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公开(公告)号：US5215838A
公开(公告)日：1993-06-01
申请号：US771910
申请日：1991-10-04
申请人： Man C. Tam , Judith P. Meester , Hany M. Aboushaka , Rafik O. Loutfy , Gregory J. Kovacs , Carol A. Jennings
发明人： Man C. Tam , Judith P. Meester , Hany M. Aboushaka , Rafik O. Loutfy , Gregory J. Kovacs , Carol A. Jennings
摘要： Disclosed is a migration imaging member comprising a substrate, an infrared or red light radiation sensitive layer comprising a pigment predominantly sensitive to infrared or red light radiation, and a softenable layer comprising a softenable material, a charge transport material, and migration marking material predominantly sensitive to radiation at a wavelength other than that to which the infrared or red light radiation sensitive pigment is sensitive contained at or near the surface of the softenable layer. When the migration imaging member is imaged and developed, it is particularly suitable for use as a xeroprinting master and can also be used for viewing or for storing data.
摘要翻译： 公开了一种迁移成像构件，其包括基底，包含主要对红外或红光辐射敏感的颜料的红外或红光辐射敏感层，以及包含可软化材料，电荷传输材料和迁移标记材料的可软化层，其主要是敏感的 以在红外或红光敏感颜料敏感的波长以外的波长处辐射包含在可软化层的表面处或附近。 当迁移成像构件成像和显影时，它特别适合用作干印母版，并且还可以用于观看或存储数据。
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公开(公告)号：US4853307A
公开(公告)日：1989-08-01
申请号：US140441
申请日：1988-01-04
申请人： Man C. Tam , Steven Bloembergen , Gregory J. Kovacs , Carol A. Jennings , Rafik O. Loutfy , Sandra J. Gardner , Michael G. Taylor
发明人： Man C. Tam , Steven Bloembergen , Gregory J. Kovacs , Carol A. Jennings , Rafik O. Loutfy , Sandra J. Gardner , Michael G. Taylor
摘要： An imaging system including a migration imaging member comprising a substrate and an electrically insulating softening layer adjacent the substrate, the softenable layer comprising a fracturable layer of electrically photosensitive migration marking material located substantially at or near the surface of the softenable layer spaced from the substrate, and a copolymer of styrene and ethyl acrylate in at least one layer adjacent the substrate, the copolymer comprising between about 40 and about 80 mole percent styrene, between about 20 and about 60 mole percent ethyl acrylate, the copolymer having a M.sub.n between about 4,000 and about 35,000, a M.sub.w between about 10,000 and about 80,000, a T.sub.g between about 30.degree. C. and about 75.degree. C., and a melt viscosity between about 1.times.10.sup.2 poise and about 1.times.10.sup.6 poise at 115.degree. C.The migration imaging member may be imaged by charging, imagewise exposing to activating radiation and developing with heat, solvent vapor, or solvent vapor pretreatment followed by heat. Some embodiments of the imaged member, wherein the softenable layer contains a charge transport material, may be utilized as a master in a zeroprinting process. The copolymer of styrene and ethyl acrylate may be in an adhesive layer of charge transport spacing layer between the substrate and the sofenable layer, or in the softenable layer itself. If desired, the copolymer in any of the aforesaid layers may be a terpolymer of styrene, ethyl acrylate and a copolymerizable organic acid having carbon-to-carbon unsaturation or a copolymerizable derivative of the organic acid.
