公开(公告)号：US5508421A

公开(公告)日：1996-04-16

申请号：US279191

申请日：1994-07-22

申请人： Makoto Suzuki ,  Hisashi Mikoshiba ,  Seiiti Kubodera ,  Osamu Takahashi ,  Yasuhiro Shimada ,  Koushin Matsuoka ,  Shigeru Yamazaki ,  Katsuyoshi Yamakawa ,  Kozo Sato

发明人： Makoto Suzuki ,  Hisashi Mikoshiba ,  Seiiti Kubodera ,  Osamu Takahashi ,  Yasuhiro Shimada ,  Koushin Matsuoka ,  Shigeru Yamazaki ,  Katsuyoshi Yamakawa ,  Kozo Sato

IPC分类号： C07D487/04 ,  C09B55/00 ,  G03C7/38 ,  G03C7/36

CPC分类号： C07D487/04 ,  C09B55/009 ,  G03C7/383

摘要： A pyrrolotriazole azomethine dye represented by formula (I), (II) or (IV) is disclosed: ##STR1## Also, a heat transfer dye providing material is disclosed, in which the material includes a support having thereon a dye providing layer containing a heat migrating dye, with the dye providing layer containing at least one pyrrolotriazole azomethine dye represented by any of the above formulae (I), (II) and (IV).

摘要翻译： （I），（II）或（IV）表示的吡咯并三氮唑代甲基染料被公开：公开了一种传热染料提供材料， 其中所述材料包括其上具有含有热迁移染料的染料提供层的载体，所述染料提供层含有至少一种由上述式（I），（II）和（IV）中的任何一种表示的吡咯并三唑甲脒染料。

公开(公告)号：US5362882A

公开(公告)日：1994-11-08

申请号：US894573

申请日：1992-06-05

申请人： Makoto Suzuki ,  Yasuhiro Shimada ,  Koushin Matsuoka ,  Shigeru Yamazaki ,  Katsuyoshi Yamakawa ,  Kozo Sato

发明人： Makoto Suzuki ,  Yasuhiro Shimada ,  Koushin Matsuoka ,  Shigeru Yamazaki ,  Katsuyoshi Yamakawa ,  Kozo Sato

IPC分类号： C07D487/04 ,  C09B55/00 ,  G03C7/38 ,  C07D487/14 ,  G03C7/36

CPC分类号： C07D487/04 ,  C09B55/009 ,  G03C7/383

摘要： A novel pyrrolotriazole derivative is disclosed, represented by any one of formulae (I), (II), (III), (IV), or (V): ##STR1## A heat transfer dye providing material is also disclosed, comprising a support having thereon a dye providing layer containing a heat migrating dye, said dye providing layer containing at least one pyrrolotriazole azomethine dye represented by any one of formulae (I), (II), (III), or (IV).

摘要翻译： 公开了由式（I），（II），（III），（IV）或（V）中的任一个表示的新颖的吡咯并三唑衍生物：其中（IMA） （V）还公开了一种传热染料提供材料，其包括其上具有含有热迁移染料的染料提供层的载体，所述染料提供层含有至少一种吡咯并三唑甲脒染料 由式（I），（II），（III）或（IV）中的任一个表示。

公开(公告)号：US5344933A

公开(公告)日：1994-09-06

申请号：US942835

申请日：1992-09-10

申请人： Hisashi Mikoshiba ,  Katsuyoshi Yamakawa ,  Kozo Sato ,  Koushin Matsuoka

发明人： Hisashi Mikoshiba ,  Katsuyoshi Yamakawa ,  Kozo Sato ,  Koushin Matsuoka

IPC分类号： B41M5/39 ,  C07D487/04 ,  C09B55/00 ,  D06P5/13 ,  G03C1/83 ,  C07D471/04 ,  B41M5/00 ,  B41M5/30 ,  G03C7/30

CPC分类号： B41M5/39 ,  C09B55/009 ,  G03C1/83

摘要： An azomethine dye is disclosed, represented by the general formula (I), (II) or (III): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently represents a hydrogen atom or nonmetallic atom group; X represents --OH or --NR.sup.5 R.sup.6 ; R.sup.5 and R.sup.6 each independently represents a hydrogen atom, alkyl group, aryl group or heterocyclic group; R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 each independently represents a hydrogen atom or nonmetallic atom group; and R.sup.1 and R.sup.2, and/or R.sup.2 and R.sup.5, and/or R.sup.5 and R.sup.6, and/or R.sup.6 and R.sup.3, and/or R.sup.3 and R.sup.4, and/or R.sup.7 and R.sup.8, and/or R.sup.9 and R.sup.10, and/or R.sup.11 and R.sup.12, and/or R.sup.12 and R.sup.13 may be connected to each other to form a cyclic structure. A heat transfer dye providing material is also disclosed, comprising a support having thereon a dye providing layer containing a heat migrating dye, the dye providing layer comprising at least one azomethine dye represented by the general formula (I), (II) or (III).

