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    Process for regenerating catalyst for a hydrocarbon conversion zone
    1.
    发明授权
    Process for regenerating catalyst for a hydrocarbon conversion zone 有权
    用于烃转化区再生催化剂的方法

    公开(公告)号：US08231834B2

    公开(公告)日：2012-07-31

    申请号：US12782244

    申请日：2010-05-18

    Applicant: David M. Fecteau ,  Leon Yuan

    Inventor： David M. Fecteau ,  Leon Yuan

    IPC: F27B15/08

    CPC classification number: B01J38/22 ,  B01J23/96 ,  B01J27/32 ,  B01J38/42 ,  C10G2300/70

    Abstract: In one exemplary embodiment, a unit for regenerating a hydrocarbon conversion catalyst for a hydrocarbon conversion zone can generally include passing the hydrocarbon conversion catalyst through, sequentially, a catalyst-disengaging zone having a first atmosphere, an adsorption zone having a second atmosphere, and a regeneration zone including a combustion zone; introducing an inert gas between the first atmosphere and the second atmosphere; and passing a flue gas from the combustion zone to the adsorption zone.

    Abstract translation: 在一个示例性实施方案中，用于再生用于烃转化区的烃转化催化剂的单元通常可以包括使烃转化催化剂依次通过具有第一气氛的催化剂分离区，具有第二气氛的吸附区和 再生区包括燃烧区; 在第一气氛和第二气氛之间引入惰性气体; 并将烟道气从燃烧区传递到吸附区。

    Regeneration method with efficient oxygen utilization
    3.
    发明授权
    Regeneration method with efficient oxygen utilization 有权
    有效利用氧气的再生方法

    公开(公告)号：US07638101B2

    公开(公告)日：2009-12-29

    申请号：US11755940

    申请日：2007-05-31

    Applicant: Leon Yuan ,  James L. Bixby ,  Kyle P. Austin ,  Brian D. Nabozny

    Inventor： Leon Yuan ,  James L. Bixby ,  Kyle P. Austin ,  Brian D. Nabozny

    IPC: G05D23/00 ,  G05D7/00 ,  F27B15/08 ,  B01J8/08 ,  B01J23/90

    CPC classification number: B01J38/12 ,  B01J23/96 ,  B01J38/18 ,  B01J2208/00061 ,  B01J2219/00202 ,  B01J2219/00238 ,  C10G35/04 ,  C10G49/002

    Abstract: This invention relates to regeneration of coked catalyst by combustion so that the catalyst can be reused in a hydrocarbon conversion reaction. The completion of coke burn is generally measured with a combination of temperature or change in oxygen concentration. Dropping outlet temperatures require time to wait for increases in inlet temperature to correspondingly move down the regenerator. Faster response times might be expected from increasing oxygen concentration, but a small increase in concentration can lead to a significant increase in peak burn temperature which negatively impacts catalyst life. Controlled peak burning is difficult over the entire bed by merely controlling inlet and outlet oxygen concentrations. The invention accordingly combines a measured lag time for temperature travel with an inlet temperature ramping step to ensure complete coke combustion with high oxygen efficiency, thus providing a rapid regeneration that permits more time for operation at desired reaction conditions.

    Abstract translation: 本发明涉及通过燃烧再生焦化催化剂，使得催化剂可以在烃转化反应中再利用。 焦炭燃烧的完成通常用温度或氧气浓度变化的组合来测量。 出口温度下降需要时间才能等待入口温度的升高，以便相应地向下移动再生器。 氧浓度增加可以预测响应时间更快，但是浓度的小幅度增加可能导致峰值燃烧温度显着增加，从而对催化剂寿命产生负面影响。 通过仅控制入口和出口氧浓度，在整个床上控制峰值燃烧是困难的。 因此，本发明将温度行程的测量滞后时间与入口温度升高步骤相结合，以确保具有高氧效率的完全焦炭燃烧，从而提供快速再生，其允许在所需反应条件下操作更多的时间。

    PROCESS FOR REFORMING A HYDROCARBON STREAM IN A UNIT HAVING FIXED AND MOVING BED REACTION ZONES
    4.
    发明申请
    PROCESS FOR REFORMING A HYDROCARBON STREAM IN A UNIT HAVING FIXED AND MOVING BED REACTION ZONES 失效
    在具有固定和移动床反应区的单元中改造碳氢化合物流的方法

    公开(公告)号：US20080156695A1

    公开(公告)日：2008-07-03

    申请号：US11851433

    申请日：2007-09-07

    Applicant: Gary A. Dziabis ,  Leon Yuan ,  David J. Fecteau

    Inventor： Gary A. Dziabis ,  Leon Yuan ,  David J. Fecteau

    IPC: C10G35/04

    CPC classification number: C10G59/02 ,  C10G35/04

    Abstract: A process for reforming a hydrocarbon stream in a reforming unit can include passing a gas including a halogen-containing material from a product separation zone through an adsorption zone to remove at least some of the halogen-containing material before the gas enters a first reforming stage having at least one fixed bed reaction zone.

