公开(公告)号：US20110226604A1

公开(公告)日：2011-09-22

申请号：US13116507

申请日：2011-05-26

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： C07C7/00 ,  C07C7/04 ,  C07C7/12

CPC分类号： C07C7/08 ,  B01D3/143 ,  C07C7/005 ,  C07C7/12 ,  C07C15/08

摘要： The apparatus includes at least two adsorptive separation zones to separate para-xylene from a feed stream comprising C8 aromatic hydrocarbons and at least one C9 aromatic hydrocarbon component. The first adsorptive separation zone delivers a raffinate stream to a raffinate distillation zone and an extract stream to an extract distillation zone. The raffinate distillation zone delivers a stream to the second adsorptive separation zone and at least one of the extract distillation zone and raffinate distillation zone delivers a recycle stream to the first adsorptive separation zone.

摘要翻译： 该装置包括至少两个吸附分离区，以从包含C8芳族烃和至少一种C9芳族烃组分的进料流中分离对二甲苯。 第一吸附分离区将萃余液流输送到萃余液蒸馏区，并将提取物流输送到萃取蒸馏区。 萃余液蒸馏区将流输送到第二吸附分离区，萃取蒸馏区和萃余液蒸馏区中的至少一个将再循环流输送到第一吸附分离区。

公开(公告)号：US20090324457A1

公开(公告)日：2009-12-31

申请号：US12146975

申请日：2008-06-26

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： B01J19/00

CPC分类号： C07C7/08 ,  B01D3/143 ,  C07C7/005 ,  C07C7/12 ,  C07C15/08

摘要： The apparatus includes at least two adsorptive separation zones to separate para-xylene from a feed stream comprising C8 aromatic hydrocarbons and at least one C9 aromatic hydrocarbon component. The first adsorptive separation zone delivers a raffinate stream to a raffinate distillation zone and an extract stream to an extract distillation zone. The raffinate distillation zone delivers a stream to the second adsorptive separation zone and at least one of the extract distillation zone and raffinate distillation zone delivers a recycle stream to the first adsorptive separation zone.

摘要翻译： 该装置包括至少两个吸附分离区，以从包含C8芳族烃和至少一种C9芳族烃组分的进料流中分离对二甲苯。 第一吸附分离区将萃余液流输送到萃余液蒸馏区，并将提取物流输送到萃取蒸馏区。 萃余液蒸馏区将流输送到第二吸附分离区，萃取蒸馏区和萃余液蒸馏区中的至少一个将再循环流输送到第一吸附分离区。

公开(公告)号：US07972568B2

公开(公告)日：2011-07-05

申请号：US12146975

申请日：2008-06-26

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： B01J8/00

CPC分类号： C07C7/08 ,  B01D3/143 ,  C07C7/005 ,  C07C7/12 ,  C07C15/08

摘要： The apparatus includes at least two adsorptive separation zones to separate para-xylene from a feed stream comprising C8 aromatic hydrocarbons and at least one C9 aromatic hydrocarbon component. The first adsorptive separation zone delivers a raffinate stream to a raffinate distillation zone and an extract stream to an extract distillation zone. The raffinate distillation zone delivers a stream to the second adsorptive separation zone and at least one of the extract distillation zone and raffinate distillation zone delivers a recycle stream to the first adsorptive separation zone.

摘要翻译： 该装置包括至少两个吸附分离区，以从包含C8芳族烃和至少一种C9芳族烃组分的进料流中分离对二甲苯。 第一吸附分离区将萃余液流输送到萃余液蒸馏区，并将提取物流输送到萃取蒸馏区。 萃余液蒸馏区将流输送到第二吸附分离区，萃取蒸馏区和萃余液蒸馏区中的至少一个将再循环流输送到第一吸附分离区。

公开(公告)号：US08198502B2

公开(公告)日：2012-06-12

申请号：US12719410

申请日：2010-03-08

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： C07C7/13

CPC分类号： C07C7/005 ,  C07C7/13 ,  C07C15/08

摘要： The invention is an adsorptive separation process for producing a para-xylene product from a feed stream comprising para-xylene, at least one other C8 aromatic, and a C9 aromatic. An adsorbent comprising X or Y zeolite and a desorbent comprising para-diethylbenzene (p-DEB) are used in an adsorptive separation zone to produce an extract stream comprising para-xylene, p-DEB, and the C9 aromatic and a raffinate stream comprising the at least one other C8 aromatic, the C9 aromatic, and p-DEB. The extract stream is separated in an extract distillation zone to produce a second desorbent stream comprising the C9 aromatic and p-DEB and the raffinate stream is separated in a raffinate distillation zone to produce a third desorbent stream comprising the C9 aromatic and p-DEB. At least a portion of at least one of the second desorbent stream and the third desorbent stream is further separated in a desorbent distillation zone to produce a stream comprising the C9 aromatic.