摘要翻译： 公开了由通式（I），（II）或（III）表示的偶氮甲碱染料：其中R1，R2，R3和R4各自独立地表示： 独立地表示氢原子或非金属原子团; X表示-OH或-NR 5 R 6; R5和R6各自独立地表示氢原子，烷基，芳基或杂环基; R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地表示氢原子或非金属原子团; 和R 1和R 2和/或R 2和R 5，和/或R 5和R 6，和/或R 6和R 3，和/或R 3和R 4，和/或R 7和R 8，和/或R 9和R 10，和/或 R11和R12，和/或R12和R13可以彼此连接以形成环状结构。 还公开了一种传热染料提供材料，其包括其上具有含有热迁移染料的染料提供层的载体，所述染料提供层包含至少一种由通式（I），（II）或（III）表示的偶氮甲碱染料 ）。

公开(公告)号：US5256526A

公开(公告)日：1993-10-26

申请号：US800082

申请日：1991-11-29

申请人： Makoto Suzuki ,  Tadahisa Sato ,  Kozo Sato ,  Yoshio Ishii ,  Hideaki Naruse ,  Yasuhiro Shimada

发明人： Makoto Suzuki ,  Tadahisa Sato ,  Kozo Sato ,  Yoshio Ishii ,  Hideaki Naruse ,  Yasuhiro Shimada

IPC分类号： G03C7/305 ,  G03C7/38 ,  G03C7/407

CPC分类号： G03C7/30529 ,  G03C7/383

摘要： A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing at least one 1H-pyrrolo[1,2-b][1,2,4]triazole cyan coupler represented by the following general formula (I) or (II): ##STR1## wherein R.sub.1 and R.sub.2 each represents an electron withdrawing group having a Hammett's substituent constant .sigma.p value of 0.20 or more; R.sub.1 and R.sub.2 may be bonded to form a ring; the sum of a Hammett's substituent constant .sigma.p value of R.sub.1 and R.sub.2 is 0.65 or more; R.sub.3 represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a substituent capable of being released upon coupling with an oxidation product of an aromatic primary amine color developing agent; said coupler may be in a form of a bis-compound or a polymer formed at R.sub.1, R.sub.2, R.sub.3 or X; and a cyan image forming method comprising imagewise exposing a silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and subjecting the exposed photographic material to color development with an aromatic primary amine color dveloping agent at the presence of the above-described 1H-pyrrolo[1,2-b][1,2,4]triazole cyan coupler.

公开(公告)号：US5192737A

公开(公告)日：1993-03-09

申请号：US787611

申请日：1991-11-04

申请人： Seiiti Kubodera ,  Kozo Sato

发明人： Seiiti Kubodera ,  Kozo Sato

IPC分类号： B41M5/385 ,  B41M5/39 ,  B41M5/392 ,  B41M5/46

CPC分类号： B41M5/465 ,  B41M5/3854 ,  B41M5/39 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/146

摘要： There is disclosed a thermal transfer dye-providing material capable of providing a sharp image having a high density. The dye-providing material includes a support having provided thereon a layer containing a thermally migrating dye, wherein at least one of the dye-containing layer and a layer adjacent thereto contains an infrared-absorbing dye represented by Formula (I), (II) or (III): ##STR1##

摘要翻译： 公开了能够提供高密度的清晰图像的热转印染料提供材料。 染料提供材料包括其上设置有含有热迁移染料的层的载体，其中含染料层和与其相邻的层中的至少一个含有由式（I），（II）表示的红外线吸收染料， 式（II）化合物（III）：式（I）

公开(公告)号：US4910187A

公开(公告)日：1990-03-20

申请号：US239580

申请日：1988-09-01

申请人： Kozo Sato ,  Takeshi Nakamine ,  Seiiti Kubodera

发明人： Kozo Sato ,  Takeshi Nakamine ,  Seiiti Kubodera

IPC分类号： B41M5/385 ,  B41M5/025 ,  B41M5/035 ,  B41M5/26 ,  B41M5/30 ,  B41M5/388 ,  B41M5/39 ,  C09B55/00 ,  C09B57/00 ,  C09D5/26 ,  D06P5/00

