公开(公告)号：US06664016B2

公开(公告)日：2003-12-16

申请号：US09900858

申请日：2001-07-10

申请人： Makoto Kanbayashi ,  Takaaki Kotaki ,  Katsumi Kondo ,  Yasuhiro Ichikawa ,  Takaaki Kaya ,  Wakashi Iida ,  Takayuki Itakura

发明人： Makoto Kanbayashi ,  Takaaki Kotaki ,  Katsumi Kondo ,  Yasuhiro Ichikawa ,  Takaaki Kaya ,  Wakashi Iida ,  Takayuki Itakura

IPC分类号： G03G909

CPC分类号： G03G9/091 ,  G03G9/0821 ,  G03G9/092

摘要： A magenta toner having a storage elastic modulus at 80° C., G′80, from 1×106 dN/m2 to 1×108 dN/m2 and a storage elastic modulus at 120° C. to 180° C., G′120-180, from 2×103 dN/m2 to 1×106 dN/m2, and containing a compound represented by Formulas (1) and (2) and a compound represented by Formula (3): wherein RD2 represents H or OCH3, RD4 represents H or CONH2, RD5 represents H, SO2N(C2H5)2, CONHC6H5, CONH2 or CONHC6H4-(p)CONH2, RK2 represents H, OCH3, CH3 or OC2H5, RK4 represents H, OCH3 or Cl, and RK5 represents H, OCH3, Cl or NO2; wherein RD2 represents H or SO3—, RD4 represents H, Cl or CH3, RD5 represents H, Cl, CH3, C2H5, or SO3—, and M represents Ba, Ca, Sr, Mn or Mg; provided that one of RD2 and RD5 is SO3. wherein RD1 and RD2 each represent H or CH3.

摘要翻译： 在80℃下具有储存弹性模量的品红色调色剂，G'80，1×10 6 dN / m 2至1×10 8 dN / m 2和120℃下的储能弹性模量。 至180℃，G'120-180℃，2×10 3 dN / m 2至1×10 6 dN / m 2，并含有由式（1）和（2）表示的化合物和 由式（3）表示的化合物：其中RD2表示H或OCH3，RD4表示H或CONH2，RD5表示H，SO2N（C2H5）2，CONHC6H5，CONH2或CONHC6H4-（p）CONH2，RK2表示H，OCH3，CH3 或OC2H5，RK4表示H，OCH3或Cl，RK5表示H，OCH3，Cl或NO2;其中RD2表示H或SO3-，RD4表示H，Cl或CH3，RD5表示H，C1，CH3，C2H5或SO3 - ，M表示Ba，Ca，Sr，Mn或Mg; 条件是RD2和RD5之一是SO3，其中RD1和RD2各自表示H或CH3。

公开(公告)号：US06751424B2

公开(公告)日：2004-06-15

申请号：US10329384

申请日：2002-12-27

申请人： Nozomu Komatsu ,  Takaaki Kotaki ,  Makoto Kanbayashi ,  Takaaki Kaya ,  Wakashi Iida ,  Nobuyoshi Sugahara ,  Takayuki Itakura ,  Yojiro Hotta

发明人： Nozomu Komatsu ,  Takaaki Kotaki ,  Makoto Kanbayashi ,  Takaaki Kaya ,  Wakashi Iida ,  Nobuyoshi Sugahara ,  Takayuki Itakura ,  Yojiro Hotta

IPC分类号： G03G1520

CPC分类号： G03G9/08795 ,  G03G7/00 ,  G03G9/0819 ,  G03G9/08782 ,  G03G9/08797 ,  G03G13/20 ,  G03G15/2064 ,  G03G15/5029 ,  G03G2215/00805 ,  G03G2215/0081 ,  G03G2215/2045

摘要： An image-forming method for fixing a toner image onto a recording medium, (i) wherein when a high-gloss recording medium (G0>40) is used, an image is formed at a low-speed mode process speed of from 20 mm/sec. to less than 130 mm/sec. and, where the maximum and minimum gloss values of the fixed image (Gmax1 and Gmin1, respectively), satisfy: Gmax1≦G0+40 and Gmin1≧G0−25; and (ii) wherein when a low-gloss recording medium (0≦G0≦40) is used, an image is formed at a high-speed mode process speed of from 130 mm/sec. to 600 mm/sec. and, where values of the fixed image (Gmax2 and Gmin2, respectively), satisfy: Gmax2≦G0+20 and Gmin2≧G0−15.

