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公开(公告)号：US07485758B2
公开(公告)日：2009-02-03
申请号：US11861381
申请日：2007-09-26
申请人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
发明人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
CPC分类号： C07C45/517 , C07C37/08 , C07C45/53 , C07C49/08 , C07C39/04
摘要： A method for the production of phenol and acetone from a cumene hydroperoxide mixture comprises a first stage and a second stage and at least two serially connected reactors, wherein the first stage comprises decomposition of a cumene hydroperoxide mixture in the presence of a catalyst mixture to form a dicumyl peroxide mixture, and the second stage comprises formation of a phenol and acetone mixture from decomposition of the dicumyl peroxide mixture formed in the first stage, wherein, the first stage further comprises: a) forming a catalyst mixture by combining sulfuric acid and phenol in a weight ratio of from 2:1 to 1:1000 in a catalyst formation reactor, b) holding the catalyst mixture in the catalyst formation reactor at a temperature of about 20 to 80° C. for about 1 to 600 minutes; and, c) adding the catalyst mixture to the cumene hydroperoxide mixture to form the phenol and acetone mixture. The proposed method permits a significant reduction in the yield of hydroxyacetone that causes deterioration in the quality of commercial phenol.
摘要翻译： 从氢过氧化枯烯混合物生产苯酚和丙酮的方法包括第一阶段和第二阶段以及至少两个串联的反应器，其中第一阶段包括在催化剂混合物存在下分解氢过氧化枯烯混合物以形成 二异辛烯过氧化物混合物，第二阶段包括由第一阶段中形成的二异辛烯过氧化物混合物的分解形成苯酚和丙酮混合物，其中第一阶段还包括：a）通过将硫酸和苯酚 在催化剂生成反应器中重量比为2:1至1:1000，b）将催化剂混合物在约20至80℃的温度下保持在催化剂生成反应器中约1至600分钟; 和c）将催化剂混合物加入氢过氧化枯烯混合物中以形成苯酚和丙酮混合物。 所提出的方法允许显着降低羟基丙酮的产率，导致商业酚的质量下降。
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公开(公告)号：US07482493B2
公开(公告)日：2009-01-27
申请号：US11861374
申请日：2007-09-26
申请人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
发明人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
摘要： A method for the production of phenol and acetone from a cumene hydroperoxide mixture comprises: decomposing the cumene hydroperoxide mixture in the presence of a catalyst mixture to form a mixture comprising phenol and acetone, wherein the method further comprises: a) forming the catalyst mixture in a catalyst formation reactor by combining sulfuric acid and phenol in a weight ratio of from 2:1 to 1:1000; b) holding the catalyst mixture in the catalyst formation reactor at a temperature of about 20 to 80° C. for about 1 to 600 minutes; and c) adding the catalyst mixture to the cumene hydroperoxide mixture to form the phenol and acetone mixture. Running the process in this manner reduces the yield of hydroxyacetone and, consequently, improves the quality of the commercial phenol. Moreover, this method reduces consumption of sulfuric acid in comparison with the process in which sulfuric acid is used as catalyst.
摘要翻译： 用于由氢过氧化枯烯混合物生产苯酚和丙酮的方法包括：在催化剂混合物存在下分解氢过氧化枯烯混合物以形成包含苯酚和丙酮的混合物，其中该方法还包括：a）将催化剂混合物形成 催化剂形成反应器，其结合硫酸和苯酚，重量比为2:1至1:1000; b）将催化剂混合物在约20至80℃的温度下保持在催化剂生成反应器中约1至600分钟; 和c）将催化剂混合物加入氢过氧化枯烯混合物中以形成苯酚和丙酮混合物。 以这种方式运行该方法降低了羟基丙酮的产率，因此改善了商业苯酚的质量。 此外，与使用硫酸作为催化剂的方法相比，该方法降低了硫酸的消耗。
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公开(公告)号：US20080214872A1
公开(公告)日：2008-09-04
申请号：US11861374
申请日：2007-09-26
申请人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
发明人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
摘要： A method for the production of phenol and acetone from a cumene hydroperoxide mixture comprises: decomposing the cumene hydroperoxide mixture in the presence of a catalyst mixture to form a mixture comprising phenol and acetone, wherein the method further comprises: a) forming the catalyst mixture in a catalyst formation reactor by combining sulfuric acid and phenol in a weight ratio of from 2:1 to 1:1000; b) holding the catalyst mixture in the catalyst formation reactor at a temperature of about 20 to 80° C. for about 1 to 600 minutes; and c) adding the catalyst mixture to the cumene hydroperoxide mixture to form the phenol and acetone mixture. Running the process in this manner reduces the yield of hydroxyacetone and, consequently, improves the quality of the commercial phenol. Moreover, this method reduces consumption of sulfuric acid in comparison with the process in which sulfuric acid is used as catalyst.
