型镍正极中，氢氧化钴粉末颗粒的至少一部分表面被选自以下的至少一种的稳定剂所覆盖：高级羧酸，羧酸酯 酸，醛，苯酚和维生素。
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公开(公告)号：US6103319A
公开(公告)日：2000-08-15
申请号：US135953
申请日：1998-08-18
申请人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
发明人： Keizo Harada , Kenichi Watanabe , Shosaku Yamanaka , Kiyoshi Hayashi , Nobuyasu Morishita , Hiroki Takeshima , Hideo Kaiya , Munehisa Ikoma
CPC分类号： H01M4/801 , B22F3/1137 , B22F3/1143 , H01M4/667 , H01M4/80 , H01M4/808 , B22F2998/00 , B22F2998/10 , B22F2999/00 , H01M10/30 , H01M2300/0014 , H01M4/661
摘要： A battery electrode substrate which is constituted of a porous metallic body structure having communicating pores at a porosity of at least 90% and an Fe/Ni multilayer structure wherein the skeletal portion of the porous metallic body is composed mainly of Fe and has an Ni covering layer on the surface thereof while pores communicating with the inside and outside of Fe skeletal portion exist in the Fe skeletal portion and the inside of the pores is covered with Ni. The electrode substrate is produced by applying an iron oxide powder of at most 20 .mu.m in an average particle size on a porous resin core body; heat treating the core to remove an organic resin component while simultaneously sintering Fe to obtain a porous Fe body; and then covering the Fe skeletal portion with Ni by electroplating. In this process, the iron oxide can be used in combination with carbon powder. Further, a nickel porous sintered body can also be produced using nickel oxide in place of iron oxide.
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公开(公告)号：US06027834A
公开(公告)日：2000-02-22
申请号：US937797
申请日：1997-09-25
CPC分类号： H01M4/52 , H01M10/30 , H01M4/32 , H01M4/383 , Y02E60/124
摘要： For providing an alkaline storage battery having a high energy density in a broader temperature range, the charge efficiency of a nickel positive electrode at the time of charging at high temperatures is enhanced by incorporating verbium and at least two elements selected from the group consisting of yttrium, and ytterbium in the form of a compound those and further at least one element selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, gadolinium, terbium, dysprosium, holmium, thulium, cerium, promethium, europium, and lutetium in the form of a compound into a positive electrode paste containing a major component of nickel oxide as an active material.
摘要翻译： 为了在较宽的温度范围内提供具有高能量密度的碱性蓄电池，在高温充电时镍正极的充电效率通过掺入韭菜和至少两种选自钇 和镱以化合物的形式存在，并且还包含选自镧，镨，钕，钐，钆，铽，镝，钬，ium，铈，ium，铕和镥中的至少一种元素 化合物的形式成为含有作为活性物质的氧化镍的主要成分的正极浆料。
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10.发明授权Nickel positive electrode for alkaline rechargeable batteries and nickel metal hydride cells 失效镍正极用于碱性可再充电电池和镍金属氢化物电池
公开(公告)号：US5968684A
公开(公告)日：1999-10-19
申请号：US918185
申请日：1997-08-21
摘要： In the paste type nickel positive electrode prepared by filling pores of a metal nickel plaque made of three-dimensional high porous sheet, or coating both sides or one side of a plaque made of either perforated nickel sheet or nickel plated steel sheet, with a paste type active material mainly composed of nickel hydroxide, by adding particles of cobalt hydroxide having the specific surface area of at least 10 m.sup.2 /g, average particle size of 1.7 microns or more, and content of fine particles with particle size of 1.0 micron or less of 20% or less, the utilization of positive electrode active material is enhanced, and by using this nickel positive electrode, the alkaline rechargeable battery, in particular, the nickel-metal hydride alkaline battery is enhanced in capacity and extended in service life.
摘要翻译： 在通过填充由三维高多孔片制成的金属镍斑块的孔隙或者由用多孔镍板或镀镍钢板制成的斑块的两面或一面涂敷糊状镍电极中， 主要由氢氧化镍组成的活性物质，通过加入比表面积至少为10m 2 / g，平均粒度为1.7微米以上的氢氧化钴颗粒和粒径为1.0微米以下的细颗粒的含量 20％以下，正极活性物质的利用率提高，通过使用该镍正极，碱性二次电池，特别是镍 - 氢化物碱性电池的容量增加，使用寿命延长。
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