摘要翻译： 一种用于将调色剂图像定影到记录介质上的图像形成方法，（i）其中当使用高光泽记录介质（G0> 40）时，以20mm的低速模式处理速度形成图像 /秒。 小于130mm / sec。 并且其中固定图像（Gmax1和Gmin1分别）的最大和最小光泽值满足：Gmax1 <= G0 + 40和Gmin1> = G0-25; 和（ii）其中当使用低光泽记录介质（0 <= G0 <= 40）时，以130mm / sec的高速模式处理速度形成图像。 至600mm / sec。 并且其中固定图像（分别为Gmax2和Gmin2）的值满足：Gmax2 <= G0 + 20和Gmin2> = G0-15。

公开(公告)号：US06537714B2

公开(公告)日：2003-03-25

申请号：US09899025

申请日：2001-07-06

申请人： Takaaki Kaya ,  Takaaki Kotaki ,  Makoto Kanbayashi ,  Yushi Mikuriya ,  Katsumi Kondo ,  Wakashi Iida

发明人： Takaaki Kaya ,  Takaaki Kotaki ,  Makoto Kanbayashi ,  Yushi Mikuriya ,  Katsumi Kondo ,  Wakashi Iida

IPC分类号： G03G1301

CPC分类号： G03G13/016

摘要： In a two-component development system containing a toner and a carrier, an a-Si photosensitive member having a diameter of from 20 mm to 80 mm is used, the photosensitive member is electrostatically charged to have a surface potential of from 300 to 450 V (absolute value), and yellow, magenta, cyan and black toners are used each of which have a weight-average particle diameter of from 4.0 &mgr;m to 10.0 &mgr;m, and, under a condition that the carrier of the two-component developer has a 50% average particle diameter of from 10 &mgr;m to 80 &mgr;m and as image density (D0.5) measured usually after the toner is fixed once when the quantity of unfixed toner on a transfer medium, M/S, is 0.5 mg/cm2, have a coloring power of from 1.0 to 1.9, and in which the difference between a maximum value and a minimum value of D0.5 of yellow, magenta, cyan and black colors is form 0 to 0.5. This makes it possible to obtain high-quality images in a high image density and a superior color reproduction.

公开(公告)号：US07147980B2

公开(公告)日：2006-12-12

申请号：US10753490

申请日：2004-01-09

申请人： Takayuki Itakura ,  Takaaki Kotaki ,  Yasuhiro Ichikawa ,  Takaaki Kaya ,  Wakashi Iida ,  Hiroyuki Fujikawa ,  Kazuhiko Hayami ,  Nobuyoshi Sugahara ,  Yojiro Hotta

发明人： Takayuki Itakura ,  Takaaki Kotaki ,  Yasuhiro Ichikawa ,  Takaaki Kaya ,  Wakashi Iida ,  Hiroyuki Fujikawa ,  Kazuhiko Hayami ,  Nobuyoshi Sugahara ,  Yojiro Hotta

IPC分类号： G03G9/087

CPC分类号： G03G9/08742 ,  G03G9/08702 ,  G03G9/0874 ,  G03G9/08755 ,  G03G9/08788

摘要： A toner having toner particles each comprising at least a binder resin, a wax, and a colorant is used in an image forming apparatus which has a fixing means comprising a belt-shaped heating member and a pressurizing member. The binder resin contains a resin formed by a reaction between an epoxy group of a vinyl resin (A) having the epoxy group and a carboxyl group of a resin (B) having at least a polyester unit and the carboxyl group. The toner has a storage elastic modulus at a temperature of 80° C. (G′ 80) in the range of 1×105 to 1×108 Pa and has a storage elastic modulus at a temperature of 160° C. (G′ 160) in the range of 1×101 to 1×104 Pa.

