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公开(公告)号:US11939453B2
公开(公告)日:2024-03-26
申请号:US17602673
申请日:2020-06-11
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Seok Ho Jeong , Jeong Ju Moon , Woo Hyuk Choi
IPC分类号: C08K5/11 , C08K5/1515
CPC分类号: C08K5/11 , C08K5/1515
摘要: A plasticizer composition including a citrate-based material and an epoxidized oil, and the plasticizer composition capable of maintaining an excellent plasticization efficiency and providing an improved mechanical properties and stress resistance when compared with conventional phthalate-based plasticizer products.
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公开(公告)号:US20220195143A1
公开(公告)日:2022-06-23
申请号:US17606403
申请日:2020-07-29
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Seok Ho Jeong , Jeong Ju Moon , Woo Hyuk Choi , Yun Ki Cho , Joo Ho Kim
摘要: A citrate-based plasticizer composition including a citrate-based composition, and a citrate-based composition including one or more citrates. The citrates are characterized in having an alkyl group derived from an isomer mixture of hexyl alcohol having a degree of branching of 2.0 or less. Stress resistance and mechanical properties can be maintained at values equal or better than conventional plasticizers, the balance between migration and volatile properties and plasticization efficiency can be maintained, and light resistance and heat resistance can be markedly improved by applying the citrate-based plasticizer composition to a resin.
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公开(公告)号:US11827767B2
公开(公告)日:2023-11-28
申请号:US16772065
申请日:2019-07-03
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Jeong Ju Moon , Woo Hyuk Choi
IPC分类号: C08K5/12 , C08K5/00 , C08L101/00
CPC分类号: C08K5/12 , C08K5/0016 , C08L101/00
摘要: Provided is a plasticizer composition comprising a cyclohexane polyester-based substance which is a compound of Chemical Formula 1 as a plasticizer:
in combination with a perhydride comprising a compound of Chemical Formula 2 having a smaller number of ester groups than the cyclohexane polyester-based substance:
Also provided are resin compositions containing the plasticizer composition and methods of preparing the plasticizer composition.-
公开(公告)号:US11629116B2
公开(公告)日:2023-04-18
申请号:US17051373
申请日:2019-05-30
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Seok Ho Jeong , Woo Hyuk Choi , Yun Ki Cho , Jeong Ju Moon , Joo Ho Kim
IPC分类号: C07C69/75 , C07C69/704 , C08K5/101 , C08K5/12
摘要: Provided is a plasticizer composition including: a cyclohexane-1,2-diester-based substance of the following Chemical Formula 1; and a citrate-based substance of the following Chemical Formula 2: wherein in Chemical Formula 1 and Chemical Formula 2: R1 and R2 each independently are a C8 to C10 alkyl group; and R3 to R5 each independently are a C5 to C10 alkyl group.
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公开(公告)号:US20220242814A1
公开(公告)日:2022-08-04
申请号:US17615787
申请日:2020-09-24
申请人: LG CHEM, LTD.
发明人: Jeong Ju Moon , Hyun Kyu Kim , Joo Ho Kim , Yun Ki Cho , Seok Ho Jeong , Woo Hyuk Choi
IPC分类号: C07C67/08
摘要: A method of preparing a raw material mixture by mixing a dicarboxylic acid and a C4-10 mono-alcohol, and obtaining a product mixture including a diester-based material and water by reacting the raw material mixture in the presence of a catalyst. In the first step, at least one among a reactor temperature (Condition A), an alcohol input amount (Condition B), and an inert gas input amount (Condition C) is controlled, and the distinction between a beginning stage of a reaction and an ending stage of the reaction in Conditions A to C above is based on a reaction control point. The reaction control point is a point of time selected at which a conversion rate of the reaction is between 10% and 80%. This method produces a diester-based material with improved reactivity and improved energy expenditure.
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公开(公告)号:US20230374263A1
公开(公告)日:2023-11-23
申请号:US18031125
申请日:2022-06-22
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Joo Ho Kim , Woo Hyuk Choi , Jeong Ju Moon , Seok Ho Jeong
IPC分类号: C08K5/11
CPC分类号: C08K5/11
摘要: The present invention relates to a triester-based plasticizer composition characterized in comprising a product derived from the esterification of a hexanoic acid isomer mixture and a trihydric alcohol, wherein the degree of branching of the hexanoic acid isomer mixture is 2.0 or less. If the plasticizer composition is applied to a resin, migration resistance and volatile loss may be maintained to equal levels, and mechanical properties, absorption rate, stress migration and plasticization efficiency may be markedly improved in contrast to a case applying the conventional plasticizer.
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公开(公告)号:US12122895B2
公开(公告)日:2024-10-22
申请号:US17052156
申请日:2019-08-23
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Jeong Ju Moon , Woo Hyuk Choi , Yun Ki Cho , Joo Ho Kim , Seok Ho Jeong
摘要: Provided is a plasticizer composition, comprising: two or more kinds of terephthalates of the same carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is the same; and one or more kinds of terephthalates of a different carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is different, the different carbon number type comprises a higher alkyl and a lower alkyl, the higher alkyl is selected from alkyl groups having a carbon number of 8 or less, and the lower alkyl is selected from alkyl groups having a carbon number of 5 or more.
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8.
公开(公告)号:US12012499B2
公开(公告)日:2024-06-18
申请号:US17442435
申请日:2020-04-29
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Jeong Ju Moon , Woo Hyuk Choi , Joo Ho Kim
CPC分类号: C08K5/12 , C07C69/75 , C07C2601/08 , C07C2601/14
摘要: The present disclosure relates to a plasticizer composition characterized in having alkyl groups derived from an isomer mixture of hexyl alcohol with the degree of branching of less than 2.0 as a cyclohexane triester. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties may be maintained to equal or better levels, migration and loss properties and plasticization efficiency may keep balance, and light resistance and heat resistance may be markedly improved.
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公开(公告)号:US11795299B2
公开(公告)日:2023-10-24
申请号:US17050933
申请日:2019-06-03
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Yun Ki Cho , Woo Hyuk Choi , Jeong Ju Moon , Joo Ho Kim , Seok Ho Jeong
IPC分类号: C08K5/12 , C08K5/00 , C08K5/1515 , C08L101/00
CPC分类号: C08K5/12 , C08K5/0016 , C08K5/1515 , C08L101/00
摘要: Provided is a plasticizer composition including a cyclohexane-1,2-diester-based material of Formula 1 and a trimellitate-based material of Formula 2:
wherein in Formula 1 and Formula 2, R1 to R5 are each independently an alkyl group of 8 to 10 carbon atoms.-
10.
公开(公告)号:US11851547B2
公开(公告)日:2023-12-26
申请号:US17055029
申请日:2019-10-29
申请人: LG CHEM, LTD.
发明人: Hyun Kyu Kim , Yun Ki Cho , Jeong Ju Moon , Joo Ho Kim , Seok Ho Jeong , Woo Hyuk Choi
摘要: A plasticizer composition which includes a lower non-hybrid-type cyclohexane triester, a lower hybrid-type cyclohexane triester, a higher hybrid-type cyclohexane triester, and a higher non-hybrid-type cyclohexane triester, wherein the alkyl groups of the cyclohexane triesters are a combination of C3-C6 alkyl groups and C7-C10 alkyl groups. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties are maintained at an equivalent level or improved, migration properties, volatile loss characteristics, and plasticization efficiency are balanced, and light resistance and heat resistance are significantly improved.
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