公开(公告)号：US5389662A

公开(公告)日：1995-02-14

申请号：US687938

申请日：1991-05-31

申请人： Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

发明人： Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

IPC分类号： A01N43/30 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N47/38 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/06 ,  A01N53/08 ,  A01N53/14 ,  A01N43/28

CPC分类号： A01N53/00

摘要： The invention relates to novel combined compositions for combatting plant, animal and sanitarian as well as forestry, horticultural and warehouse pests. These compositions contain a pyrethroid-type insecticide as an insecticidally active ingredient and at least one fungicide inhibiting the ergosterol biosynthesis as activity-strengthening agent as well as optionally piperonylbutoxide and other additives.The advantages of the compositions according to the invention consist therein that the activity-strengthening substances used are fungicidal agents widely used and have an advantageous toxicology. The activity-strengthening agent exerts a synergistic effect together with the pyrethroid-type insecticide.The combinations according to the invention bear an outstanding importance in the protection of stored crops.

摘要翻译： PCT No.PCT / HU90 / 00055 Sec。 371日期1991年5月31日 102（e）日1991年5月31日PCT提交1990年7月30日PCT公布。 出版物WO91 / 01640 日期1991年2月21日。本发明涉及用于对抗植物，动物和卫生以及林业，园艺和仓库害虫的新型组合物。 这些组合物含有拟除虫菊酯型杀虫剂作为杀虫活性成分和至少一种抑制麦角甾醇生物合成作为活性增强剂以及任选的胡椒基丁醚和其它添加剂的杀真菌剂。 根据本发明的组合物的优点在于其中使用的活性增强物质是广泛使用的杀真菌剂并且具有有利的毒理学。 活性增强剂与拟除虫菊酯类杀虫剂一起发挥协同作用。 根据本发明的组合在保存作物方面具有突出的重要性。

公开(公告)号：US5424327A

公开(公告)日：1995-06-13

申请号：US303712

申请日：1994-09-09

申请人： Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

发明人： Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

IPC分类号： A01N43/30 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N47/38 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/06 ,  A01N53/08 ,  A01N53/14

CPC分类号： A01N53/00

摘要： The invention relates to novel combined compositions for combatting plant, animal and sanitarian as well as forestry, horticultural and warehouse pests. These compositions contain a pyrethroid-type insecticide as an insecticidally active ingredient and at least one fungicide inhibiting the ergosterol biosynthesis as activity-strengthening agent as well as optionally piperonylbutoxide and other additives.The advantages of the compositions according to the invention consist therein that the activity-strengthening substances used are fungicidal agents widely used and have an advantageous toxicology. The activity-strengthening agent exerts a synergistic effect together with the pyrethroid-type insecticide.The combinations according to the invention bear an outstanding importance in the protection of stored crops.

摘要翻译： 本发明涉及用于对抗植物，动物和卫生以及林业，园艺和仓库害虫的新型组合组合物。 这些组合物含有拟除虫菊酯型杀虫剂作为杀虫活性成分和至少一种抑制麦角甾醇生物合成作为活性增强剂以及任选的胡椒基丁醚和其它添加剂的杀真菌剂。 根据本发明的组合物的优点在于其中使用的活性增强物质是广泛使用的杀真菌剂并且具有有利的毒理学。 活性增强剂与拟除虫菊酯类杀虫剂一起发挥协同作用。 根据本发明的组合在保护作物方面具有突出的重要性。

公开(公告)号：US5043163A

公开(公告)日：1991-08-27

申请号：US565881

申请日：1990-08-09

申请人： Laszlo Pap ,  Eva Somfai ,  Andras Szego ,  Istvan Szekely ,  Lajos Nagy ,  Gyorgy Hidasi ,  Sandor Zoltan ,  Andrea Toth ,  Bela Bertok ,  Sandor Botar ,  Antal Gajary ,  Agnes Hegedus ,  Aniko Deak

发明人： Laszlo Pap ,  Eva Somfai ,  Andras Szego ,  Istvan Szekely ,  Lajos Nagy ,  Gyorgy Hidasi ,  Sandor Zoltan ,  Andrea Toth ,  Bela Bertok ,  Sandor Botar ,  Antal Gajary ,  Agnes Hegedus ,  Aniko Deak

IPC分类号： A01N57/10 ,  A01N53/00 ,  A01N53/02 ,  A01N53/06 ,  A01N53/08 ,  A01N57/12 ,  A01N57/14 ,  A01N57/16 ,  A01N57/18 ,  A01P7/04