摘要翻译： 在具有包括带状加热构件和加压构件的固定装置的图像形成装置中使用具有至少粘合剂树脂，蜡和着色剂的调色剂颗粒的调色剂。 粘合剂树脂包含由具有环氧基的乙烯基树脂（A）的环氧基和至少具有聚酯单元的树脂（B）的羧基与羧基之间的反应形成的树脂。 调色剂在温度为80℃（G'80）的范围内具有在1×10 5至1×10 8 Pa的范围内的储能弹性模量，并且具有储能弹性模量 在160℃的温度下（G'160）在1×10 -1至1×10 4 Pa的范围内。

公开(公告)号：US5670288A

公开(公告)日：1997-09-23

申请号：US599845

申请日：1996-02-12

申请人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

发明人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

IPC分类号： G03G9/09 ,  G03G9/097 ,  G03G9/10 ,  G03G9/107 ,  G03G13/09

CPC分类号： G03G9/10 ,  G03G9/0918 ,  G03G9/09708 ,  G03G9/09716 ,  G03G9/107

摘要： A carrier for electrophotography has carrier particles. The carrier has a 50% average particle diameter (D.sub.50) of from 15 .mu.m to 45 .mu.m and contains from 1% to 20% of carrier particles with a size smaller than 22 .mu.m, not more than 3% of carrier particles with a size smaller than 16 .mu.m, from 2% to 15% of carrier particles with a size of 62 .mu.m or larger, and not more than 2% of carrier particles with a size of 88 .mu.m or larger. The carrier has a specific surface area S.sub.1 as measured by an air-permeability method and a specific surface area S.sub.2 as calculated by the following expression: S.sub.2 =(6/.rho..multidot.D.sub.50).times.10.sup.4 wherein .rho. is a specific gravity of carrier; satisfying the following condition: 1.2 .ltoreq.S.sub.1 /S.sub.2 .ltoreq.2.0.

摘要翻译： 电子照相用载体具有载体颗粒。 载体具有15μm至45μm的50％平均粒径（D50），并且含有1％至20％的尺寸小于22μm的载体颗粒，不超过载体颗粒的3％ 尺寸小于16μm，尺寸为62μm或更大的载体颗粒的2％至15％，以及不大于2％的尺寸为88μm或更大的载体颗粒。 载体具有通过透气度测定的比表面积S1和通过下式计算的比表面积S2：S2 =（6 / rho×D50）×104其中rho是载体的比重; 满足以下条件：1.2

公开(公告)号：US5512402A

公开(公告)日：1996-04-30

申请号：US246146

申请日：1994-05-19

申请人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

发明人： Kenji Okado ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Tsuyoshi Takiguchi ,  Yasuhiro Ichikawa ,  Wakashi Iida

IPC分类号： G03G9/09 ,  G03G9/097 ,  G03G9/10 ,  G03G9/107 ,  G03G9/08

CPC分类号： G03G9/10 ,  G03G9/0918 ,  G03G9/09708 ,  G03G9/09716 ,  G03G9/107

摘要： A carrier for electrophotography has carrier particles. The carrier has a 50% average particle diameter (D.sub.50) of from 15 .mu.m to 45 .mu.m and contains from 1% to 20% of carrier particles with a size smaller than 22 .mu.m, not more than 3% of carrier particles with a size smaller than 16 .mu.m, from 2% to 15% of carrier particles with a size of 62 .mu.m or larger, and not more than 2% of carrier particles with a size of 88 .mu.m or larger. The carrier has a specific surface area S.sub.1 as measured by an air-permeability method and a specific surface area S.sub.2 as calculated by the following expression:S.sub.2 =(6/.rho..D.sub.50).times.10.sup.4wherein .rho. is a specific gravity of carrier; satisfying the following condition:1.2.ltoreq.S.sub.1 /S.sub.2 .ltoreq.2.0.

