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公开(公告)号:US06667793B2
公开(公告)日:2003-12-23
申请号:US09809420
申请日:2001-03-16
申请人: Mark Goulding , Matthias Kuntz , Mark Verrall , David Coates
发明人: Mark Goulding , Matthias Kuntz , Mark Verrall , David Coates
IPC分类号: C09K1902
CPC分类号: C09K19/54 , C09B67/0061 , C09K19/00 , C09K2019/528 , G02B5/3016 , Y10T428/10 , Y10T428/2982
摘要: Liquid crystal pigments comprising at least one layer of liquid crystalline polymer material with a helically twisted molecular structure wherein the helical axis is oriented substantially perpendicular to the plane of the layer and which show reflection of circularly polarized light, some prepared in which the bandwidth of the reflected wavelength band is at least 100 nm. These pigments are suitable for use in reflective films or coatings for decorative applications, cosmetic compositions, and pharmaceutical compositions, optical elements, and security applications.
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公开(公告)号:US20050179003A1
公开(公告)日:2005-08-18
申请号:US10432682
申请日:2001-11-22
申请人: Michael Heckmeier , Melanie Klassen-Memmer , Georg Lüssem , Kazuaki Tarumi , David Coates , Owain Parri , Mark Verrall , Mark Goulding , Stephen Kitson
发明人: Michael Heckmeier , Melanie Klassen-Memmer , Georg Lüssem , Kazuaki Tarumi , David Coates , Owain Parri , Mark Verrall , Mark Goulding , Stephen Kitson
IPC分类号: G02F1/141 , C07C69/94 , C08F220/30 , C09K19/38 , C09K19/42 , G02F1/1334 , G02F1/1337 , G02F1/139 , C09K19/52
CPC分类号: G02F1/133711 , G02F1/1391 , G02F1/1393 , G02F2001/133715 , G02F2001/133726 , G02F2001/133742 , Y10T428/10 , Y10T428/1005 , Y10T428/1036
摘要: The invention relates to an alignment layer comprising a polymerized liquid crystal material with homeotrophic orientation, to methods of its preparation, to polymerizable liquid crystal compositions and liquid crystal polymers used for the preparation of the alignment layer, to liquid crystal devices comprising the alignment layer, and to a method of controlling the electrooptical steepness of a liquid crystal display comprising at least one alignment layer by varying the surface anchoring energy of the alignment layer.
摘要翻译: 本发明涉及一种包括具有同位素取向的聚合液晶材料的取向层,其制备方法,用于制备取向层的聚合性液晶组合物和液晶聚合物,包括取向层的液晶装置, 以及通过改变对准层的表面锚定能量来控制包括至少一个取向层的液晶显示器的电光陡度的方法。
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公开(公告)号:US06466297B1
公开(公告)日:2002-10-15
申请号:US09609396
申请日:2000-07-03
申请人: Mark Goulding , David Coates , John Patrick , Mark Verrall , John Argent
发明人: Mark Goulding , David Coates , John Patrick , Mark Verrall , John Argent
IPC分类号: G02B530
CPC分类号: G02B5/3016 , Y10T428/1041
摘要: The invention relates to a method of preparing a broadband reflective polarizer comprising the blending a first mixture A comprising at least one achiral polymerizable mesogenic compound with a second mixture B comprising at least one chiral polymerizable mesogenic compound; and coating a layer of the blended mixture onto a first substrate and aligning the chiral mesogenic material in a planar orientation so that the axis of the molecular helix extends transversely to the layer.
摘要翻译: 本发明涉及一种制备宽带反射偏光镜的方法,包括将包含至少一种非手性可聚合介晶化合物的第一混合物A与包含至少一种手性可聚合介晶化合物的第二混合物B混合; 并将一层混合的混合物涂覆到第一基底上,并将所述手性介晶材料以平面取向对准,使得分子螺旋的轴线横向延伸到该层。
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公开(公告)号:US06899929B2
公开(公告)日:2005-05-31
申请号:US09859482
申请日:2001-05-18
申请人: Mark Verrall , Mark Goulding , Quentin Hodges , Ben Godden
发明人: Mark Verrall , Mark Goulding , Quentin Hodges , Ben Godden
IPC分类号: C08F20/10 , G02B5/30 , G02F1/1335 , G02F1/13363 , G02F1/13
CPC分类号: G02F1/133632 , C09K2019/0448 , G02B5/3016 , G02F2413/105 , Y10T428/10 , Y10T428/1036 , Y10T428/1045 , Y10T428/1059
摘要: The invention relates to an optical retardation film comprising two layers of an anisotropic polymer adjacent to each other or adjacent to both sides of a substrate, characterized in that each layer exhibits a tilted structure with an optical symmetry axis having a tilt angle θ relative to the plane of the layer, to a means to produce substantially linear polarized light comprising such an optical retardation film and to a liquid crystal display comprising such an optical retardation film.