摘要翻译： 一种成像系统，其包括迁移成像构件，所述迁移成像构件包括基底和邻近所述基底的电绝缘软化层，所述可软化层包括位于所述可软化层的与所述基底隔开的表面的表面附近或附近的电光敏迁移标记材料的可破裂层， 和苯乙烯和丙烯酸乙酯在邻近基材的至少一层中的共聚物，所述共聚物包含约40至约80摩尔％的苯乙烯，约20至约60摩尔％的丙烯酸乙酯，所述共聚物的Mn在约4,000和 约35,000，约10,000至约80,000的Mw，约30℃至约75℃之间的Tg，以及在115℃下约1×102泊至约1×10 6泊的熔体粘度。迁移成像构件可以是 通过充电成像，成像暴露于活化辐射并用热，溶剂蒸气或溶剂蒸气预处理进行显影 加热。 成像构件的一些实施方案，其中可软化层含有电荷传输材料，可以在压印过程中用作母体。 苯乙烯和丙烯酸乙酯的共聚物可以在基材和可渗透层之间或在可软化层本身中的电荷输送间隔层的粘合剂层中。 如果需要，任何上述层中的共聚物可以是苯乙烯，丙烯酸乙酯和具有碳 - 碳不饱和键的可共聚有机酸或有机酸的可共聚衍生物的三元共聚物。
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公开(公告)号：US6124409A
公开(公告)日：2000-09-26
申请号：US929457
申请日：1992-08-12
申请人： T. Hwee Ng , Hadi K. Mahabadi , Man C. Tam , Gregory J. Kovacs , Eric M. Peters , Rafik O. Loutfy
发明人： T. Hwee Ng , Hadi K. Mahabadi , Man C. Tam , Gregory J. Kovacs , Eric M. Peters , Rafik O. Loutfy
CPC分类号： C08F2/001 , C08F2/06 , Y10S526/921
摘要： Disclosed is a process for preparing copolymers which comprises, in the order stated: (1) adding monomers containing unsaturated carbon-to-carbon bonds, a first polymerization initiator, a second polymerization initiator, and a solvent to a reaction vessel; (2) purging the resulting solution with an inert gas; (3) sealing the reaction vessel and pressurizing it by addition of an inert gas to a pressure of from about 20 to about 600 kilopascals over ambient atmospheric pressure; (4) maintaining the temperature within the pressurized reaction vessel at a temperature of from about 50 to about 100.degree. C. for a period of from about 60 to about 300 minutes; (5) thereafter maintaining the temperature within the pressurized reaction vessel at a temperature of from about 80 to about 115.degree. C. for a period of from about 30 to about 300 minutes, wherein the temperature in step (5) is higher than the temperature in step (4); and (6) subsequently maintaining the temperature within the pressurized reaction vessel at a temperature of from about 115 to about 160.degree. C. for a period of from about 30 to about 180 minutes, wherein the temperature in step (6) is higher than the temperature in step (5). Polymers prepared according to the process of the present invention can be particularly useful in migration imaging members.
摘要翻译： 公开了一种制备共聚物的方法，其顺序包括：（1）向反应容器中加入含有不饱和碳 - 碳键的单体，第一聚合引发剂，第二聚合引发剂和溶剂; （2）用惰性气体吹扫所得溶液; （3）密封反应容器并通过在环境大气压下加入约20至约600千帕斯卡的惰性气体对其加压; （4）将加压反应容器内的温度维持在约50至约100℃的温度下约60至约300分钟; （5）之后将加压反应容器内的温度保持在约80至约115℃的温度下约30至约300分钟的时间，其中步骤（5）中的温度高于温度 在步骤（4）中; 和（6）随后将加压反应容器内的温度保持在约115至约160℃的温度下约30至约180分钟的时间，其中步骤（6）中的温度高于 步骤（5）中的温度。 根据本发明的方法制备的聚合物可以在迁移成像构件中特别有用。
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公开(公告)号：US4970130A
公开(公告)日：1990-11-13
申请号：US444343
申请日：1989-12-01
申请人： Man C. Tam , Rafik O. Loutfy , Gregory J. Kovacs
发明人： Man C. Tam , Rafik O. Loutfy , Gregory J. Kovacs
摘要： Disclosed is a xeroprinting process which comprises(1) providing a xeroprinting master comprising(a) a substrate; and(b) a softenable layer comprising a softenable material, a charge transport material capable of transporting charges of one polarity, and migration marking material situated contiguous to the surface of the softenable layer spaced from the substrate, wherein a portion of the migration marking material has migrated through the softenable layer toward the substrate in imagewise fashion;(2) uniformly charging the xeroprinting master to a polarity opposite to the polarity of the charges that the charge transport material in the softenable layer is capable of transporting;(3) uniformly exposing the charged master to activating radiation, thereby discharging those areas of the master wherein the migration marking material has migrated toward the substrate and forming an electrostatic latent image;(4) developing the electrostatic latent image; and(5) transferring the developed image to a receiver sheet.The process results in greatly enhanced contrast potentials or contrast voltages between the charged and uncharged areas of the master subsequent to exposure to activating radiation, and the charged master can be developed with either liquid developers or dry developers.
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公开(公告)号：US5102756A
公开(公告)日：1992-04-07
申请号：US636172
申请日：1990-12-31
申请人： Paul S. Vincett , Rafik O. Loutfy , Gregory J. Kovacs , Man C. Tam , Ronald Forstinger , Brian D. Lesser , Arnold L. Pundsack , Christopher Rodgers , Philip H. Soden
发明人： Paul S. Vincett , Rafik O. Loutfy , Gregory J. Kovacs , Man C. Tam , Ronald Forstinger , Brian D. Lesser , Arnold L. Pundsack , Christopher Rodgers , Philip H. Soden
摘要： Disclosed is a printing plate precursor which comprises a base layer, a layer of photohardenable material, and a layer of softenable material containing photosensitive migration marking material. Alternatively, the precursor can comprise a base layer and a layer of softenable photohardenable material containing photosensitive migration marking material. Also disclosed are processes for preparing printing plates from the disclosed precursors.