摘要翻译： 电子照相用载体具有载体颗粒。 载体具有15μm至45μm的50％平均粒径（D50），并且含有1％至20％的尺寸小于22μm的载体颗粒，不超过载体颗粒的3％ 尺寸小于16μm，尺寸为62μm或更大的载体颗粒的2％至15％，以及不大于2％的尺寸为88μm或更大的载体颗粒。 载体具有通过透气度法测定的比表面积S1和通过下式计算的比表面积S2：S2 =（6 / rho.D50）×104其中rho是载体的比重; 满足以下条件：1.2

公开(公告)号：US5912099A

公开(公告)日：1999-06-15

申请号：US904476

申请日：1997-08-04

申请人： Makoto Kanbayashi ,  Masaaki Taya ,  Ryoichi Fujita ,  Wakashi Iida ,  Tetsuya Ida

发明人： Makoto Kanbayashi ,  Masaaki Taya ,  Ryoichi Fujita ,  Wakashi Iida ,  Tetsuya Ida

IPC分类号： G03G9/08 ,  G03G9/09

CPC分类号： G03G9/092 ,  G03G9/081

摘要： A magenta toner for developing electrostatic images is formed of a binder resin, and a quinacridone pigment providing an X-ray diffraction spectrum showing two peaks in a Bragg angle (2.theta.) region of 5-10 deg. The magenta toner has an improved light fastness, may have a desired hue comparable to a printing process ink and is suitably used for electrophotographic full-color image formation. The magenta toner may preferably be formed through a process including a first kneading step starting from wet blending of a binder resin and two paste pigments including quinacridone and 2,9-dimethylquinacridone, respectively, under mild conditions not causing crystal transformation to form a master batch and a second kneading step of diluting the master batch together with other additive.

摘要翻译： 用于静电图像显影的品红色调色剂由粘合剂树脂形成，并且提供在5-10度的布拉格角（2θ）区域中显示两个峰的X射线衍射光谱的喹吖啶酮颜料。 洋红色调色剂具有改善的耐光性，可以具有与印刷工艺油墨相当的期望色调，并且适用于电子照相全色图像形成。 品红色调色剂可以优选通过包括第一捏合步骤的方法形成，所述方法包括在不引起晶体转变以形成母料的温和条件下分别湿粘合粘合剂树脂和包括喹吖啶酮和2,9-二甲基喹吖啶酮的两种糊状颜料 以及将母料与其他添加剂一起稀释的第二捏合步骤。

公开(公告)号：US5700617A

公开(公告)日：1997-12-23

申请号：US727219

申请日：1996-10-08

申请人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Masaaki Taya ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Wakashi Iida ,  Tetsuya Ida

发明人： Tsuyoshi Takiguchi ,  Kenji Okado ,  Masaaki Taya ,  Ryoichi Fujita ,  Makoto Kanbayashi ,  Wakashi Iida ,  Tetsuya Ida

IPC分类号： G03G9/097 ,  H01B1/00 ,  H01B1/06

CPC分类号： G03G9/09733 ,  G03G9/09708 ,  G03G9/09783

摘要： A toner for developing an electrostatic image is formed from toner particles containing a binder resin, a colorant, and a charge-controlling agent. The charge-controlling agent comprises an aromatic oxycarboxylic acid, a metal compound of the aromatic oxycarboxylic acid, and an inorganic compound formed from an inorganic anion and an inorganic cation. The aromatic oxycarboxylic acid, the metal compound of the aromatic carboxylic acid and the inorganic anion are contained in proportions of A (wt. %), B (wt. %) and C (ppm), respectively, satisfying the following conditions: 1/99.ltoreq.A/B.ltoreq.20/80, and 10.sup.2 .ltoreq.C. Because of the inclusion of an inorganic compound providing a sufficient amount of inorganic anion, the charge-controlling agent shows a stable charge-controlling characteristic, and the resultant toner exhibits a stable developing performance and transferability in continuous image formation in various environmental conditions.