摘要翻译: 本发明涉及一种光学延迟膜,其包含彼此相邻或相邻于基底两侧的各向异性聚合物层,其特征在于每个层呈现倾斜结构,光学对称轴具有相对于 平面,以产生包括这种光学延迟膜的基本上线性的偏振光的装置和包括这种光学延迟膜的液晶显示器。
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公开(公告)号:US07105586B2
公开(公告)日:2006-09-12
申请号:US10790690
申请日:2004-03-03
申请人: Mark Verrall , Mark Goulding , Quentin Hodges , Ben Godden
发明人: Mark Verrall , Mark Goulding , Quentin Hodges , Ben Godden
CPC分类号: G02F1/133632 , C09K2019/0448 , G02B5/3016 , G02F2413/105 , Y10T428/10 , Y10T428/1036 , Y10T428/1045 , Y10T428/1059
摘要: The invention relates to an optical retardation film comprising two layers of an anisotropic polymer adjacent to each other or adjacent to both sides of a substrate, characterized in that each layer exhibits a tilted structure with an optical symmetry axis having a tilt angle θ relative to the plane of the layer, to a means to produce substantially linear polarized light comprising such an optical retardation film and to a liquid crystal display comprising such an optical retardation film.
摘要翻译: 本发明涉及一种光学延迟膜,其包含彼此相邻或相邻于基底的两侧的各向异性聚合物层,其特征在于每个层呈现倾斜结构,其中光学对称轴具有相对于 平面,以产生包括这种光学延迟膜的基本上线性的偏振光的装置和包括这种光学延迟膜的液晶显示器。
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公开(公告)号:US06291035B1
公开(公告)日:2001-09-18
申请号:US09254185
申请日:1999-03-02
申请人: Mark Verrall , Mark Goulding , Quentin Hodges , Ben Godden
发明人: Mark Verrall , Mark Goulding , Quentin Hodges , Ben Godden
IPC分类号: G02F11335
CPC分类号: G02F1/133632 , C09K2019/0448 , G02B5/3016 , G02F2413/105 , Y10T428/10 , Y10T428/1036 , Y10T428/1045 , Y10T428/1059
摘要: The invention relates to an optical retardation film comprising two layers of an anisotropic polymer adjacent to each other or adjacent to both sides of a substrate, characterized in that each layer exhibits a tilted structure with an optical symmetry axis having a tilt angle &thgr; relative to the plane of the layer, to a means to produce substantially linear polarized light comprising such an optical retardation film and to a liquid crystal display comprising such an optical retardation film.
摘要翻译: 本发明涉及一种光学延迟膜,其包含彼此相邻或相邻于基底两侧的各向异性聚合物层,其特征在于每个层呈现倾斜结构,光学对称轴具有相对于 平面,以产生包括这种光学延迟膜的基本上线性的偏振光的装置和包括这种光学延迟膜的液晶显示器。
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公开(公告)号:US06669865B1
公开(公告)日:2003-12-30
申请号:US09696282
申请日:2000-10-26
申请人: David Coates , Simon Greenfield , Mark Goulding , James Hanmer , Shirley Marden , Owain Llyr Parri
发明人: David Coates , Simon Greenfield , Mark Goulding , James Hanmer , Shirley Marden , Owain Llyr Parri
IPC分类号: C09K1938
CPC分类号: C09K19/38 , C09K2219/03 , G02B5/3016 , G02F1/133528 , Y10T428/1041
摘要: A liquid crystal display device containing a liquid crystal cell and at least one reflective polarizer or a polarizer combination having at least one reflective polarizer as a means to generate circular polarized light. The reflective polarizer includes an optically active layer of an anisotropic polymer material with a helically twisted planar molecular orientation. The material is oriented so that the axis of the molecular helix extends transversely to the layer, and the pitch of the molecular helix is varied in such a manner that the difference between the maximum pitch and the minimum pitch is at least 100 nm. The reflective polarizer is obtainable by copolymerization of a mixture of a chiral polymerizable mesogenic material including a) at least one achiral polymerizable mesogenic compound having at least one polymerizable functional group in the presence of b) at least one chiral polymerizable mesogenic compound having one polymerizable functional group and/or at least one non-polymerizable chiral mesogenic compound, c) an initiator, d) optionally a non-mesogenic compound having at least one polymerizable functional group, e) optionally a dye and, i) optionally a stabilizer. The invention also discloses methods of manufacturing such a reflective polarizer. The invention further discloses a mixture of a chiral polymerizable mesogenic material used for manufacturing such a reflective polarizer.
