公开(公告)号：US5726241A

公开(公告)日：1998-03-10

申请号：US715098

申请日：1996-09-17

申请人： Kunio Maruyama ,  Ryuichi Koide

发明人： Kunio Maruyama ,  Ryuichi Koide

IPC分类号： D01F9/22 ,  C08L83/00

CPC分类号： D01F9/22 ,  D06M13/342 ,  D06M13/368 ,  D06M13/372 ,  D06M15/53 ,  D06M15/6436 ,  D06M2101/28

摘要： A finish composition for a precursor for high-performance carbon fibers, containing (1) 0.2-10 parts by weight of an aminocarboxylic material selected from the group consisting of carboxylic acid salts of alkylamines, carboxylic acid salts of arylamines, carboxylic acid salts of alkylarylamines, amino acids and betaine compounds, and (2) 100 parts by weight of a mixture of (a) 80-20 parts by weight of a finish prepared by adding, to (i) a silicone finish containing 50 wt % or more of an amino-modified polysiloxane having a nitrogen content in amino groups in the range of 0.05-2.0 wt % and a viscosity at 25.degree. C. of 500 centistokes or more, (ii) 0.3-5.0 molar equivalents of a lower aliphatic monocarboxylic acid of 6 carbon atoms or less with respect to 1 mole of the amino group, and (b) 20-80 parts by weight of a nonionic emulsifier consisting mainly of a polyoxyethylene alkyl ether, a polyoxyethylene alkylaryl ether or a polyoxyethylene fatty acid ester. The finish composition prevents aging of a precursor during its preservation. Also provided is an acrylonitrile precursor for high-performance carbon fibers on which the finish composition is deposited.

摘要翻译： 含有（1）0.2-10重量份的选自烷基胺的羧酸盐，芳基胺的羧酸盐，烷基芳基胺的羧酸盐的氨基
碳原子数为0.2-10重量份的用于高性能碳纤维前体的组合物 ，氨基酸和甜菜碱化合物，和（2）100重量份的（a）80-20重量份的整理剂的混合物，其通过以下步骤制备：（i）含有50重量％或更多的 氨基改性聚硅氧烷，其氨基含量在0.05-2.0重量％范围内，25℃下的粘度为500厘沲或更多，（ii）0.3-5.0摩尔当量的低级脂族单羧酸6 碳原子或更少，和（b）20-80重量份主要由聚氧乙烯烷基醚，聚氧乙烯烷基芳基醚或聚氧乙烯脂肪酸酯组成的非离子乳化剂。 完成组合物防止前体在其保存期间的老化。 还提供了用于高性能碳纤维的丙烯腈前体，其上沉积有组合物。