摘要翻译： 用于显影静电图像的调色剂由含有粘合剂树脂，着色剂和电荷控制剂的调色剂颗粒形成。 电荷控制剂包括芳族羟基羧酸，芳族羟基羧酸的金属化合物和由无机阴离子和无机阳离子形成的无机化合物。 芳族羟基羧酸，芳族羧酸的金属化合物和无机阴离子分别以A（重量％），B（重量％）和C（ppm）的比例包含，满足以下条件：1 / 99 。 由于含有提供足够量的无机阴离子的无机化合物，电荷控制剂显示出稳定的电荷控制特性，并且所得调色剂在各种环境条件下表现出稳定的连续成像的显影性能和转印性。

公开(公告)号：US6022659A

公开(公告)日：2000-02-08

申请号：US31892

申请日：1998-02-27

申请人： Makoto Kanbayashi ,  Masaaki Taya ,  Wakashi Iida ,  Tetsuya Ida

发明人： Makoto Kanbayashi ,  Masaaki Taya ,  Wakashi Iida ,  Tetsuya Ida

IPC分类号： G03G9/08 ,  G03G9/087 ,  G03G9/09

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/09 ,  G03G9/091

摘要： A yellow toner for developing electrostatic images is formed of yellow toner particles containing a binder resin and a yellow colorant. The yellow toner has a storage modulus G'.sub.180 at 180.degree. C. and a minimum storage modulus G'.sub.min(120-170) in a temperature range of 120-170.degree. C. giving a ratio [G'.sub.180 /G'.sub.min(120-170) ] of 2.0-8.0. The binder resin comprises a polyester resin having a glass transition temperature of 50-65.degree. C. and an acid value of 2.0-25.0 mgKOH/g. The yellow toner is a compound represented by Formula (1) below:Formula (1): ##STR1## The primary particles of the yellow colorant exhibit a length/breadth ratio of at most 1.5. The yellow colorant is dispersed in the toner particles as independent particles (including primary particles and secondary particles) providing a number-average particle size of 0.1-0.7 .mu.m. The yellow toner is provided with improved fixability and anti-offset property as well as good color toner performances.

摘要翻译： 用于显影静电图像的黄色调色剂由含有粘合剂树脂和黄色着色剂的黄色调色剂颗粒形成。 黄色调色剂在180℃的储能模量G'180和120-170℃的温度范围内具有最小储能模量G'min（120-170），得到[G'180 / G'min （120-170）]为2.0-8.0。 粘合剂树脂包括玻璃化转变温度为50-65℃，酸值为2.0-25.0mgKOH / g的聚酯树脂。 黄色调色剂是由下式（1）表示的化合物：式（1）：黄色着色剂的一次颗粒的长度/宽度比至多为1.5。 作为提供数均粒径为0.1-0.7μm的独立颗粒（包括一次颗粒和二次颗粒），黄色着色剂分散在调色剂颗粒中。 黄色调色剂具有改进的定影性和抗偏移性以及良好的彩色调色剂性能。

公开(公告)号：US5994018A

公开(公告)日：1999-11-30

申请号：US299633

申请日：1999-04-27

申请人： Wakashi Iida ,  Masaaki Taya ,  Makoto Kanbayashi ,  Tetsuya Ida ,  Junko Inaba

发明人： Wakashi Iida ,  Masaaki Taya ,  Makoto Kanbayashi ,  Tetsuya Ida ,  Junko Inaba

IPC分类号： G03G9/087 ,  G03G9/08 ,  G03G9/097

CPC分类号： G03G9/09708

摘要： A toner contains toner particles and fine alumina particles. The toner particles include a binding resin and a colorant. The fine alumina particles contain 200 to 700 .mu.g of zirconium compound per gram of alumina. The toner may be used as a one-component developer or as a two-component developer with a carrier.

摘要翻译： 调色剂含有调色剂颗粒和氧化铝微粒。 调色剂颗粒包括粘合树脂和着色剂。 细氧化铝颗粒每克氧化铝含有200-700克锆化合物。 调色剂可以用作单组分显影剂或作为具有载体的双组分显影剂。