Amidoamine synthesis, methods to track the reaction process

    公开(公告)号:US11952324B2

    公开(公告)日:2024-04-09

    申请号:US16636017

    申请日:2018-08-02

    Applicant: M-I L.L.C.

    CPC classification number: C07C231/02 C09K8/035 C09K8/36 G01N30/72 G01N2030/025

    Abstract: Methods may include quantifying the concentration of residual free amine and/or free carboxylic acid in a product mixture prepared from a reaction of a multireactive species and a fatty reagent; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and combining the product mixture with one or more wellbore fluid components to generate the wellbore fluid. In another aspect, methods may include including reacting the multireactive species and a fatty reactant to generate a product mixture; quantifying the concentration of residual free amine and/or free carboxylic acid in the product mixture; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and collecting the product mixture.

    Branched acid emulsifier compositions and methods of use

    公开(公告)号:US10570325B2

    公开(公告)日:2020-02-25

    申请号:US15394056

    申请日:2016-12-29

    Applicant: M-I L.L.C.

    Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.

    Branched acid emulsifier compositions and methods of use

    公开(公告)号:US11414586B2

    公开(公告)日:2022-08-16

    申请号:US16776465

    申请日:2020-01-29

    Applicant: M-I L.L.C.

    Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.

    Alkyl cyclic anhydride based emulsifiers for oil based mud

    公开(公告)号:US11377579B2

    公开(公告)日:2022-07-05

    申请号:US16469620

    申请日:2017-12-18

    Applicant: M-I L.L.C.

    Abstract: Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and an emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the emulsifier is the product of a reaction between an alkyl cyclic anhydride and a polar reactant, wherein the polar reactant is one or more selected from a group containing alkyl amine, alkanolamine, and polyamine. Methods may include drilling a wellbore with an oil-based mud, wherein the oil-based mud is an invert emulsion containing an emulsifier stabilizing the invert emulsion, wherein the emulsifier is the product of a reaction between an alkyl cyclic anhydride and a polar reactant, wherein the polar reactant is one or more selected from the group of alkyl amine, alkanolamine, and polyamine.

    BRANCHED ACID EMULSIFIER COMPOSITIONS AND METHODS OF USE

    公开(公告)号:US20170190945A1

    公开(公告)日:2017-07-06

    申请号:US15394056

    申请日:2016-12-29

    Applicant: M-I L.L.C.

    CPC classification number: C09K8/36 C09K8/32

    Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.

    Amidoamine Synthesis, Methods to Track The Reaction Process

    公开(公告)号:US20210323909A1

    公开(公告)日:2021-10-21

    申请号:US16636017

    申请日:2018-08-02

    Applicant: M-I L.L.C.

    Abstract: Methods may include quantifying the concentration of residual free amine and/or free carboxylic acid in a product mixture prepared from a reaction of a multireactive species and a fatty reagent; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and combining the product mixture with one or more wellbore fluid components to generate the wellbore fluid. In another aspect, methods may include including reacting the multireactive species and a fatty reactant to generate a product mixture; quantifying the concentration of residual free amine and/or free carboxylic acid in the product mixture; verifying that the concentration for the free amine and/or free acid in the product mixture is within an acceptable threshold for a given application; and collecting the product mixture.

    Branched Acid Emulsifier Compositions and Methods of Use

    公开(公告)号:US20200165505A1

    公开(公告)日:2020-05-28

    申请号:US16776465

    申请日:2020-01-29

    Applicant: M-I L.L.C.

    Abstract: Compositions may contain an oleaginous base fluid, and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches. Methods may include emplacing a wellbore fluid into a wellbore, wherein the wellbore fluid contains an oleaginous base fluid; and a branched amidoamine surfactant prepared from the reaction of an alkylene amine or an oligoalkylene amine and a branched acid having a C4 to C24 primary hydrocarbon chain, and having one or more C1 to C24 branches.

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