摘要翻译： 本发明是用于从包含对二甲苯，至少一种其它C 8芳族和C 9芳族的进料流产生对二甲苯产物的吸附分离方法。 包含X或Y沸石的吸附剂和包含对二乙基苯（p-DEB）的解吸剂用于吸附分离区，以产生包含对二甲苯，p-DEB和C9芳族化合物的萃取物料流和含有 至少一种其它C 8芳族，C 9芳族和p-DEB。 萃取物流在提取蒸馏区中分离以产生包含C 9芳族和p-DEB的第二解吸流，并且萃余物流在萃余液蒸馏区中分离以产生包含C 9芳族和p-DEB的第三解吸流。 第二解吸流和第三解吸流中的至少一个的至少一部分在解吸蒸馏区进一步分离以产生包含C 9芳族的物流。

公开(公告)号：US08323581B2

公开(公告)日：2012-12-04

申请号：US13116507

申请日：2011-05-26

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： B01J8/00 ,  C07C7/12

CPC分类号： C07C7/08 ,  B01D3/143 ,  C07C7/005 ,  C07C7/12 ,  C07C15/08

摘要： The apparatus includes at least two adsorptive separation zones to separate para-xylene from a feed stream comprising C8 aromatic hydrocarbons and at least one C9 aromatic hydrocarbon component. The first adsorptive separation zone delivers a raffinate stream to a raffinate distillation zone and an extract stream to an extract distillation zone. The raffinate distillation zone delivers a stream to the second adsorptive separation zone and at least one of the extract distillation zone and raffinate distillation zone delivers a recycle stream to the first adsorptive separation zone.

摘要翻译： 该装置包括至少两个吸附分离区，以从包含C8芳族烃和至少一种C9芳族烃组分的进料流中分离对二甲苯。 第一吸附分离区将萃余液流输送到萃余液蒸馏区，并将提取物流输送到萃取蒸馏区。 萃余液蒸馏区将流输送到第二吸附分离区，萃取蒸馏区和萃余液蒸馏区中的至少一个将再循环流输送到第一吸附分离区。

公开(公告)号：US07838713B2

公开(公告)日：2010-11-23

申请号：US12146901

申请日：2008-06-26

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： C07C7/12

CPC分类号： C07C7/12 ,  C07C15/08

摘要： The process includes at least two adsorptive separation zones to separate para-xylene from a feed stream comprising C8 aromatic hydrocarbons and at least one C9 aromatic hydrocarbon component. An adsorbent comprising X or Y zeolite and a heavy desorbent are used in the first adsorptive separation zone to produce an extract stream comprising para-xylene and a raffinate stream comprising para-xylene depleted C8 aromatic hydrocarbons, the C9 aromatic hydrocarbon, and the desorbent. The raffinate stream is separated in a raffinate distillation zone to produce a stream comprising the first desorbent component and the C9 aromatic hydrocarbon which stream is further separated in a second adsorptive distillation zone to produce a stream comprising the desorbent and a C9 aromatic hydrocarbon stream.

摘要翻译： 该方法包括至少两个吸附分离区，以从包含C8芳族烃和至少一种C9芳族烃组分的进料流中分离对二甲苯。 在第一吸附分离区中使用包含X或Y沸石和重质解吸剂的吸附剂，以产生包含对二甲苯的萃取物料流和包含对二甲苯贫化的C 8芳族烃，C 9芳族烃和解吸剂的萃余物料流。 萃余液流在萃余液蒸馏区中分离以产生包含第一解吸附组分和C 9芳族烃的物流，该物流在第二吸附蒸馏区进一步分离以产生包含解吸剂和C 9芳烃流的物流。

公开(公告)号：US20100249483A1

公开(公告)日：2010-09-30

申请号：US12719410

申请日：2010-03-08

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： C07C7/04

CPC分类号： C07C7/005 ,  C07C7/13 ,  C07C15/08

摘要： The invention is an adsorptive separation process for producing a para-xylene product from a feed stream comprising para-xylene, at least one other C8 aromatic, and a C9 aromatic. An adsorbent comprising X or Y zeolite and a desorbent comprising para-diethylbenzene (p-DEB) are used in an adsorptive separation zone to produce an extract stream comprising para-xylene, p-DEB, and the C9 aromatic and a raffinate stream comprising the at least one other C8 aromatic, the C9 aromatic, and p-DEB. The extract stream is separated in an extract distillation zone to produce a second desorbent stream comprising the C9 aromatic and p-DEB and the raffinate stream is separated in a raffinate distillation zone to produce a third desorbent stream comprising the C9 aromatic and p-DEB. At least a portion of at least one of the second desorbent stream and the third desorbent stream is further separated in a desorbent distillation zone to produce a stream comprising the C9 aromatic.