摘要翻译: 一种液晶显示装置,其包含液晶单元和至少一个反射偏振器或具有至少一个反射偏振器的偏振器组合,作为产生圆偏振光的手段。 反射偏振器包括具有螺旋扭曲的平面分子取向的各向异性聚合物材料的光学活性层。 该材料被定向成使得分子螺旋线的轴线横向延伸,并且分子螺旋线的间距以最大间距和最小间距之差至少为100nm的方式变化。 反射型偏振片可通过手性可聚合介晶材料的混合物共聚获得,该混合物包括:a)至少一种具有至少一个可聚合官能团的非手性可聚合介晶化合物,其中b)至少一种具有一个可聚合官能团的手性可聚合介晶化合物 基团和/或至少一种不可聚合的手性介晶化合物,c)引发剂,d)任选的具有至少一个可聚合官能团的非介晶化合物,e)任选的染料和i)任选的稳定剂。 本发明还公开了制造这种反射偏振器的方法。 本发明还公开了用于制造这种反射偏振器的手性可聚合介晶材料的混合物。
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公开(公告)号:US5328644A
公开(公告)日:1994-07-12
申请号:US973914
申请日:1992-11-12
CPC分类号: C07C43/1742 , C07C25/18 , C07C25/24 , C09K19/44
摘要: Disclosed is a nematic liquid crystal mixture having a positive dielectric anisotropy .DELTA..epsilon. of at least +4 and a birefringence .DELTA.n of at least 0.18, said mixture comprising at least one fluorinated chloroterphenyl compound of formula IR--E--Cl IwhereinR is an alkyl or alkenyl radical having up to 15 C atoms, said radical being unsubstituted or substituted by halogen, one or more CH.sub.2 groups in the radical optionally being replaced, in each case independently of one another, by --O--, ##STR1## in such a manner that oxygen atoms are not linked directly to one another, andis ##STR2## or the mirror image thereof, and wherein the benzene rings can be optionally further substituted by fluorine.
摘要翻译: 公开了具有至少+4的正介电各向异性DELTAε和至少0.18的双折射DELTA n的向列型液晶混合物,所述混合物包含至少一种式I的氯化三苯基化合物RE-ClI,其中R是烷基或 具有至多15个C原子的烯基,所述基团是未取代的或被卤素取代,所述基团中的一个或多个CH 2基团任选被取代,在每种情况下彼此独立地以这样的方式被-O - , - IMAGE 氧原子彼此不直接连接,并且是“IMAGE”或其镜像,并且其中苯环可以任选进一步被氟取代。
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公开(公告)号:US5942648A
公开(公告)日:1999-08-24
申请号:US811179
申请日:1997-03-04
申请人: David Coates , Mark Goulding , Simon Greenfield , Volker Reiffenrath , Reinhard Hittich , Herbert Plach
发明人: David Coates , Mark Goulding , Simon Greenfield , Volker Reiffenrath , Reinhard Hittich , Herbert Plach
IPC分类号: C07C17/26 , C07C25/22 , C07C43/225 , C07C43/23 , C07C255/50 , C07C255/54 , C09K19/32 , C07C15/24
CPC分类号: C07C17/263 , C07C25/22 , C07C255/50 , C07C255/54 , C07C43/225 , C07C43/23 , C09K19/322
摘要: Naphthalene derivatives of the fomula I ##STR1## in which: R.sup.1 is an alkyl or alkenyl radical which is unsubstituted, monosubstituted by CH or CF.sub.3 or monosubstituted by halogen and has 1 to 15 carbon atoms, it also being possible for one or more CH.sub.2 groups in these radicals to be replaced, in each case independently of one another, by --O--, --S--, ##STR2## --CO--, --CO--O--, --O--CO-- or --O--CO--O-- in such a manner that oxygen atoms are not linked directly to one another, ##STR3## m is 0, 1 or 2, n is 0 or 1, wherem+n is 1 or 2,Z.sup.1 and Z.sup.2 are each, independently of one another, --CH.sub.2 CH.sub.2 --, --C.tbd.C-- or a single bond,L.sup.1 and L.sup.2 independently of one another, are H or F,x is an alkyl or alkoxy radical which is unsubstituted, monosubstituted by CN or CF.sub.3 or substituted bi halogen and has 1 to 15 carbon atoms, or is OH, CN, SCN, OCN, NCS or Q--Y,whereQ is a single bond, (CF.sub.2).sub.r or O(CF.sub.2).sub.rr is 1 or 2, andY is H, F, Cl or Br, with the provisos thata) in the case wherem=0, Z.sup.2 =a single bond, n=1 and x=CH CF.sub.3 or SCN, L.sup.1 is F,b) in the case wherem=0, Z.sup.2 =a single bond, n=1 and X=alkyl, alkoxy or F a L.sup.1 and L.sup.2 are identical and are F.