CPC分类号： A01N57/12 ,  A01N57/14 ,  A01N57/16

摘要： The present invention relates to a multi-component pesticidal composition against anthropoda containing as active ingredient pyrethroides and phosphate esters and optionally piperonyl butoxide and excipients comprising as pyrethroid component 0.1 to 40 percent by weight of cypermethrin related to the total weight comprising out of the 8 possible isomers 40 to 100 percent by weight of 1RcisS and/or 1RtransS stereoisomer and as a second component at least one phosphoric acid, thiophosphoric acid or dithiophosphate being toxic on arthropoda at a ratio of 1:1-99 related to the amount of cypermethrin.

公开(公告)号：US5189062A

公开(公告)日：1993-02-23

申请号：US827514

申请日：1992-01-28

申请人： Andras Szego ,  Laszlo Pap ,  Lajos Nagy ,  Eva Somfai ,  Gyorgy Szucsany ,  Istvan Szekely ,  Aniko D. nee Molnar ,  Agnes Hegedus

发明人： Andras Szego ,  Laszlo Pap ,  Lajos Nagy ,  Eva Somfai ,  Gyorgy Szucsany ,  Istvan Szekely ,  Aniko D. nee Molnar ,  Agnes Hegedus

IPC分类号： A01N25/02

CPC分类号： A01N25/02

摘要： ULV plant protecting arthropodicidal formulation comprising alkyl aryl polyglycol ether as further additives in addition to the active ingredient(s) dissolved in the mixture of alphatic hydrocarbons and sunflower oil. The formulation according to the invention has an initial contact angle on the plant surface of >13.degree., after 20 minutes of >6.degree. and it is often 120 minutes still at least 2.degree..

摘要翻译： ULV植物保护节肢动物杀菌制剂包含烷基芳基聚乙二醇醚作为另外的添加剂，除了溶解在脂肪烃和向日葵油的混合物中的活性成分之外。 根据本发明的制剂在> 13°的植物表面上具有初始接触角，20分钟> 6°后，通常为120分钟至少为2℃。

公开(公告)号：US4950682A

公开(公告)日：1990-08-21

申请号：US307395

申请日：1989-02-06

申请人： Laszlo Pap ,  Peter Sarkozi ,  Eva Somfai ,  Andras Szego ,  Istvan Szekely ,  Gyorgy Hidasi ,  Sandor Zoltan ,  Aniko Deak nee Moinar ,  Agnes Hegedus ,  Bela Bertok ,  Sandor Botar ,  Antal Gajary ,  Lajos Nagy

发明人： Laszlo Pap ,  Peter Sarkozi ,  Eva Somfai ,  Andras Szego ,  Istvan Szekely ,  Gyorgy Hidasi ,  Sandor Zoltan ,  Aniko Deak nee Moinar ,  Agnes Hegedus ,  Bela Bertok ,  Sandor Botar ,  Antal Gajary ,  Lajos Nagy

IPC分类号： A01N43/30 ,  A01N53/00 ,  A01N53/04 ,  A01N53/06 ,  A01N53/08 ,  A01P7/02 ,  A01P7/04

CPC分类号： A01N53/00

摘要： The present invention relates to synergistic arthropodicidal composition of several pyrethroidal active ingredients causing no damage to warm-blooded organisms comprising pyrethroides and piperonyl butoxide as active ingredient which comprises as pyrethroidal active ingredient 0.1-20% by weight of 1StransR-alpha-cyano-3-phenoxy-benzyl-3- (2,2-dichlorvinyl)-2,2-dimethyl/cyclopropane-cyrboxylate of the Formula I ##STR1## 0.05-10% by weight of cis-trans-tetramethrin (3,4,5,6-tetrahydrophthalimido-methyl(1RS)-cis-trans-chrysantemate) or trans-tetramethrin of the Formula II ##STR2## and a further pyrethroide, 0.1-40% by weight of piperonyl butoxide of the Formula III ##STR3##

公开(公告)号：US5013754A

公开(公告)日：1991-05-07

申请号：US367546

申请日：1989-06-16

申请人： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Rudolf Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

发明人： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Rudolf Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