摘要翻译： 本发明是用于从包含对二甲苯，至少一种其它C 8芳族和C 9芳族的进料流产生对二甲苯产物的吸附分离方法。 包含X或Y沸石的吸附剂和包含对二乙基苯（p-DEB）的解吸剂用于吸附分离区，以产生包含对二甲苯，p-DEB和C9芳族化合物的萃取物料流和含有 至少一种其它C 8芳族，C 9芳族和p-DEB。 萃取物流在提取蒸馏区中分离以产生包含C 9芳族和p-DEB的第二解吸流，并且萃余物流在萃余液蒸馏区中分离以产生包含C 9芳族和p-DEB的第三解吸流。 第二解吸流和第三解吸流中的至少一个的至少一部分在解吸蒸馏区进一步分离以产生包含C 9芳族的物流。

公开(公告)号：US20090326306A1

公开(公告)日：2009-12-31

申请号：US12146901

申请日：2008-06-26

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： C07C7/11

CPC分类号： C07C7/12 ,  C07C15/08

摘要： The process includes at least two adsorptive separation zones to separate para-xylene from a feed stream comprising C8 aromatic hydrocarbons and at least one C9 aromatic hydrocarbon component. An adsorbent comprising X or Y zeolite and a heavy desorbent are used in the first adsorptive separation zone to produce an extract stream comprising para-xylene and a raffinate stream comprising para-xylene depleted C8 aromatic hydrocarbons, the C9 aromatic hydrocarbon, and the desorbent. The raffinate stream is separated in a raffinate distillation zone to produce a stream comprising the first desorbent component and the C9 aromatic hydrocarbon which stream is further separated in a second adsorptive distillation zone to produce a stream comprising the desorbent and a C9 aromatic hydrocarbon stream.

摘要翻译： 该方法包括至少两个吸附分离区，以从包含C8芳族烃和至少一种C9芳族烃组分的进料流中分离对二甲苯。 在第一吸附分离区中使用包含X或Y沸石和重质解吸剂的吸附剂，以产生包含对二甲苯的萃取物料流和包含对二甲苯贫化的C 8芳族烃，C 9芳族烃和解吸剂的萃余物料流。 萃余液流在萃余液蒸馏区中分离以产生包含第一解吸附组分和C 9芳族烃的物流，该物流在第二吸附蒸馏区进一步分离以产生包含解吸剂和C 9芳烃流的物流。

公开(公告)号：US20130116495A1

公开(公告)日：2013-05-09

申请号：US13292713

申请日：2011-11-09

申请人： Stanley J. Frey ,  Lewis H. Pettengill ,  Michael R. Van de Cotte

发明人： Stanley J. Frey ,  Lewis H. Pettengill ,  Michael R. Van de Cotte

IPC分类号： C07C7/12

CPC分类号： C07C7/12 ,  B01D15/1828 ,  Y02P20/123 ,  Y02P20/57 ,  C07C15/08

摘要： The present process comprises a means for energy savings in one or more process pumps by driving the one or more pumps with a variable-speed driving means. The invention is particularly useful in the separation of an adsorbed product from a mixture of components using simulated-moving-bed adsorption associated with a large circulating stream pumped with variable-speed driving means for conservation of energy relative to the known art. The improvement is particularly applicable to a process for the separation of para-xylene from mixed C8 aromatics.

摘要翻译： 本方法包括通过用变速驱动装置驱动一个或多个泵来在一个或多个处理泵中节能的装置。 本发明特别可用于使用与用已知技术节约能源的可变速度驱动装置泵送的大循环流相关联的模拟移动床吸附分离吸附产物与组分混合物。 该改进特别适用于从混合的C8芳族化合物中分离对二甲苯的方法。

公开(公告)号：US20130012746A1

公开(公告)日：2013-01-10

申请号：US13616915

申请日：2012-09-14

申请人： Charles P. Luebke ,  Stanley J. Frey

发明人： Charles P. Luebke ,  Stanley J. Frey

IPC分类号： C10G3/00 ,  C07C1/22

CPC分类号： C10G45/04 ,  C10G3/50 ,  C10G3/60 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： A process has been developed for producing fuel from renewable feedstocks such as plant and animal oils and greases. The process involves treating a first portion of a renewable feedstock by hydrogenating and deoxygenating in a first reaction zone and a second portion of a renewable feedstock by hydrogenating and deoxygenating in a second reaction zone to provide a diesel boiling point range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the first reaction zone to increase the hydrogen solubility of the reaction mixture.

摘要翻译： 已经开发了用于从可再生原料如植物油和动物油和油脂生产燃料的方法。 该方法包括通过在第二反应区中通过氢化和脱氧来在第一反应区和第二部分可再生原料中进行氢化和脱氧处理可再生原料的第一部分以提供柴油沸点范围的燃料烃产物。 如果需要，烃产物可被异构化以改善冷流动性能。 一部分烃产物再循环到第一反应区以提高反应混合物的氢溶解度。