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公开(公告)号:US11952324B2
公开(公告)日:2024-04-09
申请号:US16636017
申请日:2018-08-02
Applicant: M-I L.L.C.
Inventor: Dimitri M. Khramov , Yiyan Chen , Albert Okhrimenko
IPC: C09K8/035 , C07C231/02 , C09K8/36 , G01N30/72 , G01N30/02
CPC classification number: C07C231/02 , C09K8/035 , C09K8/36 , G01N30/72 , G01N2030/025
Abstract: Methods may include quantifying the concentration of residual free amine and/or free carboxylic acid in a product mixture prepared from a reaction of a multireactive species and a fatty reagent; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and combining the product mixture with one or more wellbore fluid components to generate the wellbore fluid. In another aspect, methods may include including reacting the multireactive species and a fatty reactant to generate a product mixture; quantifying the concentration of residual free amine and/or free carboxylic acid in the product mixture; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and collecting the product mixture.
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公开(公告)号:US11028308B2
公开(公告)日:2021-06-08
申请号:US15817865
申请日:2017-11-20
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov , Glynda A. Addicks
Abstract: Wellbore fluids and methods of drilling with the wellbore fluids are provided. One wellbore fluid may include an oleaginous continuous phase, a non-oleaginous discontinuous phase, and a polymer having a polycyclic backbone. One method may include pumping the wellbore fluid into a wellbore through an earthen formation.
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公开(公告)号:US10570325B2
公开(公告)日:2020-02-25
申请号:US15394056
申请日:2016-12-29
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov
IPC: C09K8/36
Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.
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公开(公告)号:US11447680B2
公开(公告)日:2022-09-20
申请号:US15904897
申请日:2018-02-26
Applicant: M-I L.L.C.
Inventor: Dimitri M. Khramov , Reda Karoum , Stephen Cliffe
Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
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公开(公告)号:US11414586B2
公开(公告)日:2022-08-16
申请号:US16776465
申请日:2020-01-29
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov
Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.
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公开(公告)号:US11377579B2
公开(公告)日:2022-07-05
申请号:US16469620
申请日:2017-12-18
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov , Reda Karoum
IPC: C09K8/32
Abstract: Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and an emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the emulsifier is the product of a reaction between an alkyl cyclic anhydride and a polar reactant, wherein the polar reactant is one or more selected from a group containing alkyl amine, alkanolamine, and polyamine. Methods may include drilling a wellbore with an oil-based mud, wherein the oil-based mud is an invert emulsion containing an emulsifier stabilizing the invert emulsion, wherein the emulsifier is the product of a reaction between an alkyl cyclic anhydride and a polar reactant, wherein the polar reactant is one or more selected from the group of alkyl amine, alkanolamine, and polyamine.
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公开(公告)号:US20180142135A1
公开(公告)日:2018-05-24
申请号:US15817865
申请日:2017-11-20
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov , Glynda A. Addicks
Abstract: A wellbore fluid, comprising an oleaginous continuous phase, a non-oleaginous discontinuous phase and a polymer having a polycyclic backbone. A method of drilling comprising pumping the said wellbore fluid into a wellbore through an earthen formation is also described.
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公开(公告)号:US20170190945A1
公开(公告)日:2017-07-06
申请号:US15394056
申请日:2016-12-29
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov
IPC: C09K8/36
Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.
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公开(公告)号:US20210323909A1
公开(公告)日:2021-10-21
申请号:US16636017
申请日:2018-08-02
Applicant: M-I L.L.C.
Inventor: Dimitri M. Khramov , Yiyan Chen , Albert Okhrimenko
IPC: C07C231/02 , G01N30/72 , C09K8/035 , C09K8/36
Abstract: Methods may include quantifying the concentration of residual free amine and/or free carboxylic acid in a product mixture prepared from a reaction of a multireactive species and a fatty reagent; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and combining the product mixture with one or more wellbore fluid components to generate the wellbore fluid. In another aspect, methods may include including reacting the multireactive species and a fatty reactant to generate a product mixture; quantifying the concentration of residual free amine and/or free carboxylic acid in the product mixture; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and collecting the product mixture.
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公开(公告)号:US20200165505A1
公开(公告)日:2020-05-28
申请号:US16776465
申请日:2020-01-29
Applicant: M-I L.L.C.
Inventor: Yiyan Chen , Dimitri M. Khramov
Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.
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