CPC分类号： B41M5/39 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/265

摘要： A heat-sensitive transfer material comprising a support having provided thereon a heat-sensitive transfer layer, wherein said layer contains a dye represented by formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aryl group, aryloxy group, an aralkyl group, a cyano group, an acylamino group, a sulfonylamino group, a ureido group, an alkylthio group, an arylthio group, an alkoxycarbonyl group, carbamoyl group, a sulfamoyl group, a sulfonyl group, an acyl group, or an amino group;R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group;provided that either R.sub.3 and R.sub.4, R.sub.2 and R.sub.3, or R.sub.2 and R.sub.4, may combine to each other and the adjacent atoms to form a ring;n represents an integer of from 0 to 3;X, Y and Z, which may be the same or different,each represents a ##STR2## group or a nitrogen atom, wherein R.sub.5 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, an alkoxy group, an aryloxy group, or an amino group;when X and Y or X and Z each represents ##STR3## they may be combine with each other to form a saturated or unsaturated carbon ring; andprovided that the aforesaid group comprising R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each may be substituted.

摘要翻译： 一种热敏转印材料，其包含在其上设置有热敏转印层的载体，其中所述层含有由式（I）表示的染料：其中R1和R2可以相同或不同 各自表示氢原子，卤素原子，烷基，环烷基，烷氧基，芳基，芳氧基，芳烷基，氰基，酰氨基，磺酰基氨基，脲基， 烷硫基，芳硫基，烷氧基羰基，氨基甲酰基，氨磺酰基，磺酰基，酰基或氨基; R 3和R 4可以相同或不同，各自表示烷基，环烷基，芳烷基或芳基; 条件是R 3和R 4，R 2和R 3或R 2和R 4可以彼此结合并且相邻原子形成环; n表示0〜3的整数， X，Y和Z可以相同或不同，分别表示基或氮原子，其中R5表示氢原子，烷基，环烷基，芳烷基，芳基， 烷氧基，芳氧基或氨基; 当X和Y或X和Z各自表示“它们”时，它们可以彼此结合形成饱和或不饱和的碳环; 并且前提是包括R1，R2，R3，R4和R5各自可以被取代。

公开(公告)号：US5401624A

公开(公告)日：1995-03-28

申请号：US145630

申请日：1993-11-04

申请人： Kozo Sato ,  Yoshio Ishii ,  Katsuyoshi Yamakawa

发明人： Kozo Sato ,  Yoshio Ishii ,  Katsuyoshi Yamakawa

IPC分类号： C07D487/04 ,  G03C7/38

CPC分类号： C07D487/04 ,  G03C7/3825 ,  G03C7/383

摘要： A silver halide color photosensitive material which forms a cyan dye that has superior heat resistance and that will not readily fade in a reducing atmosphere. The silver halide color photosensitive material contains in at least one layer on a support at least one coupler represented by formula (I): ##STR1## wherein R.sup.1 represents hydrogen atom or a substituent; R.sup.2 represents a substituent; X represents hydrogen atom or a group releasable on a coupling reaction with an oxidation product of a color developing agent; Z.sup.1 represents a nonmetallic atom group necessary for forming a nitrogen-containing, six-membered, heterocyclic ring which has at least one dissociative group: Z.sup.1 cannot be --C(.dbd.O)--N(R)--C(.dbd.O)--NH--; and R represents a substituent.Also disclosed is a novel dye forming coupler which exhibits a high coupling activity and which gives a dye having a large molar extinction coefficient and superior stability, the coupler being represented by the following formula (XX) or (XXI). Also disclosed is a silver halide color photosensitive material which contains at least one of the dye forming couplers of formulae (XX) and (XXI) and which provides sharp dye images with high fastness properties. ##STR2## wherein EWG represents an electron withdrawing group having a Hammett's .sigma..sub.p value of not less than 0.3; R.sub.1 and R.sub.2 each represent a substituent; and X represents hydrogen atom or a group releasable on a coupling reaction with an oxidation product of an aromatic primary amine developing agent.

摘要翻译： 一种卤化银色感光材料，其形成具有优异耐热性且不易在还原气氛中褪色的青色染料。 卤化银色感光材料在载体上至少一层中含有至少一个由式（I）表示的成色剂：汤姆或取代基; R2表示取代基; X表示氢原子或可与显色剂的氧化产物偶联反应脱离的基团; Z1表示形成具有至少一个解离基团的含氮六元杂环所必需的非金属原子团：Z1不能为-C（= O）-N（R）-C（= O）-NH - ; R表示取代基。 还公开了一种新型的染料形成成色剂，其显示出高的偶联活性，并且得到具有大的摩尔吸光系数和优异的稳定性的染料，所述成色剂由下式（XX）或（XXI）表示。 还公开了含有式（XX）和（XXI）的染料形成成色剂中的至少一种的卤化银色感光材料，并提供具有高坚牢度性质的清晰的染料图像。 （XXI）（XXI）其中EWG表示哈米特σp值不小于0.3的吸电子基团; R1和R2各自表示取代基; X表示氢原子或可与芳族伯胺显影剂的氧化产物偶联反应脱离的基团。