摘要翻译： 用于由氢过氧化枯烯混合物生产苯酚和丙酮的方法包括：在催化剂混合物存在下分解氢过氧化枯烯混合物以形成包含苯酚和丙酮的混合物，其中该方法还包括：a）将催化剂混合物形成 催化剂形成反应器，其结合硫酸和苯酚，重量比为2:1至1:1000; b）将催化剂混合物在约20至80℃的温度下保持在催化剂生成反应器中约1至600分钟; 和c）将催化剂混合物加入氢过氧化枯烯混合物中以形成苯酚和丙酮混合物。 以这种方式运行该方法降低了羟基丙酮的产率，因此改善了商业苯酚的质量。 此外，与使用硫酸作为催化剂的方法相比，该方法降低了硫酸的消耗。
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公开(公告)号：US20080214873A1
公开(公告)日：2008-09-04
申请号：US11861381
申请日：2007-09-26
申请人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
发明人： Mark Nelson , Willem Lodewyk Sederel , Arkady Samuilovich Dyckman , Ilya Nikolaevich Grebenshchikov , Viktor Vladimirovich Pinson , Andrey Vladimirovich Zinenkov
CPC分类号： C07C45/517 , C07C37/08 , C07C45/53 , C07C49/08 , C07C39/04
摘要： A method for the production of phenol and acetone from a cumene hydroperoxide mixture comprises a first stage and a second stage and at least two serially connected reactors, wherein the first stage comprises decomposition of a cumene hydroperoxide mixture in the presence of a catalyst mixture to form a dicumyl peroxide mixture, and the second stage comprises formation of a phenol and acetone mixture from decomposition of the dicumyl peroxide mixture formed in the first stage, wherein, the first stage further comprises: a) forming a catalyst mixture by combining sulfuric acid and phenol in a weight ratio of from 2:1 to 1:1000 in a catalyst formation reactor, b) holding the catalyst mixture in the catalyst formation reactor at a temperature of about 20 to 80° C. for about 1 to 600 minutes; and, c) adding the catalyst mixture to the cumene hydroperoxide mixture to form the phenol and acetone mixture. The proposed method permits a significant reduction in the yield of hydroxyacetone that causes deterioration in the quality of commercial phenol.
摘要翻译： 从氢过氧化枯烯混合物生产苯酚和丙酮的方法包括第一阶段和第二阶段以及至少两个串联的反应器，其中第一阶段包括在催化剂混合物存在下分解氢过氧化枯烯混合物以形成 二异辛烯过氧化物混合物，第二阶段包括由第一阶段中形成的二异辛烯过氧化物混合物的分解形成苯酚和丙酮混合物，其中第一阶段还包括：a）通过将硫酸和苯酚 在催化剂生成反应器中重量比为2:1至1:1000，b）将催化剂混合物在约20至80℃的温度下保持在催化剂生成反应器中约1至600分钟; 和c）将催化剂混合物加入氢过氧化枯烯混合物中以形成苯酚和丙酮混合物。 所提出的方法允许显着降低羟基丙酮的产率，导致商业酚的质量下降。
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