    Abstract translation: 在重整单元中重整烃流的方法可以包括在气体进入第一重整阶段之前使含有含卤物质的气体从产物分离区通过吸附区以去除至少一些含卤物质 具有至少一个固定床反应区。

    Radial flow continuous reaction/regeneration apparatus
    5.
    发明授权
    Radial flow continuous reaction/regeneration apparatus 失效
    径流连续反应/再生装置

    公开(公告)号：US08182772B2

    公开(公告)日：2012-05-22

    申请号：US12790941

    申请日：2010-05-31

    Applicant: Leon Yuan

    Inventor： Leon Yuan

    IPC: B01J8/02 ,  B01J8/04 ,  B01D53/04

    CPC classification number: B01J8/0214 ,  B01D53/0431 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/06 ,  B01J8/0278 ,  B01J2208/00814 ,  B01J2208/00876

    Abstract: This specification discloses a radial flow continuous reaction/regeneration apparatus. Through employing a rotary device to individually and annularly distributing process fluid and regeneration fluid into a stationary segmented reaction/regeneration box and receiving effluents individually and annularly from the same stationary reaction/regeneration box, the mentioned radial flow continuous reaction/regeneration apparatus can be operated continuously and efficiently without the need for shutting down for regeneration. This radial flow continuous reaction/regeneration apparatus is not only used to separate components by adsorption, such as dehumidification, but also is used in chemical processes to carry out catalytic reaction, regenerate catalyst and used as filtration device to trap particles by changing the filler in the stationary reaction/regeneration box.

    Abstract translation: 本说明书公开了径向流动连续反应/再生装置。 通过采用旋转装置将过程流体和再生流体单独地和环形地分配到静止分段的反应/再生箱中并且从相同的固定反应/再生箱单独地和环形地接收流出物，所述径向流动连续反应/再生装置可以被操作 连续而有效地进行，不需要关闭再生。 这种径向流动连续反应/再生装置不仅用于通过除湿等吸附分离组分，而且还用于化学过程中进行催化反应，再生催化剂并用作过滤装置以通过改变填料来捕获颗粒 静止反应/再生箱。

    Multi-catalyst selection for chlorided reforming catalyst
    9.
    发明授权
    Multi-catalyst selection for chlorided reforming catalyst 失效
    氯化重整催化剂的多催化剂选择

    公开(公告)号：US07410565B1

    公开(公告)日：2008-08-12

    申请号：US11015156

    申请日：2004-12-17

    Applicant: Mark P. Lapinski ,  Leon Yuan ,  Mark D. Moser

    Inventor： Mark P. Lapinski ,  Leon Yuan ,  Mark D. Moser

    IPC: C10G35/04

    CPC classification number: C10G35/085

    Abstract: The chloride retention of an alumina catalyst over the course of operation and regeneration can be controlled and stabilized by incorporating a small amount of a component selected from the group including phosphorus, boron, titanium, silicon, and zirconium. Steam treatments have been used to simulate commercial hydrothermal stability and a small amount of the stabilizer component has been discovered which balances chloride retention. Moreover, in a multi-catalyst hydrocarbon conversion process, such as the two-step reforming of naphtha, it has been discovered that proper selection of a catalyst having lower chloride retention in combination with another catalyst having higher chloride retention results in a process with increased yield and/or higher octane gasoline.

    Abstract translation: 通过加入少量选自磷，硼，钛，硅和锆的组分，可以控制和稳定氧化铝催化剂在操作和再生过程中的氯化物保留。 已经使用蒸汽处理来模拟商业水热稳定性，并且已经发现少量的稳定剂组分平衡氯化物保留。 此外，在诸如石脑油两步重整的多催化剂烃转化方法中，已经发现，适当选择具有较低氯化物保留性的催化剂与另外具有较高氯化物保留性的催化剂结合使催化剂具有增加的过程 产率和/或更高辛烷值的汽油。

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