摘要翻译： 公开了一种印版前体，其包括基底层，可光硬化材料层和含有光敏迁移标记材料的可软化材料层。 或者，前体可以包含基层和含有光敏迁移标记材料的可软化光可硬化材料层。 还公开了从所公开的前体制备印刷版的方法。
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公开(公告)号：US5576129A
公开(公告)日：1996-11-19
申请号：US353461
申请日：1994-12-09
申请人： Edward G. Zwartz , Carol A. Jennings , Man C. Tam , Philip H. Soden , Arthur Y. Jones , Arnold L. Pundsack , Enrique Levy , Ah-Mee Hor , William W. Limburg , John F. Yanus , Damodar M. Pai , Dale S. Renfer
发明人： Edward G. Zwartz , Carol A. Jennings , Man C. Tam , Philip H. Soden , Arthur Y. Jones , Arnold L. Pundsack , Enrique Levy , Ah-Mee Hor , William W. Limburg , John F. Yanus , Damodar M. Pai , Dale S. Renfer
CPC分类号： G03G17/10
摘要： Disclosed is a migration imaging member comprising a substrate, a first softenable layer comprising a first softenable material and a first migration marking material contained at or near the surface of the first softenable layer spaced from the substrate, and a second softenable layer comprising a second softenable material and a second migration marking material. Also disclosed is a migration imaging process employing the aforesaid imaging member.
摘要翻译： 公开了一种迁移成像构件，其包括基底，包含第一可软化材料的第一可软化层和包含在与基底间隔开的第一可软化层的表面处或附近的第一迁移标记材料，以及包含第二可软化层 材料和第二种迁移标记材料。 还公开了采用上述成像构件的迁移成像处理。
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公开(公告)号：US4496642A
公开(公告)日：1985-01-29
申请号：US493914
申请日：1983-05-12
申请人： Man C. Tam , Gregory J. Kovacs
发明人： Man C. Tam , Gregory J. Kovacs
摘要： An imaging member comprising a substrate, an electrically insulating swellable, softenable layer on the substrate, the softenable layer having particulate migration marking material located at least at or near the surface of the softenable layer spaced from the substrate, and a protective overcoating comprising a film-forming resin, a portion of which extends beneath the surface of the softenable layer. This migration imaging member may be prepared with the aid of a material which swells at least the surface of the softenable layer to allow the film-forming resin to penetrate beneath the surface of the softenable layer.
摘要翻译： 一种成像构件，包括基底，在基底上的电绝缘的可溶胀的可软化层，所述可软化层具有至少位于或接近与所述基底隔开的可软化层的表面或附近的颗粒迁移标记材料，以及保护性外涂层， 形成树脂，其一部分在可软化层的表面下方延伸。 该迁移成像构件可以借助于至少溶胀可软化层的表面的材料来制备，以允许成膜树脂穿透在可软化层的表面之下。
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公开(公告)号：US06180297B2
公开(公告)日：2001-01-30
申请号：US08432291
申请日：1995-05-01
申请人： Man C. Tam , Edward G. Zwartz
发明人： Man C. Tam , Edward G. Zwartz
IPC分类号： G03G1710
CPC分类号： G03G17/10
摘要： Disclosed is a process which comprises (a) providing a migration imaging member comprising (1) a substrate, (2) an infrared or red light radiation sensitive layer comprising a pigment predominantly sensitive to infrared or red light radiation, and (3) a softenable layer comprising a softenable material, a charge transport material, and a photosensitive migration marking material predominantly sensitive to radiation at a wavelength other than that to which the infrared or red light sensitive pigment is predominantly sensitive; (b) uniformly charging the imaging member; (c) subsequent to step (b), uniformly exposing the charged imaging member to a source of activating radiation with a wavelength to which the migration marking material is sensitive, wherein a filter comprising the infrared or red light radiation sensitive pigment is situated between the radiation source and the imaging member; (d) subsequent to step (b), exposing the imaging member to infrared or red light radiation at a wavelength to which the infrared or red light radiation sensitive pigment is sensitive in an imagewise pattern, thereby forming an electrostatic latent image on the imaging member; and (e) subsequent to steps (c) and (d), causing the softenable material to soften, thereby enabling the migration marking material to migrate through the softenable material toward the substrate in an imagewise pattern.
