公开(公告)号：US20090158640A1

公开(公告)日：2009-06-25

申请号：US12343457

申请日：2008-12-23

申请人： Marc Kellens ,  Francesco Soragna ,  Wim De Greyt

发明人： Marc Kellens ,  Francesco Soragna ,  Wim De Greyt

IPC分类号： C10L1/18 ,  C11C3/06

CPC分类号： C07C67/03 ,  C10G2300/1011 ,  C10L1/026 ,  C11C1/103 ,  C11C3/003 ,  Y02E50/13 ,  Y02P30/20 ,  C07C69/52 ,  C07C69/24

摘要： A process for the production and purification of fatty acid esters of lower alkyl alcohols with improved filtration characteristics comprising the steps of: a) transesterifying a mixture of fatty acid esters of glycerol with a lower alkyl alcohol while using an alkaline catalyst; b) separating the reaction mixture resulting from step (a) into a glycerol phase and a fatty acid lower alkyl ester phase; c) inactivating the catalytic intermediates present in said fatty acid lower alkyl ester phase; d) removing the lower alkyl alcohol from the mixture resulting from step (c) by evaporation at reduced pressure to a value of less than 2% by weight; e) treating the evaporation residue resulting from step (d) with water; and f) isolating the fatty acid esters of lower alcohols by drying the product resulting from step (e); and biodiesel containing FAME produced according to this process.

摘要翻译： 一种制备和纯化具有改进的过滤特性的低级烷基醇的脂肪酸酯的方法，包括以下步骤：a）使用碱性催化剂，将甘油的脂肪酸酯与低级烷基醇的酯交换反应; b）将由步骤（a）得到的反应混合物分离成甘油相和脂肪酸低级烷基酯相; c）使存在于所述脂肪酸低级烷基酯相中的催化中间体失活; d）通过在减压下蒸发至低于2重量％的值，从步骤（c）得到的混合物中除去低级烷基醇; e）用水处理步骤（d）产生的蒸发残余物; 和f）通过干燥由步骤（e）得到的产物来分离低级醇的脂肪酸酯; 和含有根据该方法生产的FAME的生物柴油。

公开(公告)号：US20080287697A1

公开(公告)日：2008-11-20

申请号：US12149887

申请日：2008-05-09

申请人： Marc Kellens ,  Icilio Adami ,  Francesco Soragna ,  Wim De Greyt

发明人： Marc Kellens ,  Icilio Adami ,  Francesco Soragna ,  Wim De Greyt

IPC分类号： C11B1/00

CPC分类号： C07C67/03 ,  C10L1/026 ,  C10L1/19 ,  C11C1/08 ,  C11C3/003 ,  Y02E50/13 ,  C07C69/52

摘要： This invention provides a process for forming fatty acid esters of C1-4 alkyl alcohols by alkaline transesterification of a glyceride oil, comprising the steps of: (a) providing a glyceride oil with a free fatty acid content below 2% more preferably below 0.5 weight % expressed as oleic acid; (b) mixing said glyceride oil with at least a part of one or more alcoholic phases originating from the alkaline transesterification as referred to above; (c) separating the mixture thus formed into a heavy, alcoholic phase and a light, pre-treated fatty phase; and (d) transesterifying said pre-treated fatty phase with said C1-4 alkyl alcohols. The transesterified product can be used in biodiesel production.

摘要翻译： 本发明提供了通过甘油酯油的碱性酯交换形成C 1-4烷基醇的脂肪酸酯的方法，包括以下步骤：（a）提供具有游离脂肪酸含量的甘油酯油 低于2％，更优选低于0.5重量％，表示为油酸; （b）将所述甘油酯油与源自上述碱性酯交换的一种或多种醇相的至少一部分混合; （c）将由此形成的混合物分离成重的醇相和轻的预处理脂肪相; 和（d）使所述预处理的脂肪相与所述C 1-4烷基醇进行酯交换。 酯交换产物可用于生物柴油生产。

公开(公告)号：US20080051599A1

公开(公告)日：2008-02-28

申请号：US11841255

申请日：2007-08-20

申请人： Icilio ADAMI ,  Francesco Soragna ,  Marc Kellens

发明人： Icilio ADAMI ,  Francesco Soragna ,  Marc Kellens

IPC分类号： C07C69/00

CPC分类号： C07C67/03 ,  C10G2300/1011 ,  C10L1/026 ,  C11B3/04 ,  C11B3/10 ,  C11B3/12 ,  C11B3/14 ,  C11C1/08 ,  C11C3/003 ,  Y02E50/13 ,  Y02P20/582 ,  Y02P30/20 ,  C07C69/52 ,  C07C69/24

摘要： Process for the production of esters of fatty acids and C1-C5 alkyl alcohols comprising the steps of: (a) providing a fatty feed comprising a triglyceride oil or fat, partial glycerides and/or free fatty acids, (b) neutralising said fatty feed by vacuum stripping at a temperature from 200° C. to 280° C., thus providing a vapour stream and a residue, (c) collecting a distillate by scrubbing said vapour stream, (d) transesterifying said residue with a C1-C5 alkyl alcohol while using an alkaline catalyst, (e) separating the transesterification reaction mixture from step (d) into a fraction comprising C1-C5 alkyl esters of fatty acids and an alcoholic fraction (a) wherein at least part of free acids obtained as side products in step (a) and/or (c) and/or (e) are esterifyed with an alcohol using an acid catalyst, the product of this esterification being added to said fatty feed or said residue.

摘要翻译： 制备脂肪酸和C 1 -C 5烷基醇的酯的方法，包括以下步骤：（a）提供包含甘油三酯油或脂肪的脂肪进料， 部分甘油酯和/或游离脂肪酸，（b）通过在200℃至280℃的温度下真空汽提中和所述脂肪进料，从而提供蒸汽流和残余物，（c）通过洗涤收集馏出物 所述蒸汽流，（d）使用碱性催化剂，用C 1 -C 5烷基醇酯交换所述残余物，（e）将酯交换反应混合物从步骤 d）成分包含脂肪酸C 1 -C 5烷基酯和醇部分（a）的馏分，其中至少部分作为步骤中副产物获得的游离酸 （a）和/或（c）和/或（e）使用酸催化剂用醇酯化，将该酯化的产物加入到所述脂肪进料或所述残余物中。