摘要翻译: 式I的萘衍生物,其中:R 1是未被取代的,被CH或CF 3单取代或被卤素单取代且具有1至15个碳原子的烷基或烯基,它们也可以在这些基团中一个或多个CH 2基团 在各种情况下彼此独立地被-O-,-S-,-CO-,-CO-O-,-O-CO-或-O-CO-O-取代,使得氧 原子不直接相互连接,m为0,1或2,n为0或1,其中m + n为1或2,Z 1和Z 2各自独立地为-CH 2 CH 2 - , - CO 3 C或单键,L 1和L 2彼此独立地是H或F,x是未被取代的,被CN或CF 3或被取代的双卤素单取代且具有1至15个碳原子的烷基或烷氧基,或者是 OH,CN,SCN,OCN,NCS或QY,其中Q为单键,(CF2)r或O(CF2)rr为1或2,Y为H,F,Cl或Br,条件是 )在m = 0的情况下,Z2 =单键,n = 1,x = CH CF 3或SCN,L1为F,b) 在m = 0的情况下,Z 2 =单键,n = 1,X =烷基,烷氧基或F a,L1和L2相同,为F.
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公开(公告)号:US5750051A
公开(公告)日:1998-05-12
申请号:US623163
申请日:1996-03-28
申请人: Mark Goulding , David Coates , Simon Greenfield
发明人: Mark Goulding , David Coates , Simon Greenfield
IPC分类号: G02F1/13 , C07C43/225 , C07C69/54 , C07C69/653 , C07D303/22 , C07D303/24 , C09K19/12 , C09K19/38 , C08F22/00 , C09K19/52
CPC分类号: C07D303/22 , C07C43/225 , C07C69/54 , C07C69/653 , C07D303/24 , C09K19/12 , C09K19/126 , C09K19/38 , C09K2219/03 , Y10T428/1041
摘要: The invention relates to monofunctional reactive terphenyls of formula I ##STR1## in which R.sup.4 is CH.sub.2 =CW--COO--, ##STR2## HWN--, CH.sub.2 =CH--, CH.sub.2 =CH--O-- or HS--CH.sub.2 --(CH.sub.2).sub.m --COO-- with W being H, Cl or alkyl with 1-5 C atoms and m being 1-7, P is alkylene with up to 12 C atoms, it being also possible for one or more non adjacent CH.sub.2 groups to be replaced by --O--, L.sup.1 is H or F, X is --O--, --S--, --COO--, --OCO-- or a single bond, u is 0 or 1, n is an integer 1 to 8, and m is an integer 2 to 8.
摘要翻译: 本发明涉及式I的单官能反应性三联苯,其中R 4是CH 2 = CW-COO-,CH 3 = CH-,CH 2 = CH-,CH 2 = CH-O-或HS-CH 2 - (CH 2) m-COO-,其中W是H,Cl或具有1-5个C原子的烷基,m是1-7,P是具有最多12个C原子的亚烷基,也可以被一个或多个不相邻的CH 2基团取代 通过-O-,L 1是H或F,X是-O - , - S-,-COO-,-OCO-或单键,u是0或1,n是1到8的整数,m是 整数2到8。
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