摘要翻译： 公开了一种方法，其包括（a）提供迁移成像构件，其包括（1）基底，（2）包含主要对红外或红光辐射敏感的颜料的红外或红光辐射敏感层，和（3）可软化 层，其包含可软化材料，电荷传输材料和主要对红外或红色光敏颜料主要敏感的波长以外的波长的辐射敏感的光敏迁移标记材料; （b）对成像构件均匀充电; （c）在步骤（b）之后，将所充电的成像构件均匀地暴露于迁移标记材料敏感的波长的激活辐射源，其中包含红外或红光辐射敏感颜料的滤光器位于 辐射源和成像构件; （d）在步骤（b）之后，以成像图案将成像构件暴露于红外或红光敏感颜料敏感的波长处的红外或红光辐射，从而在成像构件上形成静电潜像 ; 和（e）步骤（c）和（d）之后，使可软化材料软化，从而使迁移标记材料能够以可成形图案向基材迁移通过可软化材料。
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公开(公告)号：US06699570B2
公开(公告)日：2004-03-02
申请号：US09985825
申请日：2001-11-06
申请人： Naveen Chopra , Steven Georges , Peter M. Kazmaier , Sammy Y.H. Ro , Man C. Tam , Francisco E. Torres , Sophie V. Vandebroek
发明人： Naveen Chopra , Steven Georges , Peter M. Kazmaier , Sammy Y.H. Ro , Man C. Tam , Francisco E. Torres , Sophie V. Vandebroek
IPC分类号： B32B300
CPC分类号： B32B5/02 , B32B2554/00 , Y10T428/24835 , Y10T428/25 , Y10T428/2915 , Y10T428/2982 , Y10T442/2418
摘要： A dynamic reimageable document or electric paper can be formed from ordinary substrates such as paper, transparencies or fabric by printing of microencapsulated Gyricon beads onto one or more discrete surface areas of the substrate. The substrate can include both fixed print regions formed by conventional fixed ink processes and dynamic reimageable regions formed by the Gyricon beads. The Gyricon beads are preferably bichromal and of contrasting colors, such as black/white so as to be changeable to display two states by selective application of electromagnetic force to the beads. By providing bichromal beads in differing color combinations, such as red/white and black/white, a multi-colored document can be achieved in which various fields of the document, representing text, images or graphics, may be in differing colors. Moreover, operations to perform both imaging or erasure can act on the discrete reimageable regions so that the versatility of the electric paper can be enhanced. The Gyricon beads may be dispersed in a solution to form a liquid Gyricon toner that can be directly marked, such as by a jet nozzle, into a desired pattern on the substrate.
摘要翻译： 通过将微胶囊化Gyricon珠粒印刷到基底的一个或多个离散的表面区域上，可以由诸如纸，透明胶片或织物的普通基材形成动态可再成像的文件或电纸。 衬底可以包括通过常规固定油墨工艺形成的固定印刷区域和由Gyricon珠形成的动态可再形成区域。 Gyricon珠子优选是双色的，并且具有对比色，例如黑色/白色，以便通过选择性地向珠粒施加电磁力来显示两种状态。 通过提供不同颜色组合的双色珠，例如红/白和黑/白，可以实现多色文档，其中表示文本，图像或图形的文档的各个领域可以具有不同的颜色。 此外，执行成像或擦除的操作可以作用于离散的可再成像区域，使得可以增强电纸的通用性。 Gyricon珠可以分散在溶液中以形成液体Gyricon调色剂，其可以通过喷嘴直接标记成基底上所需的图案。
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公开(公告)号：US5683840A
公开(公告)日：1997-11-04
申请号：US632333
申请日：1996-04-11
申请人： Man C. Tam , Edward G. Zwartz , Daniel Bihon , Robert J. Kleckner
发明人： Man C. Tam , Edward G. Zwartz , Daniel Bihon , Robert J. Kleckner
摘要： Methods and techniques of electrically biasing and providing a ground for migration imaging members are disclosed. An electrically conductive contact is fixed to the migration imaging member, the electrically conductive contact connecting at least an electrically conductive layer of the migration imaging member to a ground to insure proper imaging. The contacts are fixed to the migration imaging member without having to remove a portion of the softenable layer along its edge to expose the electrically conductive layer of the migration imaging member as is the current practice.
摘要翻译： 公开了电偏置并为迁移成像构件提供接地的方法和技术。 将导电接触件固定到迁移成像构件，导电接触件将至少一个移动成像构件的导电层连接到地面以确保适当的成像。 接触件固定到迁移成像构件上，而不必沿着其边缘去除可软化层的一部分，以暴露迁移成像构件的导电层，如目前的做法。
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