IPC分类号： C07C69/747 ,  A01N20060101 ,  A01N37/34 ,  A01N53/00 ,  A01N53/08 ,  A01P7/04 ,  C07B20060101 ,  C07B57/00 ,  C07B61/00 ,  C07B63/04 ,  C07C20060101 ,  C07C67/52 ,  C07C69/743 ,  C07C253/30 ,  C07C253/34 ,  C07C255/00 ,  C07C255/37 ,  C07C255/39

CPC分类号： A01N53/00

摘要： According to the present invention there is provided a synergistic insecticidal composition containing more than one active ingredients and being harmless to environment characterized by comprising in an amount of from 0.001 to 99% by weight a synthetic pyrethroid of the Formula /I/ ##STR1## namely substantially only the 1RtransS and 1StransR entantiomer-pair /Ib/ out from the possible eight isomers--optionally in admixture with an amount of up to 100% by weight of one or more activator/s/ and auxiliary agent/s/, particularly antioxidants, stabilizing agents, wetting agents, emulsifying agents, dispersing agents, antifoam agents, diluents and/or fillers.The enantiomer-pair Ib consisting of the 1RtransS and 1StransR isomers is new and the invention also relates to the said new enantiomer-pair and a process for the preparation thereof.The advantage of the insecticidal composition of the present invention is that it is less toxical towards warm-blooded animals and useful parasites and is therefore much less harmful to the environment.

公开(公告)号：US5273953A

公开(公告)日：1993-12-28

申请号：US663911

申请日：1991-03-07

申请人： Istvan Szekely ,  Lajos Nagy ,  Peter Bohus ,  Andras Szego ,  Laszlo Pap ,  Tamasne Marmarosi

发明人： Istvan Szekely ,  Lajos Nagy ,  Peter Bohus ,  Andras Szego ,  Laszlo Pap ,  Tamasne Marmarosi

IPC分类号： A01N20060101 ,  A01N25/30 ,  A61K9/00 ,  A61K47/14 ,  A01N25/22

CPC分类号： A01N25/30 ,  A61K47/14

摘要： The invention relates to a plant protecting or veterinary or additive composition, containing beside the active ingredient and other usually applied auxiliaries, such as solid and liquid carrier(s), surface active agent(s) and further additive(s), one or more surface active agent(s) of the general formulae (I) ##STR1## or a mixture thereof, wherein R, R.sup.2, R.sup.3 and R.sup.4 are independently from each other hydrogen atom, an organic or inorganic cation or a group of the general formula --(CH.sub.2 --CH.sub.2 --O).sub.n R.sup.1, whereinR.sup.1 is a C.sub.10-20 alkyl group andn is an integer from 4 to 20, with the provisio that from among the substituents R, R.sup.2 and R.sup.3 at least one is a group of the general formula (CH.sub.2 --CH.sub.2 O).sub.n R.sup.1.

摘要翻译： PCT No.PCT / HU90 / 00032 Sec。 371日期1991年3月7日 102（e）1991年3月7日PCT PCT 1990年5月7日PCT公布。 出版物WO90 / 13222 1990年11月15日，本发明涉及植物保护或兽医或添加剂组合物，除了活性成分和其它通常使用的助剂如固体和液体载体，表面活性剂和另外的添加剂 （I）的一种或多种表面活性剂，或其混合物，其中R，R 2，R 3和R 4彼此独立地为氢， 原子，有机或无机阳离子或通式 - （CH 2 -CH 2 -O）n R 1的基团，其中R 1是C 10-20烷基，n是4至20的整数，条件是从 取代基R，R 2和R 3至少一个是通式（CH 2 -CH 2 O）n R 1的基团。

公开(公告)号：US5006545A

公开(公告)日：1991-04-09

申请号：US391780

申请日：1989-08-09

申请人： Peter Sarkozy ,  Laszlo Pap ,  Andras Szego ,  Lajos Nagy ,  Istvan Szekely ,  Katalin Marmarosi ,  Janos Grosch

发明人： Peter Sarkozy ,  Laszlo Pap ,  Andras Szego ,  Lajos Nagy ,  Istvan Szekely ,  Katalin Marmarosi ,  Janos Grosch

IPC分类号： C07D209/49 ,  A61K31/215 ,  A61K31/275 ,  A61K31/34 ,  A61K31/341 ,  A61K31/40 ,  A61K31/403 ,  A61K31/4035 ,  A61K31/415 ,  A61K31/4184 ,  A61K31/425 ,  A61P33/00 ,  C07C69/747 ,  C07D235/32 ,  C07D307/45