公开(公告)号：US5364941A

公开(公告)日：1994-11-15

申请号：US70245

申请日：1993-06-02

申请人： Katsuyoshi Yamakawa ,  Kozo Sato ,  Takashi Suginome

发明人： Katsuyoshi Yamakawa ,  Kozo Sato ,  Takashi Suginome

IPC分类号： C07D495/04 ,  C07D471/04

CPC分类号： C07D495/04

摘要： An intermediate, 5-Acyl-4,5,6,7-tetrahydrothieno [3,2-c ]pyridine- 2-carboxylic acid derivative of the following general formula (I): ##STR1## wherein R.sup.1 represents an acyl group and R.sup.2 represents a hydrogen atom or an alkyl group is useful for synthesizing ticlopidine hydrochloride from an inexpensive, easily available compound in short steps.

摘要翻译： 具有下列通式（I）的中间体5-酰基-4,5,6,7-四氢噻吩并[3,2-c]吡啶-2-甲酸衍生物：其中R 1表示酰基 基团，R 2表示氢原子或烷基可用于从廉价的易于获得的化合物以短步骤合成噻氯匹定盐酸盐。

公开(公告)号：US5296603A

公开(公告)日：1994-03-22

申请号：US070685

申请日：1993-06-02

申请人： Katsuyoshi Yamakawa ,  Kozo Sato ,  Takashi Suginome

发明人： Katsuyoshi Yamakawa ,  Kozo Sato ,  Takashi Suginome

IPC分类号： C07D495/04 ,  C07D333/50

CPC分类号： C07D495/04

摘要： Intermediates of the following formulae (I) and (II): ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group ##STR2## wherein R.sup.1 represents a hydrogen atom or an alkyl group, and R.sup.2 represents a hydrogen atom, an alkylcarbonyl group, arylcarbonyl group, alkylsulfonyl group, arylsulfonyl group, alkoxycarbonyl group or aryloxycarbonyl groupand acid salt thereof are useful for synthesizing ticlopidine hydrochloride from an inexpensive and easily available compound in short steps.

摘要翻译： 下列通式（I）和（II）的中间体：（*化学结构*）（I）其中R1表示氢原子或烷基（*化学结构*）（II）其中R 1表示氢原子或烷基 并且R 2表示氢原子，烷基羰基，芳基羰基，烷基磺酰基，芳基磺酰基，烷氧基羰基或芳氧基羰基及其酸式盐可用于从廉价且容易获得的化合物中以短时间合成盐酸噻氯匹定。

公开(公告)号：US5162196A

公开(公告)日：1992-11-10

申请号：US615797

申请日：1990-11-20

申请人： Kozo Sato ,  Yasuhiro Shimada ,  Hideaki Naruse

发明人： Kozo Sato ,  Yasuhiro Shimada ,  Hideaki Naruse

IPC分类号： C07C255/23 ,  C07C255/30 ,  C07C255/34 ,  C07C255/35 ,  C07C255/41 ,  C07C255/44 ,  C07C255/45 ,  G03C7/36

CPC分类号： C07C255/45 ,  C07C255/23 ,  C07C255/30 ,  C07C255/34 ,  C07C255/35 ,  C07C255/41 ,  C07C255/44 ,  G03C7/36

摘要： The present invention relates to a novel color coupler for photography and a silver halide color photographic material comprising the same, wherein the color coupler is one of the .beta.,.gamma.-unsaturated nitriles represented by formula (I). The invention provides for a color coupler, particularly a cyan coupler, which forms color images less in subsidiary absorption, good in color reproduction, and excellent in fastness, and a silver halide color photographic material having color images as described above. Further the color coupler can be synthesized from inexpensive raw material at a low cost ##STR1## wherein W represents a hydrogen atom or a group capable of being released when the compound is subjected to a coupling reaction with the oxidized product of an aromatic primary amine derivative, R.sub.1 represents a represents a nitrogen atom, R.sub.2 represents a substituent, if V represents ##STR2## R.sub.2 and R.sub.3 each represent substituent, provided that at least one of R.sub.2 and R.sub.3 represents an electron attractive substituent, and provided that if R.sub.2 or R.sub.3 represents an aliphatic group or an aromatic group, the other does not represent an acyl group, and R.sub.1 and R.sub.2 may bond together to form a ring.