CPC分类号： A61K31/34 ,  A61K31/215 ,  A61K31/275 ,  A61K31/40 ,  A61K31/415 ,  A61K31/425

摘要： A veterinary composition is disclosed which is suitable against endoparasites and which contains as active ingredients:(a) alpha-(cyano)-3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane-carboxylic acid-3-phenoxybenzyl ester or any isomeric mixture thereof; and(b) 5(6)-propylthio-2-benzimidazolyl-methylcarbamate, wherein the weight ratio of the two respective compounds is 1:1 to 1.5:1, in combination with a carrier that is inert for veterinary purposes.

公开(公告)号：US4963584A

公开(公告)日：1990-10-16

申请号：US371650

申请日：1989-06-19

申请人： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Ruldof Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

发明人： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Ruldof Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

IPC分类号： C07C69/747 ,  A01N20060101 ,  A01N37/34 ,  A01N53/00 ,  A01N53/08 ,  A01P7/04 ,  C07B20060101 ,  C07B57/00 ,  C07B61/00 ,  C07B63/04 ,  C07C20060101 ,  C07C67/52 ,  C07C69/743 ,  C07C253/30 ,  C07C253/34 ,  C07C255/00 ,  C07C255/37 ,  C07C255/39

CPC分类号： A01N53/00

摘要： According to the present invention there is provided an insecticidal composition containing more than one active ingredients which comprises as active ingredient in an amount of 0.001-99% by weight a synthetic pyrethroid of the general Formula I ##STR1## wherein X stands for chlorine or bromine--namely out of the eight possible isomers at least 95% of a 55:45-25:75 mixture of the enantiomer-pairs Ia:Ib, wherein Ia is 1RcisS+1ScisR and Ib is 1RtransS++1StransR--if desired, in admixture with an activator and/or with an amount of up to 100% of an auxiliary agent, preferably an antioxidant, stabilizer, wetting agent, emulsifying agent, dispersing agent, antifoam agent, diluent, carrier, and/or filler.The advantage of the insecticidal composition of the present invention is that it is less toxical towards warm-blooded animals and useful parasites and is therefore much less harmful to the environment.

公开(公告)号：US5110976A

公开(公告)日：1992-05-05

申请号：US696580

申请日：1991-05-07

申请人： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Rudolf Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

发明人： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Rudolf Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

IPC分类号： C07C69/747 ,  A01N20060101 ,  A01N37/34 ,  A01N53/00 ,  A01N53/08 ,  A01P7/04 ,  C07B20060101 ,  C07B57/00 ,  C07B61/00 ,  C07B63/04 ,  C07C20060101 ,  C07C67/52 ,  C07C69/743 ,  C07C253/30 ,  C07C253/34 ,  C07C255/00 ,  C07C255/37 ,  C07C255/39

CPC分类号： A01N53/00

摘要： A process is disclosed for preparing a synergistic, crystalline product consisting of solely enantiomer pair 1RCisS and 1SCisR and enantiomer pair 1RTransS and 1STransR of cypermethrin in a 3:7 to 5:5 crystalline mixture, which comprises the steps of: (a) epimerizing an oily melt or a saturated solution of enantiomer pair 1RCisS and 1SCisR and enantiomer pair 1RTransS and 1STransR in a ratio other than 3:7 to 5:5, or a mixture of enantiomer pair 1RCisS and 1SCisR, enantiomer pair 1RTransS and 1STransR together with enantiomer pair 1RCisR and 1SCisS and enantiomer pair 1RTransR and 1STransS, said saturated solution including a protic or apolar, aprotic inert organic solvent by treating said oily melt or saturated solution with an organic or inorganic base at a temperature of -15.degree. C. to 30.degree. C. to precipitate crystals consisting solely of the 1RCisS and 1SCisR and the 1RTransS and 1RTransR enantiomer pairs in a 3:7 to 5:5 weight ratio; (b) isolating the precipitated crystals consisting solely of the enantiomer pairs 1RCisS and 1SCisR and 1RTransS and 1STransR at -10.degree. to 30.degree. C., optionally after inoculating the reaction mixture with a seeding crystal consisting of a mixture of the enantiomer pairs 1RCisS and 1SCisR and 1RTransS and 1STransR at a weight ratio of 3:7 to 5:5 before crystallization; and (c) repeating any of the above steps, if necessary.